Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051418\ Data File : VX001709.D Acq On : 14 May 2018 13:22 Operator : JC/MD Sample : VX0514WBSD01 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 5 Sample Multiplier: 1 Quant Time: May 16 03:26:51 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\624X051118W.M Quant Title : METHOD 624 VOLATILE ORGANIC ANALYSIS QLast Update : Fri May 11 07:16:13 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane 5.03 128 61484 30.00 ug/l 0.00 28) 1,4-Difluorobenzene 6.87 114 317753 30.00 ug/l 0.00 57) Chlorobenzene-d5 10.12 117 284562 30.00 ug/l 0.00 System Monitoring Compounds 27) 1,2-Dichloroethane-d4 6.07 65 128870 28.73 ug/l -0.01 Spiked Amount 30.000 Range 50 - 169 Recovery = 95.77% 60) 4-Bromofluorobenzene 11.14 95 135554 30.10 ug/l 0.00 Spiked Amount 30.000 Range 56 - 143 Recovery = 100.33% 63) Toluene-d8 8.72 98 396395 31.24 ug/l 0.00 Spiked Amount 30.000 Range 66 - 137 Recovery = 104.13% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 69860 23.32 ug/l 99 3) Chloromethane 1.32 50 68839 20.75 ug/l 100 4) Vinyl Chloride 1.40 62 72997 21.08 ug/l 99 5) Bromomethane 1.64 94 38218 22.32 ug/l 100 6) Chloroethane 1.73 64 46403 20.12 ug/l 97 7) Trichlorofluoromethane 1.93 101 110878 22.28 ug/l 98 8) Diethyl Ether 2.19 74 44601 20.67 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.39 101 69010 24.96 ug/l 98 10) 1,1-Dichloroethene 2.38 96 60044 21.10 ug/l 96 11) Methyl Iodide 2.51 142 67528 16.33 ug/l 99 12) Methyl Acetate 2.78 43 91624 18.94 ug/l 97 13) Acrolein 2.29 56 51401 93.69 ug/l 99 14) Acrylonitrile 3.15 53 184561 95.49 ug/l 100 15) Acetone 2.45 58 54530 105.02 ug/l 95 16) Carbon Disulfide 2.57 76 147885 20.98 ug/l 100 17) Allyl chloride 2.73 41 113668 20.94 ug/l 97 18) Methylene Chloride 2.86 84 68688 20.45 ug/l 97 19) trans-1,2-Dichloroethene 3.17 96 66224 21.44 ug/l 96 20) Diisopropyl ether 3.87 45 216872 21.38 ug/l 98 21) 1,1-Dichloroethane 3.70 63 120155 20.60 ug/l 99 22) cis-1,2-Dichloroethene 4.60 96 74293 21.33 ug/l 97 23) tert-Butyl Alcohol 3.07 59 81124 94.34 ug/l # 100 24) Methyl tert-Butyl Ether 3.21 73 211993 20.50 ug/l 99 25) Chloroform 5.22 83 125633 20.91 ug/l 97 26) Cyclohexane 5.58 56 104429 24.54 ug/l # 99 29) 1,1-Dichloropropene 5.81 75 90933 22.78 ug/l 99 30) 2-Butanone 4.71 43 256949 97.54 ug/l 99 31) 2,2-Dichloropropane 4.59 77 96407 28.09 ug/l 97 32) 1,1,1-Trichloroethane 5.50 97 110320 21.73 ug/l 98 33) Carbon Tetrachloride 5.79 117 98700 22.07 ug/l 98 34) Benzene 6.15 78 274849 21.53 ug/l 99 35) Methacrylonitrile 5.06 41 54391 19.04 ug/l 96 36) 1,2-Dichloroethane 6.20 62 104721 20.74 ug/l 100 37) Trichloroethene 7.22 130 84939 22.58 ug/l 97 38) Methylcyclohexane 7.46 83 109965 25.76 ug/l 99 39) 1,2-Dichloropropane 7.52 63 66567 20.80 ug/l 100 40) Dibromomethane 7.67 93 48054 20.96 ug/l 98 41) Bromodichloromethane 7.90 83 90297 20.93 ug/l 97 42) Vinyl Acetate 3.82 43 931143 107.17 ug/l 100 43) Ethyl Acetate 4.86 43 97141 19.35 ug/l 97 44) Isopropyl Acetate 6.47 43 150772 19.61 ug/l 98 45) 1,4-Dioxane 7.76 88 35044 388.73 ug/l 98 46) Methyl methacrylate 7.78 41 80159 19.31 ug/l 95 47) n-amyl Acetate 10.90 43 121926 18.57 ug/l 100 48) t-1,3-Dichloropropene 8.44 75 104599 21.97 ug/l 99 49) cis-1,3-Dichloropropene 9.04 75 93917 22.32 ug/l 99 50) 1,1,2-Trichloroethane 9.22 97 73581 21.67 ug/l 97 51) Ethyl methacrylate 9.18 69 97314 19.88 ug/l 97 52) 1,3-Dichloropropane 9.38 76 115555 20.66 ug/l 98 53) Dibromochloromethane 9.59 129 71752 20.35 ug/l 99 54) 1,2-Dibromoethane 9.68 107 74516 20.81 ug/l 99 55) 2-Chloroethyl vinyl ether 8.32 63 269688 103.63 ug/l 99 56) Bromoform 10.86 173 56046 19.44 ug/l 98 58) 4-Methyl-2-Pentanone 8.65 43 506611 98.98 ug/l 100 59) 2-Hexanone 9.50 43 365706 95.37 ug/l 99 61) Tetrachloroethene 9.34 164 99239 23.97 ug/l 98 62) Toluene 8.79 91 308087 22.51 ug/l 100 64) Chlorobenzene 10.14 112 198465 22.07 ug/l 100 65) 1,1,1,2-Tetrachloroethane 10.23 131 71177 20.94 ug/l 99 66) Ethyl Benzene 10.26 91 319151 22.47 ug/l 97 67) m/p-Xylenes 10.37 106 257587 45.41 ug/l 99 68) o-Xylene 10.70 106 122069 21.75 ug/l 99 69) Styrene 10.72 104 202906 21.91 ug/l 98 70) Isopropylbenzene 11.02 105 333206 23.05 ug/l 100 71) 1,1,2,2-Tetrachloroethane 11.27 83 95716 19.74 ug/l 100 72) 1,2,3-Trichloropropane 11.30 75 96500m 20.54 ug/l 73) Bromobenzene 11.26 156 96237 21.97 ug/l 99 74) n-propylbenzene 11.37 91 383714 24.11 ug/l 99 75) 2-Chlorotoluene 11.43 91 224772 22.52 ug/l 99 76) 1,3,5-Trimethylbenzene 11.51 105 284015 23.34 ug/l 99 77) t-1,4-Dichloro-2-butene 11.08 75 25269 20.91 ug/l 91 78) 4-Chlorotoluene 11.51 91 260494 22.95 ug/l 100 79) tert-butylbenzene 12.07 119 314645 24.44 ug/l 99 80) 1,2,4-Trimethylbenzene 11.81 105 289854 23.34 ug/l 100 81) sec-Butylbenzene 11.95 105 341222 24.22 ug/l 100 82) p-Isopropyltoluene 12.07 119 314645 24.44 ug/l 99 83) 1,3-Dichlorobenzene 12.03 146 175279 22.94 ug/l 99 84) 1,4-Dichlorobenzene 12.10 146 177189 23.07 ug/l 99 85) n-Butylbenzene 12.40 91 265118 25.90 ug/l 100 86) Hexachloroethane 12.60 117 44755 21.91 ug/l 96 87) 1,2-Dichlorobenzene 12.40 146 173903 21.95 ug/l 99 88) 1,2-Dibromo-3-Chloropropan 13.01 75 19937 17.65 ug/l 94 89) 1,2,4-Trichlorobenzene 13.65 180 135172 24.02 ug/l 99 90) Hexachlorobutadiene 13.79 225 75402 26.18 ug/l 99 91) Naphthalene 13.84 128 358304 21.26 ug/l 100 92) 1,2,3-Trichlorobenzene 14.02 180 139507 23.44 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed