Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051218\ Data File : VX001666.D Acq On : 12 May 2018 14:56 Operator : JC/MD Sample : VX0512WBSD01 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 9 Sample Multiplier: 1 Quant Time: May 14 06:53:29 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 235450 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 301741 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 282002 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 197443 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 152816 45.16 ug/l 0.00 Spiked Amount 50.000 Recovery = 90.32% 35) Dibromofluoromethane 5.51 113 126987 47.31 ug/l 0.00 Spiked Amount 50.000 Recovery = 94.62% 50) Toluene-d8 8.72 98 438353 44.74 ug/l 0.00 Spiked Amount 50.000 Recovery = 89.48% 62) 4-Bromofluorobenzene 11.14 95 163140 43.38 ug/l 0.00 Spiked Amount 50.000 Recovery = 86.76% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 58160 18.35 ug/l 100 3) Chloromethane 1.32 50 56060 18.16 ug/l 100 4) Vinyl Chloride 1.40 62 61845 19.20 ug/l 97 5) Bromomethane 1.64 94 36209 22.67 ug/l 97 6) Chloroethane 1.72 64 42321 19.87 ug/l 100 7) Trichlorofluoromethane 1.93 101 94203 19.43 ug/l 99 8) Diethyl Ether 2.19 74 37343 19.65 ug/l 95 9) 1,1,2-Trichlorotrifluoroet 2.39 101 57572 20.25 ug/l 99 10) Methyl Iodide 2.51 142 55685 13.58 ug/l 99 11) Tert butyl alcohol 3.08 59 74287 104.11 ug/l 100 12) 1,1-Dichloroethene 2.37 96 51065 19.60 ug/l 98 13) Acrolein 2.29 56 9800 60.84 ug/l 99 14) Allyl chloride 2.73 41 98895 20.36 ug/l 97 15) Acrylonitrile 3.15 53 165507 102.65 ug/l 99 16) Acetone 2.45 43 174447 113.52 ug/l 100 17) Carbon Disulfide 2.57 76 112173 16.92 ug/l 100 18) Methyl Acetate 2.78 43 92228 22.84 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 185204 20.42 ug/l 96 20) Methylene Chloride 2.86 84 59823 19.66 ug/l 98 21) trans-1,2-Dichloroethene 3.17 96 54368 18.70 ug/l 94 22) Diisopropyl ether 3.88 45 187895 20.70 ug/l 96 23) Vinyl Acetate 3.83 43 758358 100.26 ug/l 99 24) 1,1-Dichloroethane 3.70 63 100333 19.79 ug/l 99 25) 2-Butanone 4.71 43 233752 105.23 ug/l 99 26) 2,2-Dichloropropane 4.59 77 83785 21.40 ug/l 98 27) cis-1,2-Dichloroethene 4.60 96 62800 20.28 ug/l 99 28) Bromochloromethane 5.03 49 49302 22.43 ug/l 97 29) Tetrahydrofuran 5.17 42 138905 97.74 ug/l 99 30) Chloroform 5.22 83 111332 21.32 ug/l 99 31) Cyclohexane 5.58 56 82664 18.98 ug/l 98 32) 1,1,1-Trichloroethane 5.50 97 95758 20.98 ug/l 99 36) 1,1-Dichloropropene 5.81 75 73329 19.10 ug/l 99 37) Ethyl Acetate 4.87 43 84093 19.99 ug/l 99 38) Carbon Tetrachloride 5.79 117 84649 20.68 ug/l 99 39) Methylcyclohexane 7.46 83 85693 18.88 ug/l 98 40) Benzene 6.15 78 230730 20.58 ug/l 100 41) Methacrylonitrile 5.07 41 49025 20.37 ug/l 99 42) 1,2-Dichloroethane 6.20 62 90823 21.08 ug/l 99 43) Isopropyl Acetate 6.47 43 130985 20.28 ug/l 100 44) Trichloroethene 7.22 130 69863 20.39 ug/l 98 45) 1,2-Dichloropropane 7.53 63 58845 21.05 ug/l 100 46) Dibromomethane 7.67 93 40539 20.49 ug/l 98 47) Bromodichloromethane 7.90 83 77444 21.15 ug/l 99 48) Methyl methacrylate 7.79 41 69346 19.72 ug/l 99 49) 1,4-Dioxane 7.76 88 30256 398.19 ug/l 98 51) 4-Methyl-2-Pentanone 8.66 43 450529 104.97 ug/l 99 52) Toluene 8.79 92 151155 20.62 ug/l 99 53) t-1,3-Dichloropropene 8.44 75 87534 21.15 ug/l 97 54) cis-1,3-Dichloropropene 9.05 75 78484 19.78 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 63454 21.49 ug/l 98 56) Ethyl methacrylate 9.19 69 86571 20.34 ug/l 100 57) 1,3-Dichloropropane 9.38 76 101597 20.81 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 224108 107.33 ug/l 99 59) 2-Hexanone 9.51 43 336778 102.47 ug/l 99 60) Dibromochloromethane 9.59 129 62110 20.54 ug/l 99 61) 1,2-Dibromoethane 9.68 107 63243 20.40 ug/l 99 64) Tetrachloroethene 9.34 164 81598 20.76 ug/l 97 65) Chlorobenzene 10.14 112 170332 20.60 ug/l 97 66) 1,1,1,2-Tetrachloroethane 10.23 131 63273 21.39 ug/l 100 67) Ethyl Benzene 10.26 91 272392 20.09 ug/l 100 68) m/p-Xylenes 10.37 106 218836 40.86 ug/l 100 69) o-Xylene 10.71 106 107790 20.71 ug/l 100 70) Styrene 10.72 104 174298 20.61 ug/l 100 71) Bromoform 10.86 173 48930 19.54 ug/l 99 73) Isopropylbenzene 11.02 105 291771 21.35 ug/l 99 74) N-amyl acetate 6.47 43 130985 21.10 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 87483 21.67 ug/l 98 76) 1,2,3-Trichloropropane 11.30 75 84769m 21.17 ug/l 77) Bromobenzene 11.26 156 82993 20.88 ug/l 98 78) n-propylbenzene 11.37 91 316466 21.26 ug/l 98 79) 2-Chlorotoluene 11.43 91 192504 21.02 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 239769 21.07 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 20856 19.47 ug/l 90 82) 4-Chlorotoluene 11.52 91 219673 20.79 ug/l 100 83) tert-Butylbenzene 11.77 119 237239 20.95 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 249671 21.35 ug/l 99 85) sec-Butylbenzene 11.95 105 289770 21.32 ug/l 100 86) p-Isopropyltoluene 12.07 119 264974 21.25 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 145474 20.48 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 148523 20.50 ug/l 99 89) n-Butylbenzene 12.40 91 206361 19.98 ug/l 99 90) Hexachloroethane 12.60 117 40036 21.33 ug/l 98 91) 1,2-Dichlorobenzene 12.40 146 150674 20.85 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 18825 21.22 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 104944 19.84 ug/l 99 94) Hexachlorobutadiene 13.79 225 58392 20.18 ug/l 100 95) Naphthalene 13.84 128 304124 20.79 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 113867 20.98 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed