Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051218\ Data File : VX001680.D Acq On : 12 May 2018 21:35 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 24 Sample Multiplier: 1 Quant Time: May 14 07:25:06 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 223595 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 289461 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 271614 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 194160 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 145532 45.28 ug/l 0.00 Spiked Amount 50.000 Recovery = 90.56% 35) Dibromofluoromethane 5.51 113 123153 47.83 ug/l 0.00 Spiked Amount 50.000 Recovery = 95.66% 50) Toluene-d8 8.72 98 433177 46.09 ug/l 0.00 Spiked Amount 50.000 Recovery = 92.18% 62) 4-Bromofluorobenzene 11.14 95 161341 44.72 ug/l 0.00 Spiked Amount 50.000 Recovery = 89.44% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 142668 47.40 ug/l 99 3) Chloromethane 1.32 50 135498 46.22 ug/l 99 4) Vinyl Chloride 1.40 62 147925 48.35 ug/l 99 5) Bromomethane 1.64 94 59101 41.63 ug/l 99 6) Chloroethane 1.72 64 99683 49.29 ug/l 99 7) Trichlorofluoromethane 1.93 101 232890 50.58 ug/l 100 8) Diethyl Ether 2.19 74 92936 51.50 ug/l 97 9) 1,1,2-Trichlorotrifluoroet 2.39 101 137633 50.99 ug/l 99 10) Methyl Iodide 2.51 142 166690 42.80 ug/l 99 11) Tert butyl alcohol 3.09 59 170734 251.97 ug/l 99 12) 1,1-Dichloroethene 2.37 96 125383 50.68 ug/l 99 13) Acrolein 2.30 56 23074 168.96 ug/l 96 14) Allyl chloride 2.73 41 240796 52.20 ug/l 97 15) Acrylonitrile 3.15 53 400712 261.71 ug/l 99 16) Acetone 2.45 43 350130 239.93 ug/l 99 17) Carbon Disulfide 2.57 76 285249 45.30 ug/l 99 18) Methyl Acetate 2.78 43 224829 58.64 ug/l 98 19) Methyl tert-butyl Ether 3.21 73 453413 52.64 ug/l 97 20) Methylene Chloride 2.86 84 145531 50.37 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 133270 48.27 ug/l 98 22) Diisopropyl ether 3.88 45 468547 54.36 ug/l 99 23) Vinyl Acetate 3.83 43 1887166 262.72 ug/l 100 24) 1,1-Dichloroethane 3.70 63 250369 52.00 ug/l 99 25) 2-Butanone 4.71 43 543121 257.47 ug/l 99 26) 2,2-Dichloropropane 4.59 77 180099 48.44 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 157207 53.46 ug/l 94 28) Bromochloromethane 5.03 49 115363 55.26 ug/l 100 29) Tetrahydrofuran 5.17 42 348584 258.27 ug/l 100 30) Chloroform 5.22 83 274728 55.39 ug/l 96 31) Cyclohexane 5.57 56 211503 51.15 ug/l 96 32) 1,1,1-Trichloroethane 5.50 97 240763 55.54 ug/l 99 36) 1,1-Dichloropropene 5.81 75 188840 51.29 ug/l 100 37) Ethyl Acetate 4.87 43 208819 51.74 ug/l 100 38) Carbon Tetrachloride 5.79 117 217183 55.31 ug/l 99 39) Methylcyclohexane 7.46 83 219648 50.46 ug/l 97 40) Benzene 6.15 78 582606 54.17 ug/l 98 41) Methacrylonitrile 5.07 41 120495 52.18 ug/l 98 42) 1,2-Dichloroethane 6.20 62 222430 53.81 ug/l 100 43) Isopropyl Acetate 6.47 43 329116 53.12 ug/l 99 44) Trichloroethene 7.22 130 176096 53.57 ug/l 99 45) 1,2-Dichloropropane 7.52 63 146615 54.68 ug/l 99 46) Dibromomethane 7.67 93 102384 53.94 ug/l 98 47) Bromodichloromethane 7.90 83 202673 57.70 ug/l 98 48) Methyl methacrylate 7.78 41 179042 53.07 ug/l 98 49) 1,4-Dioxane 7.76 88 76318 1047.01 ug/l 99 51) 4-Methyl-2-Pentanone 8.66 43 1127268 273.78 ug/l 98 52) Toluene 8.79 92 385952 54.88 ug/l 99 53) t-1,3-Dichloropropene 8.44 75 226098 56.95 ug/l 98 54) cis-1,3-Dichloropropene 9.05 75 206134 50.21 ug/l 97 55) 1,1,2-Trichloroethane 9.22 97 153981 54.35 ug/l 98 56) Ethyl methacrylate 9.19 69 219712 53.80 ug/l 97 57) 1,3-Dichloropropane 9.38 76 251267 53.64 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 573649 286.39 ug/l 100 59) 2-Hexanone 9.51 43 825772 261.91 ug/l 100 60) Dibromochloromethane 9.59 129 165040 56.89 ug/l 99 61) 1,2-Dibromoethane 9.68 107 159356 53.57 ug/l 100 64) Tetrachloroethene 9.34 164 204891 54.12 ug/l 97 65) Chlorobenzene 10.15 112 427866 53.71 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 163550 57.40 ug/l 99 67) Ethyl Benzene 10.26 91 704583 53.97 ug/l 99 68) m/p-Xylenes 10.37 106 560753 108.70 ug/l 99 69) o-Xylene 10.70 106 274775 54.80 ug/l 99 70) Styrene 10.72 104 460597 56.55 ug/l 99 71) Bromoform 10.87 173 134057 49.00 ug/l 99 73) Isopropylbenzene 11.02 105 742689 55.25 ug/l 100 74) N-amyl acetate 6.47 43 329116 53.91 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 217028 54.67 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 182959m 46.46 ug/l 77) Bromobenzene 11.26 156 209166 53.53 ug/l 100 78) n-propylbenzene 11.37 91 818259 55.90 ug/l 100 79) 2-Chlorotoluene 11.43 91 490455 54.45 ug/l 98 80) 1,3,5-Trimethylbenzene 11.51 105 616693 55.11 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 56523 46.13 ug/l 98 82) 4-Chlorotoluene 11.52 91 569683 54.83 ug/l 100 83) tert-Butylbenzene 11.77 119 611583 54.92 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 638887 55.55 ug/l 100 85) sec-Butylbenzene 11.95 105 753365 56.37 ug/l 100 86) p-Isopropyltoluene 12.07 119 688309 56.14 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 378083 54.12 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 380031 53.34 ug/l 100 89) n-Butylbenzene 12.39 91 556061 54.74 ug/l 100 90) Hexachloroethane 12.60 117 109012 59.05 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 389991 54.87 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 48501 55.61 ug/l 97 93) 1,2,4-Trichlorobenzene 13.65 180 286284 55.05 ug/l 99 94) Hexachlorobutadiene 13.79 225 152501 53.59 ug/l 99 95) Naphthalene 13.84 128 823466 57.25 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 299832 56.19 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed