Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051218\ Data File : VX001683.D Acq On : 12 May 2018 22:55 Operator : JC/MD Sample : VX0512WBSD02 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 27 Sample Multiplier: 1 Quant Time: May 14 07:27:29 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 217931 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 283187 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 264437 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 184194 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 147949 47.23 ug/l 0.00 Spiked Amount 50.000 Recovery = 94.46% 35) Dibromofluoromethane 5.51 113 123486 49.02 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.04% 50) Toluene-d8 8.72 98 429687 46.73 ug/l 0.00 Spiked Amount 50.000 Recovery = 93.46% 62) 4-Bromofluorobenzene 11.14 95 156777 44.42 ug/l 0.00 Spiked Amount 50.000 Recovery = 88.84% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 54859 18.70 ug/l 99 3) Chloromethane 1.32 50 53011 18.55 ug/l 97 4) Vinyl Chloride 1.40 62 58716 19.69 ug/l 99 5) Bromomethane 1.64 94 31944 21.44 ug/l 98 6) Chloroethane 1.73 64 38370 19.47 ug/l 94 7) Trichlorofluoromethane 1.93 101 90296 20.12 ug/l 97 8) Diethyl Ether 2.19 74 36597 20.81 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.39 101 52938 20.12 ug/l 100 10) Methyl Iodide 2.51 142 59560 15.69 ug/l 99 11) Tert butyl alcohol 3.08 59 77666 117.60 ug/l 100 12) 1,1-Dichloroethene 2.38 96 48036 19.92 ug/l 94 13) Acrolein 2.29 56 9525 64.50 ug/l 94 14) Allyl chloride 2.73 41 90177 20.06 ug/l 97 15) Acrylonitrile 3.15 53 161085 107.94 ug/l 100 16) Acetone 2.45 43 144156 101.35 ug/l 98 17) Carbon Disulfide 2.57 76 104316 17.00 ug/l 99 18) Methyl Acetate 2.78 43 90605 24.25 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 177244 21.11 ug/l 98 20) Methylene Chloride 2.86 84 55928 19.86 ug/l 96 21) trans-1,2-Dichloroethene 3.17 96 50692 18.84 ug/l 99 22) Diisopropyl ether 3.88 45 177159 21.09 ug/l 99 23) Vinyl Acetate 3.83 43 719197 102.72 ug/l 99 24) 1,1-Dichloroethane 3.70 63 95344 20.32 ug/l 99 25) 2-Butanone 4.71 43 219984 107.00 ug/l 98 26) 2,2-Dichloropropane 4.59 77 62793 17.33 ug/l 97 27) cis-1,2-Dichloroethene 4.60 96 59915 20.90 ug/l 95 28) Bromochloromethane 5.03 49 47021 23.11 ug/l 99 29) Tetrahydrofuran 5.17 42 138579 105.35 ug/l 99 30) Chloroform 5.22 83 103640 21.44 ug/l 99 31) Cyclohexane 5.58 56 78242 19.41 ug/l 96 32) 1,1,1-Trichloroethane 5.50 97 88934 21.05 ug/l 99 36) 1,1-Dichloropropene 5.81 75 69990 19.43 ug/l 99 37) Ethyl Acetate 4.87 43 83282 21.09 ug/l 100 38) Carbon Tetrachloride 5.79 117 77910 20.28 ug/l 98 39) Methylcyclohexane 7.46 83 77532 18.21 ug/l 94 40) Benzene 6.15 78 217600 20.68 ug/l 99 41) Methacrylonitrile 5.07 41 47944 21.22 ug/l 99 42) 1,2-Dichloroethane 6.20 62 85660 21.18 ug/l 100 43) Isopropyl Acetate 6.47 43 126325 20.84 ug/l 99 44) Trichloroethene 7.22 130 65102 20.24 ug/l 97 45) 1,2-Dichloropropane 7.52 63 55415 21.13 ug/l 99 46) Dibromomethane 7.67 93 39329 21.18 ug/l 99 47) Bromodichloromethane 7.90 83 73659 21.43 ug/l 98 48) Methyl methacrylate 7.79 41 67463 20.44 ug/l 99 49) 1,4-Dioxane 7.76 88 30446 426.94 ug/l 98 51) 4-Methyl-2-Pentanone 8.66 43 440713 109.41 ug/l 99 52) Toluene 8.79 92 143796 20.90 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 80420 20.71 ug/l 100 54) cis-1,3-Dichloropropene 9.05 75 71226 19.20 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 58899 21.25 ug/l 98 56) Ethyl methacrylate 9.19 69 79456 19.89 ug/l 99 57) 1,3-Dichloropropane 9.38 76 96316 21.02 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 217512 111.00 ug/l 100 59) 2-Hexanone 9.50 43 322617 104.59 ug/l 100 60) Dibromochloromethane 9.59 129 59186 20.85 ug/l 100 61) 1,2-Dibromoethane 9.68 107 60385 20.75 ug/l 99 64) Tetrachloroethene 9.34 164 75480 20.48 ug/l 98 65) Chlorobenzene 10.15 112 159794 20.60 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 59413 21.42 ug/l 99 67) Ethyl Benzene 10.26 91 256547 20.18 ug/l 99 68) m/p-Xylenes 10.37 106 204210 40.66 ug/l 100 69) o-Xylene 10.70 106 100945 20.68 ug/l 99 70) Styrene 10.72 104 163569 20.63 ug/l 99 71) Bromoform 10.86 173 46153 19.63 ug/l # 100 73) Isopropylbenzene 11.02 105 269645 21.15 ug/l 100 74) N-amyl acetate 6.47 43 126325 21.81 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 83227 22.10 ug/l 100 76) 1,2,3-Trichloropropane 11.30 75 82613m 22.11 ug/l 77) Bromobenzene 11.26 156 77359 20.87 ug/l 98 78) n-propylbenzene 11.37 91 294888 21.24 ug/l 99 79) 2-Chlorotoluene 11.43 91 180645 21.14 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 222470 20.96 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 18385 18.63 ug/l 93 82) 4-Chlorotoluene 11.52 91 205792 20.88 ug/l 99 83) tert-Butylbenzene 11.77 119 219689 20.80 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 230960 21.17 ug/l 100 85) sec-Butylbenzene 11.95 105 265037 20.90 ug/l 100 86) p-Isopropyltoluene 12.07 119 244981 21.06 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 137437 20.74 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 140191 20.74 ug/l 99 89) n-Butylbenzene 12.40 91 186957 19.40 ug/l 99 90) Hexachloroethane 12.60 117 36809 21.02 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 141556 21.00 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 18181 21.97 ug/l 100 93) 1,2,4-Trichlorobenzene 13.65 180 99526 20.17 ug/l 99 94) Hexachlorobutadiene 13.79 225 53321 19.75 ug/l 99 95) Naphthalene 13.84 128 288611 21.15 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 105399 20.82 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed