Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051418\ Data File : VX001708.D Acq On : 14 May 2018 12:47 Operator : JC/MD Sample : VX0514WBS01 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 4 Sample Multiplier: 1 Quant Time: May 16 03:22:14 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\624X051118W.M Quant Title : METHOD 624 VOLATILE ORGANIC ANALYSIS QLast Update : Fri May 11 07:16:13 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane 5.03 128 64072 30.00 ug/l 0.00 28) 1,4-Difluorobenzene 6.87 114 333335 30.00 ug/l 0.00 57) Chlorobenzene-d5 10.12 117 305294 30.00 ug/l 0.00 System Monitoring Compounds 27) 1,2-Dichloroethane-d4 6.07 65 133362 28.53 ug/l 0.00 Spiked Amount 30.000 Range 50 - 169 Recovery = 95.10% 60) 4-Bromofluorobenzene 11.14 95 144692 29.95 ug/l 0.00 Spiked Amount 30.000 Range 56 - 143 Recovery = 99.83% 63) Toluene-d8 8.72 98 416618 30.60 ug/l 0.00 Spiked Amount 30.000 Range 66 - 137 Recovery = 102.00% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 75875 24.30 ug/l 100 3) Chloromethane 1.33 50 73798 21.35 ug/l 99 4) Vinyl Chloride 1.41 62 78295 21.69 ug/l 100 5) Bromomethane 1.65 94 39837 22.33 ug/l 93 6) Chloroethane 1.73 64 49915 20.77 ug/l 93 7) Trichlorofluoromethane 1.93 101 119822 23.11 ug/l 99 8) Diethyl Ether 2.19 74 45347 20.17 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.39 101 73009 25.34 ug/l 98 10) 1,1-Dichloroethene 2.38 96 65161 21.97 ug/l 97 11) Methyl Iodide 2.51 142 67449 15.65 ug/l 97 12) Methyl Acetate 2.78 43 92106 18.27 ug/l 97 13) Acrolein 2.30 56 48102 84.14 ug/l 97 14) Acrylonitrile 3.15 53 184557 91.63 ug/l 99 15) Acetone 2.45 58 55004 101.65 ug/l 97 16) Carbon Disulfide 2.57 76 160338 21.83 ug/l 99 17) Allyl chloride 2.73 41 119544 21.13 ug/l 97 18) Methylene Chloride 2.86 84 72180 20.62 ug/l 97 19) trans-1,2-Dichloroethene 3.17 96 70471 21.89 ug/l 97 20) Diisopropyl ether 3.87 45 226132 21.40 ug/l 98 21) 1,1-Dichloroethane 3.70 63 128622 21.16 ug/l 100 22) cis-1,2-Dichloroethene 4.60 96 77685 21.41 ug/l 98 23) tert-Butyl Alcohol 3.06 59 80410m 89.73 ug/l 24) Methyl tert-Butyl Ether 3.21 73 216554 20.10 ug/l 99 25) Chloroform 5.22 83 133553 21.33 ug/l 99 26) Cyclohexane 5.58 56 111354 25.11 ug/l # 99 29) 1,1-Dichloropropene 5.81 75 98844 23.60 ug/l 98 30) 2-Butanone 4.71 43 255978 92.63 ug/l 99 31) 2,2-Dichloropropane 4.59 77 104518 29.03 ug/l 97 32) 1,1,1-Trichloroethane 5.50 97 117507 22.06 ug/l 99 33) Carbon Tetrachloride 5.79 117 105693 22.53 ug/l 96 34) Benzene 6.15 78 288886 21.57 ug/l # 95 35) Methacrylonitrile 5.07 41 55332 18.47 ug/l 94 36) 1,2-Dichloroethane 6.20 62 107272 20.25 ug/l 99 37) Trichloroethene 7.22 130 91030 23.07 ug/l 98 38) Methylcyclohexane 7.46 83 119683 26.73 ug/l 98 39) 1,2-Dichloropropane 7.52 63 70286 20.94 ug/l 100 40) Dibromomethane 7.67 93 49555 20.60 ug/l 98 41) Bromodichloromethane 7.90 83 94255 20.83 ug/l 99 42) Vinyl Acetate 3.83 43 948296 104.04 ug/l 100 43) Ethyl Acetate 4.86 43 96762 18.37 ug/l 99 44) Isopropyl Acetate 6.47 43 149085 18.49 ug/l 98 45) 1,4-Dioxane 7.76 88 34573 365.58 ug/l 95 46) Methyl methacrylate 7.78 41 80868 18.57 ug/l 97 47) n-amyl Acetate 10.90 43 124307 18.05 ug/l 98 48) t-1,3-Dichloropropene 8.44 75 110825 22.19 ug/l 99 49) cis-1,3-Dichloropropene 9.04 75 97608 22.12 ug/l 99 50) 1,1,2-Trichloroethane 9.22 97 75913 21.31 ug/l 95 51) Ethyl methacrylate 9.18 69 99814 19.44 ug/l 100 52) 1,3-Dichloropropane 9.38 76 124765 21.26 ug/l 99 53) Dibromochloromethane 9.59 129 78737 21.29 ug/l 100 54) 1,2-Dibromoethane 9.68 107 79532 21.17 ug/l 99 55) 2-Chloroethyl vinyl ether 8.32 63 265796 97.36 ug/l 99 56) Bromoform 10.86 173 58349 19.29 ug/l 98 58) 4-Methyl-2-Pentanone 8.65 43 503287 91.65 ug/l 100 59) 2-Hexanone 9.50 43 381038 92.62 ug/l 99 61) Tetrachloroethene 9.34 164 110457 24.87 ug/l 97 62) Toluene 8.79 91 324773 22.12 ug/l 100 64) Chlorobenzene 10.14 112 212679 22.04 ug/l 99 65) 1,1,1,2-Tetrachloroethane 10.23 131 78437 21.51 ug/l 99 66) Ethyl Benzene 10.26 91 344219 22.59 ug/l 98 67) m/p-Xylenes 10.37 106 292750 48.11 ug/l 97 68) o-Xylene 10.70 106 130119 21.61 ug/l 99 69) Styrene 10.72 104 218831 22.03 ug/l 98 70) Isopropylbenzene 11.02 105 357473 23.05 ug/l 100 71) 1,1,2,2-Tetrachloroethane 11.27 83 96415 18.53 ug/l 100 72) 1,2,3-Trichloropropane 11.30 75 97645m 19.37 ug/l 73) Bromobenzene 11.26 156 100866 21.46 ug/l 99 74) n-propylbenzene 11.37 91 412238 24.14 ug/l 99 75) 2-Chlorotoluene 11.43 91 244398 22.82 ug/l 100 76) 1,3,5-Trimethylbenzene 11.51 105 301446 23.09 ug/l 99 77) t-1,4-Dichloro-2-butene 11.08 75 25958 20.02 ug/l 93 78) 4-Chlorotoluene 11.52 91 281808 23.14 ug/l 100 79) tert-butylbenzene 12.07 119 341663 24.74 ug/l 100 80) 1,2,4-Trimethylbenzene 11.81 105 309075 23.19 ug/l 99 81) sec-Butylbenzene 11.95 105 366996 24.28 ug/l 99 82) p-Isopropyltoluene 12.07 119 341663 24.74 ug/l 100 83) 1,3-Dichlorobenzene 12.03 146 187242 22.84 ug/l 100 84) 1,4-Dichlorobenzene 12.10 146 189022 22.94 ug/l 99 85) n-Butylbenzene 12.40 91 285433 25.99 ug/l 99 86) Hexachloroethane 12.60 117 48640 22.20 ug/l 97 87) 1,2-Dichlorobenzene 12.40 146 185309 21.81 ug/l 100 88) 1,2-Dibromo-3-Chloropropan 13.01 75 20485 16.90 ug/l 95 89) 1,2,4-Trichlorobenzene 13.65 180 142749 23.64 ug/l 100 90) Hexachlorobutadiene 13.79 225 79362 25.69 ug/l 98 91) Naphthalene 13.84 128 367873 20.34 ug/l 100 92) 1,2,3-Trichlorobenzene 14.02 180 144919 22.69 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed