Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051418\ Data File : VX001706.D Acq On : 14 May 2018 11:14 Operator : JC/MD Sample : VSTDCCC020 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 2 Sample Multiplier: 1 Quant Time: May 16 03:13:07 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\624X051118W.M Quant Title : METHOD 624 VOLATILE ORGANIC ANALYSIS QLast Update : Fri May 11 07:16:13 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane 5.02 128 61355 30.00 ug/l 0.00 28) 1,4-Difluorobenzene 6.87 114 327253 30.00 ug/l 0.00 57) Chlorobenzene-d5 10.12 117 307403 30.00 ug/l 0.00 System Monitoring Compounds 27) 1,2-Dichloroethane-d4 6.07 65 128306 28.66 ug/l -0.01 Spiked Amount 30.000 Range 50 - 169 Recovery = 95.53% 60) 4-Bromofluorobenzene 11.14 95 139973 28.77 ug/l 0.00 Spiked Amount 30.000 Range 56 - 143 Recovery = 95.90% 63) Toluene-d8 8.72 98 404012 29.47 ug/l 0.00 Spiked Amount 30.000 Range 66 - 137 Recovery = 98.23% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 79502 26.59 ug/l 99 3) Chloromethane 1.32 50 77797 23.50 ug/l 99 4) Vinyl Chloride 1.41 62 80857 23.40 ug/l 98 5) Bromomethane 1.65 94 43682 25.57 ug/l 97 6) Chloroethane 1.73 64 50466 21.93 ug/l 92 7) Trichlorofluoromethane 1.93 101 124669 25.11 ug/l 100 8) Diethyl Ether 2.19 74 46937 21.80 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.39 101 76449 27.71 ug/l 98 10) 1,1-Dichloroethene 2.38 96 67315 23.71 ug/l 98 11) Methyl Iodide 2.51 142 87210 21.14 ug/l 99 12) Methyl Acetate 2.78 43 92619 19.18 ug/l 99 13) Acrolein 2.29 56 53182 97.14 ug/l 99 14) Acrylonitrile 3.15 53 186084 96.48 ug/l 99 15) Acetone 2.45 58 55364 106.85 ug/l 98 16) Carbon Disulfide 2.57 76 170409 24.23 ug/l 99 17) Allyl chloride 2.73 41 124541 22.99 ug/l 95 18) Methylene Chloride 2.86 84 74633 22.27 ug/l 95 19) trans-1,2-Dichloroethene 3.17 96 72094 23.39 ug/l 98 20) Diisopropyl ether 3.87 45 233334 23.06 ug/l 97 21) 1,1-Dichloroethane 3.70 63 131977 22.68 ug/l 98 22) cis-1,2-Dichloroethene 4.60 96 81716 23.51 ug/l 97 23) tert-Butyl Alcohol 3.06 59 77640 90.47 ug/l # 100 24) Methyl tert-Butyl Ether 3.20 73 221682 21.49 ug/l 99 25) Chloroform 5.21 83 137001 22.85 ug/l 96 26) Cyclohexane 5.58 56 117582 27.69 ug/l # 100 29) 1,1-Dichloropropene 5.80 75 100583 24.47 ug/l 98 30) 2-Butanone 4.70 43 257204 94.81 ug/l 100 31) 2,2-Dichloropropane 4.59 77 109395 30.95 ug/l 97 32) 1,1,1-Trichloroethane 5.49 97 121661 23.27 ug/l 99 33) Carbon Tetrachloride 5.79 117 110796 24.06 ug/l 100 34) Benzene 6.15 78 300045 22.82 ug/l 98 35) Methacrylonitrile 5.06 41 55440 18.85 ug/l 96 36) 1,2-Dichloroethane 6.20 62 111549 21.45 ug/l 99 37) Trichloroethene 7.21 130 94854 24.48 ug/l 98 38) Methylcyclohexane 7.46 83 125590 28.57 ug/l 99 39) 1,2-Dichloropropane 7.52 63 73432 22.28 ug/l 99 40) Dibromomethane 7.67 93 51390 21.76 ug/l 97 41) Bromodichloromethane 7.90 83 98305 22.13 ug/l 98 42) Vinyl Acetate 3.82 43 966431 108.00 ug/l 99 43) Ethyl Acetate 4.85 43 98126 18.98 ug/l 98 44) Isopropyl Acetate 6.47 43 154275 19.48 ug/l 99 45) 1,4-Dioxane 7.76 88 34739 374.17 ug/l 98 46) Methyl methacrylate 7.78 41 83098 19.43 ug/l 96 47) n-amyl Acetate 10.90 43 129496 19.15 ug/l 98 48) t-1,3-Dichloropropene 8.44 75 114686 23.39 ug/l 99 49) cis-1,3-Dichloropropene 9.04 75 103937 23.99 ug/l 98 50) 1,1,2-Trichloroethane 9.22 97 78523 22.46 ug/l 98 51) Ethyl methacrylate 9.18 69 104238 20.68 ug/l 98 52) 1,3-Dichloropropane 9.38 76 129678 22.51 ug/l 98 53) Dibromochloromethane 9.59 129 77616 21.37 ug/l 99 54) 1,2-Dibromoethane 9.68 107 77543 21.02 ug/l 99 55) 2-Chloroethyl vinyl ether 8.32 63 242121 90.34 ug/l 100 56) Bromoform 10.86 173 59889 20.17 ug/l 98 58) 4-Methyl-2-Pentanone 8.65 43 506242 91.56 ug/l 99 59) 2-Hexanone 9.50 43 386649 93.34 ug/l 100 61) Tetrachloroethene 9.34 164 114752 25.66 ug/l 100 62) Toluene 8.79 91 340013 22.99 ug/l 100 64) Chlorobenzene 10.14 112 228739 23.54 ug/l 99 65) 1,1,1,2-Tetrachloroethane 10.23 131 83890 22.85 ug/l 100 66) Ethyl Benzene 10.26 91 375014 24.44 ug/l 99 67) m/p-Xylenes 10.37 106 305161 49.80 ug/l 99 68) o-Xylene 10.70 106 143615 23.69 ug/l 99 69) Styrene 10.71 104 238587 23.85 ug/l 99 70) Isopropylbenzene 11.02 105 369778 23.68 ug/l 100 71) 1,1,2,2-Tetrachloroethane 11.27 83 98221 18.75 ug/l 100 72) 1,2,3-Trichloropropane 11.30 75 99731m 19.65 ug/l 73) Bromobenzene 11.26 156 103552 21.88 ug/l 99 74) n-propylbenzene 11.37 91 426270 24.79 ug/l 100 75) 2-Chlorotoluene 11.43 91 248743 23.07 ug/l 99 76) 1,3,5-Trimethylbenzene 11.51 105 309947 23.58 ug/l 99 77) t-1,4-Dichloro-2-butene 11.08 75 27321 20.93 ug/l 91 78) 4-Chlorotoluene 11.51 91 290084 23.66 ug/l 100 79) tert-butylbenzene 12.07 119 357086 25.68 ug/l 99 80) 1,2,4-Trimethylbenzene 11.81 105 319057 23.78 ug/l 100 81) sec-Butylbenzene 11.95 105 380586 25.00 ug/l 100 82) p-Isopropyltoluene 12.07 119 357086 25.68 ug/l 99 83) 1,3-Dichlorobenzene 12.03 146 193327 23.42 ug/l 100 84) 1,4-Dichlorobenzene 12.10 146 197448 23.80 ug/l 98 85) n-Butylbenzene 12.39 91 295020 26.68 ug/l 99 86) Hexachloroethane 12.60 117 51518 23.35 ug/l 99 87) 1,2-Dichlorobenzene 12.40 146 191107 22.33 ug/l 100 88) 1,2-Dibromo-3-Chloropropan 13.01 75 21201 17.37 ug/l 97 89) 1,2,4-Trichlorobenzene 13.65 180 149338 24.56 ug/l 100 90) Hexachlorobutadiene 13.79 225 82364 26.47 ug/l 98 91) Naphthalene 13.84 128 376556 20.68 ug/l 100 92) 1,2,3-Trichlorobenzene 14.02 180 150818 23.45 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed