Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051118\ Data File : VX001656.D Acq On : 11 May 2018 22:48 Operator : JC/MD Sample : J2741-09MSD Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 22 Sample Multiplier: 1 Quant Time: May 12 07:27:37 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 252106 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 328781 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 307315 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 214538 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 152142 41.99 ug/l 0.00 Spiked Amount 50.000 Recovery = 83.98% 35) Dibromofluoromethane 5.51 113 130248 44.54 ug/l 0.00 Spiked Amount 50.000 Recovery = 89.08% 50) Toluene-d8 8.72 98 451216 42.27 ug/l 0.00 Spiked Amount 50.000 Recovery = 84.54% 62) 4-Bromofluorobenzene 11.14 95 167366 40.84 ug/l 0.00 Spiked Amount 50.000 Recovery = 81.68% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 147186 43.37 ug/l 99 3) Chloromethane 1.32 50 144337 43.67 ug/l 99 4) Vinyl Chloride 1.40 62 412587 119.61 ug/l 99 5) Bromomethane 1.64 94 68339 42.79 ug/l 100 6) Chloroethane 1.72 64 108187 47.45 ug/l 100 7) Trichlorofluoromethane 1.93 101 237252 45.70 ug/l 100 8) Diethyl Ether 2.19 74 96792 47.57 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.39 101 137884 45.30 ug/l 99 10) Methyl Iodide 2.51 142 165686 37.73 ug/l 99 11) Tert butyl alcohol 3.09 59 173223 226.74 ug/l 99 12) 1,1-Dichloroethene 2.37 96 135705 48.65 ug/l 98 13) Acrolein 2.30 56 24687 159.70 ug/l 97 14) Allyl chloride 2.73 41 245464 47.19 ug/l 98 15) Acrylonitrile 3.15 53 418338 242.32 ug/l 100 16) Acetone 2.45 43 351725 213.76 ug/l 97 17) Carbon Disulfide 2.57 76 305834 43.08 ug/l 99 18) Methyl Acetate 2.78 43 218658 50.58 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 469902 48.38 ug/l 98 20) Methylene Chloride 2.86 84 148438 45.56 ug/l 98 21) trans-1,2-Dichloroethene 3.17 96 143747 46.17 ug/l 98 22) Diisopropyl ether 3.88 45 477300 49.11 ug/l 99 23) Vinyl Acetate 3.83 43 1857303 229.32 ug/l 99 24) 1,1-Dichloroethane 3.70 63 275386 50.73 ug/l 100 25) 2-Butanone 4.72 43 564880 237.50 ug/l 99 26) 2,2-Dichloropropane 4.59 77 173340 41.35 ug/l # 1 27) cis-1,2-Dichloroethene 4.60 96 2908042 877.06 ug/l 85 28) Bromochloromethane 5.03 49 116889 49.66 ug/l 99 29) Tetrahydrofuran 5.18 42 366280 240.69 ug/l 100 30) Chloroform 5.22 83 279515 49.98 ug/l 98 31) Cyclohexane 5.58 56 216118 46.35 ug/l 100 32) 1,1,1-Trichloroethane 5.50 97 247518 50.64 ug/l 100 36) 1,1-Dichloropropene 5.81 75 192542 46.04 ug/l 99 37) Ethyl Acetate 4.87 43 205153 44.75 ug/l # 81 38) Carbon Tetrachloride 5.79 117 222888 49.97 ug/l 100 39) Methylcyclohexane 7.46 83 222667 45.03 ug/l 97 40) Benzene 6.15 78 594772 48.69 ug/l 99 41) Methacrylonitrile 5.07 41 126120 48.08 ug/l 99 42) 1,2-Dichloroethane 6.20 62 224683 47.86 ug/l 100 43) Isopropyl Acetate 6.48 43 338068 48.04 ug/l 99 44) Trichloroethene 7.22 130 180631 48.38 ug/l 99 45) 1,2-Dichloropropane 7.52 63 152529 50.09 ug/l 99 46) Dibromomethane 7.67 93 104814 48.62 ug/l 99 47) Bromodichloromethane 7.90 83 208219 52.19 ug/l 98 48) Methyl methacrylate 7.79 41 189451 49.44 ug/l 99 49) 1,4-Dioxane 7.76 88 72310 873.38 ug/l 98 51) 4-Methyl-2-Pentanone 8.66 43 1181252 252.58 ug/l 99 52) Toluene 8.79 92 390805 48.93 ug/l 99 53) t-1,3-Dichloropropene 8.44 75 227125 50.37 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 206718 44.60 ug/l 97 55) 1,1,2-Trichloroethane 9.22 97 158481 49.25 ug/l 98 56) Ethyl methacrylate 9.19 69 228891 49.34 ug/l 98 57) 1,3-Dichloropropane 9.38 76 256543 48.21 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.29 63 471 0.21 ug/l # 43 59) 2-Hexanone 9.51 43 860440 240.27 ug/l 99 60) Dibromochloromethane 9.59 129 170922 51.87 ug/l 99 61) 1,2-Dibromoethane 9.68 107 164751 48.76 ug/l 99 64) Tetrachloroethene 9.34 164 195612 45.67 ug/l 97 65) Chlorobenzene 10.15 112 436019 48.38 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 166966 51.79 ug/l 99 67) Ethyl Benzene 10.26 91 716015 48.47 ug/l 99 68) m/p-Xylenes 10.37 106 571435 97.90 ug/l 99 69) o-Xylene 10.71 106 280156 49.39 ug/l 99 70) Styrene 10.72 104 462782 50.22 ug/l 99 71) Bromoform 10.87 173 139429 45.33 ug/l 99 73) Isopropylbenzene 11.02 105 748392 50.39 ug/l 100 74) N-amyl acetate 6.48 43 338068 50.11 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 232580 53.02 ug/l 98 76) 1,2,3-Trichloropropane 11.30 75 217665m 50.03 ug/l 77) Bromobenzene 11.26 156 214549 49.69 ug/l 99 78) n-propylbenzene 11.37 91 818167 50.59 ug/l 100 79) 2-Chlorotoluene 11.43 91 496390 49.88 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 618673 50.03 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 59387 44.07 ug/l 98 82) 4-Chlorotoluene 11.52 91 571036 49.74 ug/l 100 83) tert-Butylbenzene 11.77 119 648141 52.68 ug/l 98 84) 1,2,4-Trimethylbenzene 11.81 105 642681 50.57 ug/l 99 85) sec-Butylbenzene 11.95 105 755365 51.15 ug/l 100 86) p-Isopropyltoluene 12.07 119 689109 50.87 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 379328 49.14 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 383320 48.69 ug/l 100 89) n-Butylbenzene 12.40 91 549676 48.97 ug/l 100 90) Hexachloroethane 12.60 117 112370 55.09 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 388641 49.49 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 52100 54.06 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 286521 49.86 ug/l 99 94) Hexachlorobutadiene 13.79 225 150206 47.77 ug/l 99 95) Naphthalene 13.84 128 849515 53.45 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 299593 50.81 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed