Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051118\ Data File : VX001657.D Acq On : 11 May 2018 23:15 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 23 Sample Multiplier: 1 Quant Time: May 12 07:28:28 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 236530 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 307390 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 286924 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 204140 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 150427 44.25 ug/l 0.00 Spiked Amount 50.000 Recovery = 88.50% 35) Dibromofluoromethane 5.51 113 128530 47.01 ug/l 0.00 Spiked Amount 50.000 Recovery = 94.02% 50) Toluene-d8 8.72 98 453340 45.42 ug/l 0.00 Spiked Amount 50.000 Recovery = 90.84% 62) 4-Bromofluorobenzene 11.14 95 171080 44.65 ug/l 0.00 Spiked Amount 50.000 Recovery = 89.30% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 150781 47.35 ug/l 100 3) Chloromethane 1.32 50 145081 46.78 ug/l 99 4) Vinyl Chloride 1.40 62 158729 49.05 ug/l 99 5) Bromomethane 1.64 94 64085 42.76 ug/l 97 6) Chloroethane 1.71 64 105408 49.27 ug/l 100 7) Trichlorofluoromethane 1.92 101 237961 48.86 ug/l 98 8) Diethyl Ether 2.19 74 97966 51.32 ug/l 100 9) 1,1,2-Trichlorotrifluoroet 2.38 101 138351 48.45 ug/l 98 10) Methyl Iodide 2.51 142 163548 39.69 ug/l 99 11) Tert butyl alcohol 3.09 59 184949 258.03 ug/l 99 12) 1,1-Dichloroethene 2.37 96 130559 49.88 ug/l 98 13) Acrolein 2.29 56 25501 177.07 ug/l 94 14) Allyl chloride 2.73 41 249132 51.05 ug/l 97 15) Acrylonitrile 3.15 53 423123 261.23 ug/l 100 16) Acetone 2.45 43 371847 240.88 ug/l 98 17) Carbon Disulfide 2.57 76 306793 46.06 ug/l 99 18) Methyl Acetate 2.78 43 236091 58.21 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 473058 51.91 ug/l 99 20) Methylene Chloride 2.86 84 150639 49.28 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 138767 47.51 ug/l 97 22) Diisopropyl ether 3.88 45 483829 53.06 ug/l 98 23) Vinyl Acetate 3.83 43 1990860 262.00 ug/l 100 24) 1,1-Dichloroethane 3.70 63 267228 52.47 ug/l 99 25) 2-Butanone 4.72 43 581733 260.69 ug/l 98 26) 2,2-Dichloropropane 4.59 77 169695 43.14 ug/l 97 27) cis-1,2-Dichloroethene 4.60 96 168678 54.22 ug/l 94 28) Bromochloromethane 5.03 49 114460 51.83 ug/l 99 29) Tetrahydrofuran 5.18 42 375078 262.71 ug/l 100 30) Chloroform 5.22 83 280155 53.40 ug/l 100 31) Cyclohexane 5.58 56 220069 50.31 ug/l 96 32) 1,1,1-Trichloroethane 5.50 97 248987 54.30 ug/l 100 36) 1,1-Dichloropropene 5.81 75 195763 50.07 ug/l 100 37) Ethyl Acetate 4.87 43 222060 51.81 ug/l 100 38) Carbon Tetrachloride 5.79 117 223428 53.58 ug/l 98 39) Methylcyclohexane 7.46 83 227308 49.17 ug/l 98 40) Benzene 6.15 78 595244 52.12 ug/l 97 41) Methacrylonitrile 5.07 41 128702 52.48 ug/l 99 42) 1,2-Dichloroethane 6.20 62 228019 51.95 ug/l 100 43) Isopropyl Acetate 6.48 43 355219 53.99 ug/l 100 44) Trichloroethene 7.22 130 181104 51.88 ug/l 99 45) 1,2-Dichloropropane 7.52 63 151499 53.21 ug/l 98 46) Dibromomethane 7.67 93 105805 52.49 ug/l 99 47) Bromodichloromethane 7.90 83 208465 55.88 ug/l 100 48) Methyl methacrylate 7.79 41 189777 52.97 ug/l 98 49) 1,4-Dioxane 7.76 88 81759 1056.23 ug/l 100 51) 4-Methyl-2-Pentanone 8.66 43 1200335 274.53 ug/l 99 52) Toluene 8.79 92 397614 53.24 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 234918 55.72 ug/l 97 54) cis-1,3-Dichloropropene 9.05 75 215365 49.44 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 157594 52.38 ug/l 100 56) Ethyl methacrylate 9.19 69 234201 54.00 ug/l 98 57) 1,3-Dichloropropane 9.38 76 258877 52.04 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 595642 280.02 ug/l 100 59) 2-Hexanone 9.51 43 880385 262.95 ug/l 99 60) Dibromochloromethane 9.59 129 173601 56.35 ug/l 100 61) 1,2-Dibromoethane 9.68 107 165810 52.49 ug/l 99 64) Tetrachloroethene 9.34 164 211931 52.99 ug/l 98 65) Chlorobenzene 10.15 112 439131 52.19 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 167543 55.66 ug/l 99 67) Ethyl Benzene 10.26 91 726211 52.65 ug/l 100 68) m/p-Xylenes 10.37 106 579268 106.29 ug/l 99 69) o-Xylene 10.71 106 284079 53.64 ug/l 99 70) Styrene 10.72 104 473443 55.02 ug/l 99 71) Bromoform 10.87 173 141649 49.01 ug/l 100 73) Isopropylbenzene 11.02 105 764344 54.09 ug/l 100 74) N-amyl acetate 6.48 43 355219 55.34 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 229634 55.02 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 219459m 53.01 ug/l 77) Bromobenzene 11.26 156 216633 52.73 ug/l 99 78) n-propylbenzene 11.37 91 842983 54.78 ug/l 100 79) 2-Chlorotoluene 11.43 91 503491 53.17 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 634091 53.89 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 59974 46.51 ug/l 97 82) 4-Chlorotoluene 11.52 91 586157 53.65 ug/l 100 83) tert-Butylbenzene 11.77 119 625048 53.39 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 657509 54.37 ug/l 100 85) sec-Butylbenzene 11.95 105 773007 55.01 ug/l 99 86) p-Isopropyltoluene 12.07 119 708885 54.99 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 385750 52.52 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 388746 51.89 ug/l 99 89) n-Butylbenzene 12.40 91 569276 53.30 ug/l 100 90) Hexachloroethane 12.60 117 113254 58.35 ug/l 100 91) 1,2-Dichlorobenzene 12.40 146 396633 53.08 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 53950 58.83 ug/l 100 93) 1,2,4-Trichlorobenzene 13.65 180 297130 54.34 ug/l 100 94) Hexachlorobutadiene 13.79 225 155536 51.99 ug/l 99 95) Naphthalene 13.84 128 868916 57.46 ug/l 100 96) 1,2,3-Trichlorobenzene 14.03 180 310283 55.30 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed