Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051218\ Data File : VX001678.D Acq On : 12 May 2018 20:16 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 21 Sample Multiplier: 1 Quant Time: May 14 07:24:19 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 238001 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 306778 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 288603 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 206404 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 145789 42.62 ug/l 0.00 Spiked Amount 50.000 Recovery = 85.24% 35) Dibromofluoromethane 5.51 113 124516 45.63 ug/l 0.00 Spiked Amount 50.000 Recovery = 91.26% 50) Toluene-d8 8.72 98 436517 43.83 ug/l 0.00 Spiked Amount 50.000 Recovery = 87.66% 62) 4-Bromofluorobenzene 11.14 95 162743 42.56 ug/l 0.00 Spiked Amount 50.000 Recovery = 85.12% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 142623 44.52 ug/l 99 3) Chloromethane 1.32 50 139866 44.82 ug/l 98 4) Vinyl Chloride 1.40 62 149781 45.99 ug/l 98 5) Bromomethane 1.64 94 58177 38.22 ug/l 97 6) Chloroethane 1.72 64 101053 46.95 ug/l 99 7) Trichlorofluoromethane 1.93 101 233114 47.57 ug/l 100 8) Diethyl Ether 2.19 74 93144 48.49 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.39 101 138253 48.12 ug/l 100 10) Methyl Iodide 2.51 142 163980 39.55 ug/l 99 11) Tert butyl alcohol 3.08 59 175335 243.10 ug/l 100 12) 1,1-Dichloroethene 2.37 96 124831 47.40 ug/l 98 13) Acrolein 2.30 56 22813 156.07 ug/l 95 14) Allyl chloride 2.73 41 242366 49.36 ug/l 97 15) Acrylonitrile 3.15 53 402488 246.96 ug/l 99 16) Acetone 2.45 43 353750 227.74 ug/l 98 17) Carbon Disulfide 2.57 76 285631 42.62 ug/l 100 18) Methyl Acetate 2.78 43 225921 55.36 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 454902 49.61 ug/l 99 20) Methylene Chloride 2.86 84 145556 47.33 ug/l 100 21) trans-1,2-Dichloroethene 3.17 96 134162 45.65 ug/l 98 22) Diisopropyl ether 3.88 45 468491 51.06 ug/l 99 23) Vinyl Acetate 3.83 43 1907400 249.46 ug/l 100 24) 1,1-Dichloroethane 3.70 63 249057 48.60 ug/l 100 25) 2-Butanone 4.71 43 547041 243.63 ug/l 98 26) 2,2-Dichloropropane 4.59 77 183552 46.38 ug/l 98 27) cis-1,2-Dichloroethene 4.60 96 155859 49.79 ug/l 96 28) Bromochloromethane 5.03 49 116970 52.64 ug/l 99 29) Tetrahydrofuran 5.17 42 352545 245.40 ug/l 99 30) Chloroform 5.22 83 276622 52.40 ug/l 98 31) Cyclohexane 5.58 56 210131 47.74 ug/l 96 32) 1,1,1-Trichloroethane 5.50 97 242280 52.51 ug/l 100 36) 1,1-Dichloropropene 5.80 75 188018 48.18 ug/l 100 37) Ethyl Acetate 4.87 43 208223 48.68 ug/l 100 38) Carbon Tetrachloride 5.79 117 218069 52.40 ug/l 99 39) Methylcyclohexane 7.46 83 217945 47.24 ug/l 99 40) Benzene 6.15 78 581659 51.03 ug/l 98 41) Methacrylonitrile 5.07 41 123512 50.47 ug/l 99 42) 1,2-Dichloroethane 6.20 62 221236 50.50 ug/l 100 43) Isopropyl Acetate 6.47 43 335325 51.06 ug/l 99 44) Trichloroethene 7.21 130 176220 50.58 ug/l 99 45) 1,2-Dichloropropane 7.52 63 147809 52.02 ug/l 100 46) Dibromomethane 7.67 93 101585 50.50 ug/l 99 47) Bromodichloromethane 7.90 83 203891 54.77 ug/l 100 48) Methyl methacrylate 7.79 41 181441 50.74 ug/l 98 49) 1,4-Dioxane 7.76 88 76394 988.89 ug/l 98 51) 4-Methyl-2-Pentanone 8.66 43 1137468 260.67 ug/l 99 52) Toluene 8.79 92 388462 52.12 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 229750 54.61 ug/l 96 54) cis-1,3-Dichloropropene 9.05 75 208644 48.06 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 154835 51.57 ug/l 97 56) Ethyl methacrylate 9.19 69 222718 51.46 ug/l 97 57) 1,3-Dichloropropane 9.38 76 253000 50.96 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 567497 267.32 ug/l 99 59) 2-Hexanone 9.51 43 830596 248.57 ug/l 99 60) Dibromochloromethane 9.59 129 167813 54.58 ug/l 100 61) 1,2-Dibromoethane 9.68 107 161477 51.22 ug/l 100 64) Tetrachloroethene 9.34 164 202092 50.24 ug/l 99 65) Chlorobenzene 10.15 112 431564 50.99 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 162371 53.63 ug/l 98 67) Ethyl Benzene 10.26 91 707276 50.98 ug/l 99 68) m/p-Xylenes 10.37 106 564854 103.04 ug/l 99 69) o-Xylene 10.71 106 276543 51.91 ug/l 100 70) Styrene 10.72 104 462047 53.39 ug/l 98 71) Bromoform 10.87 173 135607 46.82 ug/l 100 73) Isopropylbenzene 11.02 105 739824 51.78 ug/l 99 74) N-amyl acetate 6.47 43 335325 51.67 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 221691 52.53 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 215427m 51.46 ug/l 77) Bromobenzene 11.26 156 209266 50.37 ug/l 99 78) n-propylbenzene 11.37 91 820533 52.73 ug/l 99 79) 2-Chlorotoluene 11.43 91 492935 51.48 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 617629 51.92 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 58053 44.71 ug/l 98 82) 4-Chlorotoluene 11.52 91 568224 51.44 ug/l 99 83) tert-Butylbenzene 11.77 119 615347 51.98 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 637828 52.17 ug/l 99 85) sec-Butylbenzene 11.95 105 756231 53.23 ug/l 99 86) p-Isopropyltoluene 12.07 119 686756 52.69 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 377454 50.83 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 378086 49.92 ug/l 99 89) n-Butylbenzene 12.40 91 553772 51.28 ug/l 100 90) Hexachloroethane 12.60 117 111308 56.71 ug/l 100 91) 1,2-Dichlorobenzene 12.40 146 389555 51.56 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 49549 53.44 ug/l 97 93) 1,2,4-Trichlorobenzene 13.65 180 288655 52.21 ug/l 100 94) Hexachlorobutadiene 13.79 225 151462 50.07 ug/l 99 95) Naphthalene 13.84 128 831278 54.37 ug/l 99 96) 1,2,3-Trichlorobenzene 14.02 180 297450 52.43 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed