Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051218\ Data File : VX001682.D Acq On : 12 May 2018 22:28 Operator : JC/MD Sample : VX0512WBS02 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 26 Sample Multiplier: 1 Quant Time: May 14 07:27:02 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 221748 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 288964 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 268655 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 187061 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 149684 46.96 ug/l 0.00 Spiked Amount 50.000 Recovery = 93.92% 35) Dibromofluoromethane 5.51 113 125740 48.92 ug/l 0.00 Spiked Amount 50.000 Recovery = 97.84% 50) Toluene-d8 8.72 98 434317 46.29 ug/l 0.00 Spiked Amount 50.000 Recovery = 92.58% 62) 4-Bromofluorobenzene 11.14 95 161394 44.81 ug/l 0.00 Spiked Amount 50.000 Recovery = 89.62% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 56877 19.05 ug/l 99 3) Chloromethane 1.32 50 53446 18.38 ug/l 99 4) Vinyl Chloride 1.40 62 58984 19.44 ug/l 98 5) Bromomethane 1.64 94 33350 22.09 ug/l 99 6) Chloroethane 1.73 64 39285 19.59 ug/l 95 7) Trichlorofluoromethane 1.93 101 90792 19.88 ug/l 98 8) Diethyl Ether 2.19 74 36729 20.52 ug/l 97 9) 1,1,2-Trichlorotrifluoroet 2.39 101 53852 20.12 ug/l 100 10) Methyl Iodide 2.51 142 59594 15.43 ug/l 98 11) Tert butyl alcohol 3.07 59 73784 109.80 ug/l 100 12) 1,1-Dichloroethene 2.37 96 48767 19.87 ug/l 99 13) Acrolein 2.30 56 9319 61.55 ug/l 98 14) Allyl chloride 2.73 41 92825 20.29 ug/l 97 15) Acrylonitrile 3.15 53 158667 104.49 ug/l 100 16) Acetone 2.45 43 143180 98.93 ug/l 99 17) Carbon Disulfide 2.57 76 106209 17.01 ug/l 99 18) Methyl Acetate 2.78 43 89973 23.66 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 178396 20.88 ug/l 98 20) Methylene Chloride 2.86 84 57873 20.20 ug/l 97 21) trans-1,2-Dichloroethene 3.17 96 51869 18.94 ug/l 98 22) Diisopropyl ether 3.88 45 178270 20.86 ug/l 99 23) Vinyl Acetate 3.83 43 715537 100.44 ug/l 99 24) 1,1-Dichloroethane 3.70 63 96826 20.28 ug/l 99 25) 2-Butanone 4.71 43 213983 102.29 ug/l 99 26) 2,2-Dichloropropane 4.59 77 64272 17.43 ug/l 97 27) cis-1,2-Dichloroethene 4.60 96 60392 20.71 ug/l 96 28) Bromochloromethane 5.03 49 48016 23.19 ug/l 98 29) Tetrahydrofuran 5.17 42 135091 100.93 ug/l 99 30) Chloroform 5.22 83 105231 21.39 ug/l 95 31) Cyclohexane 5.58 56 78278 19.09 ug/l 100 32) 1,1,1-Trichloroethane 5.50 97 91424 21.27 ug/l 99 36) 1,1-Dichloropropene 5.80 75 69773 18.98 ug/l 99 37) Ethyl Acetate 4.87 43 81952 20.34 ug/l 100 38) Carbon Tetrachloride 5.79 117 79172 20.20 ug/l 98 39) Methylcyclohexane 7.47 83 79067 18.19 ug/l 99 40) Benzene 6.15 78 222757 20.75 ug/l 99 41) Methacrylonitrile 5.07 41 46570 20.20 ug/l 99 42) 1,2-Dichloroethane 6.21 62 87350 21.17 ug/l 100 43) Isopropyl Acetate 6.47 43 124112 20.07 ug/l 99 44) Trichloroethene 7.22 130 67117 20.45 ug/l 98 45) 1,2-Dichloropropane 7.52 63 56072 20.95 ug/l 100 46) Dibromomethane 7.66 93 39561 20.88 ug/l 99 47) Bromodichloromethane 7.90 83 74816 21.33 ug/l 98 48) Methyl methacrylate 7.79 41 67306 19.98 ug/l 98 49) 1,4-Dioxane 7.76 88 29416 404.25 ug/l 97 51) 4-Methyl-2-Pentanone 8.66 43 431932 105.09 ug/l 99 52) Toluene 8.79 92 144076 20.52 ug/l 98 53) t-1,3-Dichloropropene 8.44 75 80460 20.30 ug/l 97 54) cis-1,3-Dichloropropene 9.05 75 70579 18.71 ug/l 100 55) 1,1,2-Trichloroethane 9.22 97 60161 21.27 ug/l 98 56) Ethyl methacrylate 9.19 69 80430 19.73 ug/l 98 57) 1,3-Dichloropropane 9.38 76 97345 20.82 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 218545 109.29 ug/l 99 59) 2-Hexanone 9.50 43 314298 99.86 ug/l 100 60) Dibromochloromethane 9.59 129 58861 20.32 ug/l 99 61) 1,2-Dibromoethane 9.68 107 60645 20.42 ug/l 99 64) Tetrachloroethene 9.34 164 76416 20.41 ug/l 99 65) Chlorobenzene 10.15 112 161381 20.48 ug/l 98 66) 1,1,1,2-Tetrachloroethane 10.23 131 60325 21.40 ug/l 100 67) Ethyl Benzene 10.26 91 259247 20.07 ug/l 98 68) m/p-Xylenes 10.37 106 208512 40.86 ug/l 100 69) o-Xylene 10.71 106 101699 20.51 ug/l 99 70) Styrene 10.72 104 165376 20.53 ug/l 99 71) Bromoform 10.87 173 45770 19.25 ug/l # 99 73) Isopropylbenzene 11.02 105 275279 21.26 ug/l 100 74) N-amyl acetate 6.47 43 124112 21.10 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 83768 21.90 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 79938m 21.07 ug/l 77) Bromobenzene 11.26 156 79169 21.03 ug/l 99 78) n-propylbenzene 11.37 91 299150 21.21 ug/l 99 79) 2-Chlorotoluene 11.43 91 184163 21.22 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 227005 21.05 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 19101 18.96 ug/l 88 82) 4-Chlorotoluene 11.52 91 210921 21.07 ug/l 100 83) tert-Butylbenzene 11.77 119 222647 20.75 ug/l 98 84) 1,2,4-Trimethylbenzene 11.81 105 236144 21.31 ug/l 100 85) sec-Butylbenzene 11.95 105 271433 21.08 ug/l 99 86) p-Isopropyltoluene 12.07 119 244303 20.68 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 139418 20.72 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 141872 20.67 ug/l 99 89) n-Butylbenzene 12.40 91 189126 19.32 ug/l 100 90) Hexachloroethane 12.60 117 36987 20.79 ug/l 100 91) 1,2-Dichlorobenzene 12.40 146 143858 21.01 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 18280 21.75 ug/l 99 93) 1,2,4-Trichlorobenzene 13.65 180 100550 20.07 ug/l 100 94) Hexachlorobutadiene 13.79 225 54951 20.04 ug/l 99 95) Naphthalene 13.84 128 289775 20.91 ug/l 100 96) 1,2,3-Trichlorobenzene 14.03 180 106993 20.81 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed