Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051218\ Data File : VX001659.D Acq On : 12 May 2018 10:39 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 2 Sample Multiplier: 1 Quant Time: May 14 06:24:53 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 259644 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 319683 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 299107 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 218773 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 156921 42.05 ug/l 0.00 Spiked Amount 50.000 Recovery = 84.10% 35) Dibromofluoromethane 5.51 113 134475 47.29 ug/l 0.00 Spiked Amount 50.000 Recovery = 94.58% 50) Toluene-d8 8.72 98 474106 45.68 ug/l 0.00 Spiked Amount 50.000 Recovery = 91.36% 62) 4-Bromofluorobenzene 11.14 95 182270 45.75 ug/l 0.00 Spiked Amount 50.000 Recovery = 91.50% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 163905 46.89 ug/l 100 3) Chloromethane 1.32 50 147540 43.34 ug/l 99 4) Vinyl Chloride 1.40 62 162846 45.84 ug/l 98 5) Bromomethane 1.64 94 66600 40.29 ug/l 100 6) Chloroethane 1.72 64 104911 44.67 ug/l 100 7) Trichlorofluoromethane 1.93 101 255940 47.87 ug/l 100 8) Diethyl Ether 2.19 74 98605 47.05 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.39 101 154699 49.35 ug/l 99 10) Methyl Iodide 2.51 142 161959 35.81 ug/l 100 11) Tert butyl alcohol 3.07 59 161588 205.37 ug/l 100 12) 1,1-Dichloroethene 2.37 96 134914 46.96 ug/l 99 13) Acrolein 2.29 56 22919 142.75 ug/l 95 14) Allyl chloride 2.73 41 256064 47.80 ug/l 100 15) Acrylonitrile 3.15 53 392741 220.89 ug/l 100 16) Acetone 2.45 43 441994 260.83 ug/l 99 17) Carbon Disulfide 2.57 76 317360 43.40 ug/l 99 18) Methyl Acetate 2.78 43 220782 49.59 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 483387 48.32 ug/l 99 20) Methylene Chloride 2.86 84 150757 44.93 ug/l 98 21) trans-1,2-Dichloroethene 3.17 96 144769 45.15 ug/l 98 22) Diisopropyl ether 3.87 45 495872 49.54 ug/l 98 23) Vinyl Acetate 3.82 43 2061437 247.14 ug/l 100 24) 1,1-Dichloroethane 3.70 63 272970 48.82 ug/l 100 25) 2-Butanone 4.71 43 589413 240.62 ug/l 99 26) 2,2-Dichloropropane 4.59 77 239403 55.45 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 171484 50.22 ug/l 96 28) Bromochloromethane 5.02 49 124977 51.56 ug/l 99 29) Tetrahydrofuran 5.17 42 347347 221.63 ug/l 100 30) Chloroform 5.22 83 292204 50.74 ug/l 97 31) Cyclohexane 5.58 56 237415 49.44 ug/l 98 32) 1,1,1-Trichloroethane 5.50 97 262497 52.15 ug/l 100 36) 1,1-Dichloropropene 5.80 75 212826 52.34 ug/l 99 37) Ethyl Acetate 4.86 43 214259 48.07 ug/l 100 38) Carbon Tetrachloride 5.79 117 236910 54.63 ug/l 99 39) Methylcyclohexane 7.46 83 258158 53.70 ug/l 99 40) Benzene 6.15 78 620966 52.28 ug/l 99 41) Methacrylonitrile 5.07 41 125036 49.03 ug/l 100 42) 1,2-Dichloroethane 6.20 62 236008 51.70 ug/l 100 43) Isopropyl Acetate 6.47 43 349628 51.09 ug/l 100 44) Trichloroethene 7.21 130 193009 53.16 ug/l 99 45) 1,2-Dichloropropane 7.52 63 159287 53.79 ug/l 99 46) Dibromomethane 7.67 93 108461 51.74 ug/l 99 47) Bromodichloromethane 7.90 83 217519 56.07 ug/l 99 48) Methyl methacrylate 7.78 41 189366 50.82 ug/l 98 49) 1,4-Dioxane 7.76 88 70067 870.38 ug/l 98 51) 4-Methyl-2-Pentanone 8.65 43 1142496 251.25 ug/l 100 52) Toluene 8.79 92 416378 53.61 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 253877 57.90 ug/l 98 54) cis-1,3-Dichloropropene 9.04 75 233607 51.47 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 167692 53.60 ug/l 98 56) Ethyl methacrylate 9.18 69 242634 53.80 ug/l 100 57) 1,3-Dichloropropane 9.38 76 266761 51.56 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 618089 279.40 ug/l 100 59) 2-Hexanone 9.50 43 865362 248.52 ug/l 99 60) Dibromochloromethane 9.59 129 179222 55.93 ug/l 100 61) 1,2-Dibromoethane 9.68 107 168916 51.42 ug/l 99 64) Tetrachloroethene 9.34 164 232424 55.75 ug/l 99 65) Chlorobenzene 10.14 112 463164 52.80 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 175409 55.90 ug/l 100 67) Ethyl Benzene 10.26 91 772464 53.73 ug/l 100 68) m/p-Xylenes 10.37 106 619696 109.08 ug/l 99 69) o-Xylene 10.70 106 296816 53.76 ug/l 99 70) Styrene 10.72 104 494683 55.15 ug/l 99 71) Bromoform 10.86 173 143991 47.88 ug/l 100 73) Isopropylbenzene 11.02 105 818344 54.03 ug/l 99 74) N-amyl acetate 6.47 43 349628 50.83 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 224330 50.15 ug/l 100 76) 1,2,3-Trichloropropane 11.30 75 226686m 51.09 ug/l 77) Bromobenzene 11.26 156 225491 51.21 ug/l 99 78) n-propylbenzene 11.37 91 925279 56.10 ug/l 99 79) 2-Chlorotoluene 11.43 91 539553 53.16 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 683738 54.22 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 65559 47.36 ug/l 98 82) 4-Chlorotoluene 11.52 91 626718 53.53 ug/l 99 83) tert-Butylbenzene 11.77 119 678152 54.05 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 705437 54.43 ug/l 99 85) sec-Butylbenzene 11.95 105 846717 56.22 ug/l 99 86) p-Isopropyltoluene 12.07 119 783883 56.74 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 417135 53.00 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 423188 52.71 ug/l 100 89) n-Butylbenzene 12.40 91 652735 57.02 ug/l 100 90) Hexachloroethane 12.60 117 120676 58.01 ug/l 97 91) 1,2-Dichlorobenzene 12.40 146 424074 52.96 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 51295 52.19 ug/l 99 93) 1,2,4-Trichlorobenzene 13.65 180 331951 56.65 ug/l 100 94) Hexachlorobutadiene 13.79 225 180148 56.19 ug/l 99 95) Naphthalene 13.84 128 874370 53.95 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 330782 55.01 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed