Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051218\ Data File : VX001661.D Acq On : 12 May 2018 12:43 Operator : JC/MD Sample : VX0512WBS01 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 4 Sample Multiplier: 1 Quant Time: May 14 06:39:37 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 250642 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 310700 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 292900 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 208838 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 159919 44.39 ug/l 0.00 Spiked Amount 50.000 Recovery = 88.78% 35) Dibromofluoromethane 5.51 113 133210 48.20 ug/l 0.00 Spiked Amount 50.000 Recovery = 96.40% 50) Toluene-d8 8.72 98 468692 46.46 ug/l 0.00 Spiked Amount 50.000 Recovery = 92.92% 62) 4-Bromofluorobenzene 11.14 95 176621 45.61 ug/l 0.00 Spiked Amount 50.000 Recovery = 91.22% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 61292 18.17 ug/l 98 3) Chloromethane 1.32 50 58248 17.73 ug/l 99 4) Vinyl Chloride 1.40 62 62979 18.36 ug/l 97 5) Bromomethane 1.64 94 37129 21.70 ug/l 98 6) Chloroethane 1.73 64 40953 18.07 ug/l 99 7) Trichlorofluoromethane 1.93 101 98347 19.05 ug/l 98 8) Diethyl Ether 2.19 74 38611 19.09 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.39 101 59803 19.76 ug/l 100 10) Methyl Iodide 2.51 142 54817 12.56 ug/l 100 11) Tert butyl alcohol 3.07 59 72156 95.00 ug/l 100 12) 1,1-Dichloroethene 2.37 96 51539 18.58 ug/l 99 13) Acrolein 2.29 56 9302 52.92 ug/l 100 14) Allyl chloride 2.73 41 97918 18.93 ug/l 100 15) Acrylonitrile 3.15 53 159569 92.97 ug/l 99 16) Acetone 2.45 43 160130 97.89 ug/l 100 17) Carbon Disulfide 2.57 76 116302 16.48 ug/l 100 18) Methyl Acetate 2.78 43 90032 20.95 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 188528 19.52 ug/l 98 20) Methylene Chloride 2.86 84 60312 18.62 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 55102 17.80 ug/l 99 22) Diisopropyl ether 3.87 45 184701 19.12 ug/l 98 23) Vinyl Acetate 3.82 43 763779 94.85 ug/l 98 24) 1,1-Dichloroethane 3.70 63 106258 19.69 ug/l 100 25) 2-Butanone 4.71 43 224884 95.10 ug/l 99 26) 2,2-Dichloropropane 4.59 77 87013 20.88 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 64438 19.55 ug/l 98 28) Bromochloromethane 5.03 49 49597 21.20 ug/l 99 29) Tetrahydrofuran 5.17 42 137360 90.79 ug/l 99 30) Chloroform 5.22 83 113482 20.41 ug/l 96 31) Cyclohexane 5.58 56 86925 18.75 ug/l 97 32) 1,1,1-Trichloroethane 5.50 97 97771 20.12 ug/l 99 36) 1,1-Dichloropropene 5.80 75 77310 19.56 ug/l 99 37) Ethyl Acetate 4.87 43 81119 18.72 ug/l 99 38) Carbon Tetrachloride 5.79 117 87297 20.71 ug/l 97 39) Methylcyclohexane 7.46 83 92235 19.74 ug/l 97 40) Benzene 6.15 78 236806 20.51 ug/l 98 41) Methacrylonitrile 5.06 41 48843 19.70 ug/l 99 42) 1,2-Dichloroethane 6.20 62 92611 20.87 ug/l 99 43) Isopropyl Acetate 6.47 43 129566 19.48 ug/l 99 44) Trichloroethene 7.22 130 71974 20.40 ug/l 99 45) 1,2-Dichloropropane 7.52 63 61653 21.42 ug/l 98 46) Dibromomethane 7.67 93 41849 20.54 ug/l 99 47) Bromodichloromethane 7.90 83 80200 21.27 ug/l 99 48) Methyl methacrylate 7.78 41 70068 19.35 ug/l 100 49) 1,4-Dioxane 7.76 88 30316 387.48 ug/l 99 51) 4-Methyl-2-Pentanone 8.65 43 441280 99.85 ug/l 99 52) Toluene 8.79 92 155362 20.58 ug/l 99 53) t-1,3-Dichloropropene 8.44 75 89648 21.04 ug/l 98 54) cis-1,3-Dichloropropene 9.05 75 81195 19.86 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 64889 21.34 ug/l 95 56) Ethyl methacrylate 9.19 69 86791 19.80 ug/l 98 57) 1,3-Dichloropropane 9.38 76 103437 20.57 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 227632 105.87 ug/l 99 59) 2-Hexanone 9.50 43 327975 96.91 ug/l 100 60) Dibromochloromethane 9.59 129 63914 20.52 ug/l 100 61) 1,2-Dibromoethane 9.68 107 63748 19.97 ug/l 100 64) Tetrachloroethene 9.34 164 83799 20.53 ug/l 97 65) Chlorobenzene 10.14 112 174231 20.28 ug/l 98 66) 1,1,1,2-Tetrachloroethane 10.23 131 64645 21.04 ug/l 99 67) Ethyl Benzene 10.26 91 286657 20.36 ug/l 98 68) m/p-Xylenes 10.37 106 228164 41.01 ug/l 99 69) o-Xylene 10.70 106 110912 20.51 ug/l 99 70) Styrene 10.72 104 181367 20.65 ug/l 99 71) Bromoform 10.86 173 49464 19.11 ug/l 99 73) Isopropylbenzene 11.02 105 304552 21.07 ug/l 100 74) N-amyl acetate 6.47 43 129566 19.73 ug/l # 98 75) 1,1,2,2-Tetrachloroethane 11.27 83 87569 20.51 ug/l 100 76) 1,2,3-Trichloropropane 11.30 75 87377m 20.63 ug/l 77) Bromobenzene 11.26 156 84365 20.07 ug/l 99 78) n-propylbenzene 11.37 91 335394 21.30 ug/l 99 79) 2-Chlorotoluene 11.43 91 200880 20.73 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 252260 20.96 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 21792 19.29 ug/l 91 82) 4-Chlorotoluene 11.52 91 233852 20.92 ug/l 100 83) tert-Butylbenzene 11.77 119 250658 20.93 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 261264 21.12 ug/l 100 85) sec-Butylbenzene 11.95 105 306462 21.32 ug/l 99 86) p-Isopropyltoluene 12.07 119 285034 21.61 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 154973 20.63 ug/l 98 88) 1,4-Dichlorobenzene 12.10 146 156848 20.47 ug/l 99 89) n-Butylbenzene 12.40 91 224696 20.56 ug/l 99 90) Hexachloroethane 12.60 117 42268 21.29 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 156513 20.47 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 18910 20.16 ug/l 97 93) 1,2,4-Trichlorobenzene 13.65 180 114642 20.49 ug/l 100 94) Hexachlorobutadiene 13.79 225 63883 20.87 ug/l 100 95) Naphthalene 13.84 128 312616 20.21 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 118765 20.69 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed