Data Path : W:\HPCHEM1\MSVOA_X\Data\VX051518\ Quantitation Report (QT Reviewed) Data File : VX001712.D Acq On : 14 May 2018 15:49 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 8 Sample Multiplier: 1 Quant Time: May 15 00:54:25 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051418W.M Quant Title : SW846 8260 QLast Update : Mon May 14 17:33:12 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 286203 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 349044 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 314551 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 231186 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 160072 38.91 ug/l 0.00 Spiked Amount 50.000 Recovery = 77.82% 35) Dibromofluoromethane 5.51 113 141005 45.42 ug/l 0.00 Spiked Amount 50.000 Recovery = 90.84% 50) Toluene-d8 8.72 98 499195 44.05 ug/l 0.00 Spiked Amount 50.000 Recovery = 88.10% 62) 4-Bromofluorobenzene 11.14 95 181791 41.79 ug/l 0.00 Spiked Amount 50.000 Recovery = 83.58% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 184456 47.88 ug/l 98 3) Chloromethane 1.32 50 170756 45.51 ug/l 100 4) Vinyl Chloride 1.40 62 189677 48.44 ug/l 100 5) Bromomethane 1.64 94 76993 33.65 ug/l 98 6) Chloroethane 1.72 64 120034 46.37 ug/l 99 7) Trichlorofluoromethane 1.93 101 293120 49.74 ug/l 99 8) Diethyl Ether 2.19 74 118053 51.11 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.39 101 185296 53.63 ug/l 99 10) Methyl Iodide 2.51 142 161275 32.35 ug/l 98 11) Tert butyl alcohol 3.07 59 182320 210.21 ug/l 100 12) 1,1-Dichloroethene 2.37 96 159343 50.31 ug/l 100 13) Acrolein 2.29 56 21521 106.15 ug/l 96 14) Allyl chloride 2.73 41 303120 51.33 ug/l 98 15) Acrylonitrile 3.15 53 471403 240.53 ug/l 100 16) Acetone 2.45 43 411997 220.56 ug/l 98 17) Carbon Disulfide 2.57 76 360535 44.73 ug/l 99 18) Methyl Acetate 2.78 43 262684 53.53 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 575323 52.18 ug/l 99 20) Methylene Chloride 2.86 84 180080 48.69 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 169775 48.04 ug/l 99 22) Diisopropyl ether 3.87 45 605738 54.90 ug/l 97 23) Vinyl Acetate 3.82 43 2448288 266.28 ug/l 100 24) 1,1-Dichloroethane 3.70 63 325724 52.85 ug/l 100 25) 2-Butanone 4.71 43 656226 243.04 ug/l 100 26) 2,2-Dichloropropane 4.59 77 282655 59.39 ug/l 98 27) cis-1,2-Dichloroethene 4.60 96 206937 54.98 ug/l 95 28) Bromochloromethane 5.02 49 140283 52.50 ug/l 100 29) Tetrahydrofuran 5.17 42 418498 242.25 ug/l 99 30) Chloroform 5.21 83 348402 54.88 ug/l 99 31) Cyclohexane 5.58 56 278542 52.62 ug/l 97 32) 1,1,1-Trichloroethane 5.49 97 305278 55.02 ug/l 98 36) 1,1-Dichloropropene 5.80 75 250601 56.44 ug/l 99 37) Ethyl Acetate 4.86 43 253583 52.10 ug/l 99 38) Carbon Tetrachloride 5.79 117 276113 58.31 ug/l 99 39) Methylcyclohexane 7.46 83 309961 59.05 ug/l 99 40) Benzene 6.15 78 745827 57.51 ug/l 98 41) Methacrylonitrile 5.07 41 152916 54.91 ug/l 98 42) 1,2-Dichloroethane 6.20 62 270786 54.33 ug/l 98 43) Isopropyl Acetate 6.47 43 422283 56.52 ug/l 99 44) Trichloroethene 7.21 130 233988 59.03 ug/l 98 45) 1,2-Dichloropropane 7.52 63 192545 59.55 ug/l 100 46) Dibromomethane 7.67 93 128488 56.14 ug/l 98 47) Bromodichloromethane 7.90 83 261279 61.68 ug/l 100 48) Methyl methacrylate 7.78 41 225792 55.50 ug/l 96 49) 1,4-Dioxane 7.76 88 76974 875.74 ug/l 98 51) 4-Methyl-2-Pentanone 8.65 43 1365061 274.94 ug/l 98 52) Toluene 8.79 92 501957 59.19 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 309585 64.67 ug/l 98 54) cis-1,3-Dichloropropene 9.04 75 288037 66.10 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 205766 60.23 ug/l 96 56) Ethyl methacrylate 9.18 69 299592 60.84 ug/l 97 57) 1,3-Dichloropropane 9.38 76 311715 55.18 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 687895 284.80 ug/l 100 59) 2-Hexanone 9.50 43 951704 250.33 ug/l 98 60) Dibromochloromethane 9.59 129 207193 59.22 ug/l 99 61) 1,2-Dibromoethane 9.68 107 198913 55.45 ug/l 99 64) Tetrachloroethene 9.34 164 259243 59.13 ug/l 99 65) Chlorobenzene 10.14 112 536941 58.20 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 205279 62.21 ug/l 100 67) Ethyl Benzene 10.26 91 896443 59.29 ug/l 99 68) m/p-Xylenes 10.37 106 710848 118.98 ug/l 98 69) o-Xylene 10.70 106 344857 59.39 ug/l 100 70) Styrene 10.72 104 573077 60.75 ug/l 99 71) Bromoform 10.86 173 169021 62.47 ug/l 99 73) Isopropylbenzene 11.02 105 932830 58.29 ug/l 99 74) N-amyl acetate 6.47 43 422283 58.09 ug/l # 98 75) 1,1,2,2-Tetrachloroethane 11.27 83 260646 55.14 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 262618m 56.01 ug/l 77) Bromobenzene 11.26 156 264075 56.75 ug/l 98 78) n-propylbenzene 11.37 91 1063165 61.00 ug/l 99 79) 2-Chlorotoluene 11.43 91 614449 57.29 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 778553 58.43 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 80063 65.12 ug/l 93 82) 4-Chlorotoluene 11.52 91 725757 58.66 ug/l 99 83) tert-Butylbenzene 11.77 119 773958 58.38 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 806382 58.88 ug/l 100 85) sec-Butylbenzene 11.95 105 975119 61.27 ug/l 100 86) p-Isopropyltoluene 12.07 119 903479 61.89 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 492798 59.25 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 496580 58.53 ug/l 100 89) n-Butylbenzene 12.40 91 780135 64.49 ug/l 100 90) Hexachloroethane 12.60 117 141036 64.16 ug/l 98 91) 1,2-Dichlorobenzene 12.40 146 491622 58.10 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 57654 55.51 ug/l 95 93) 1,2,4-Trichlorobenzene 13.65 180 409913 66.20 ug/l 100 94) Hexachlorobutadiene 13.79 225 222995 65.82 ug/l 100 95) Naphthalene 13.84 128 1047087 61.14 ug/l 99 96) 1,2,3-Trichlorobenzene 14.02 180 403751 63.54 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed 82X051418W.M Tue May 15 00:55:34 2018