Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051518\ Data File : VX001713.D Acq On : 14 May 2018 16:57 Operator : JC/MD Sample : VSTDICC001 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 9 Sample Multiplier: 1 Quant Time: May 15 01:32:32 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:02:23 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 347726 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 451329 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 395565 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 258933 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 5403 1.10 ug/l 0.00 Spiked Amount 50.000 Recovery = 2.20% 35) Dibromofluoromethane 5.51 113 4265 1.08 ug/l 0.00 Spiked Amount 50.000 Recovery = 2.16% 50) Toluene-d8 8.72 98 13370 0.92 ug/l 0.00 Spiked Amount 50.000 Recovery = 1.84% 62) 4-Bromofluorobenzene 11.14 95 5133 0.94 ug/l 0.00 Spiked Amount 50.000 Recovery = 1.88% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 3727 0.84 ug/l 96 3) Chloromethane 1.32 50 4380 0.99 ug/l 98 4) Vinyl Chloride 1.40 62 4414 0.95 ug/l 92 5) Bromomethane 1.65 94 3118 1.15 ug/l 96 6) Chloroethane 1.73 64 2809 0.92 ug/l 97 7) Trichlorofluoromethane 1.94 101 6598 0.95 ug/l 95 8) Diethyl Ether 2.19 74 2554 0.93 ug/l 96 9) 1,1,2-Trichlorotrifluoroet 2.39 101 4145 1.01 ug/l 99 12) 1,1-Dichloroethene 2.38 96 3941 1.05 ug/l 98 14) Allyl chloride 2.73 41 6958 0.99 ug/l 96 15) Acrylonitrile 3.15 53 10819 4.64 ug/l 97 16) Acetone 2.45 43 10582 4.81 ug/l 100 17) Carbon Disulfide 2.57 76 11228 1.17 ug/l 98 18) Methyl Acetate 2.78 43 5278 0.89 ug/l # 88 19) Methyl tert-butyl Ether 3.20 73 12209 0.93 ug/l 95 20) Methylene Chloride 2.86 84 4748 1.08 ug/l 92 21) trans-1,2-Dichloroethene 3.17 96 4700 1.11 ug/l 93 22) Diisopropyl ether 3.87 45 13129 0.99 ug/l # 86 23) Vinyl Acetate 3.83 43 50024 4.69 ug/l 98 24) 1,1-Dichloroethane 3.70 63 7545 1.03 ug/l 95 25) 2-Butanone 4.71 43 13688 4.26 ug/l 97 26) 2,2-Dichloropropane 4.59 77 5881 1.03 ug/l 98 27) cis-1,2-Dichloroethene 4.60 96 5014 1.10 ug/l 99 28) Bromochloromethane 5.02 49 3145 0.97 ug/l # 97 29) Tetrahydrofuran 5.17 42 9216 4.47 ug/l 97 30) Chloroform 5.22 83 7556 0.99 ug/l 93 31) Cyclohexane 5.58 56 6040 0.95 ug/l 94 32) 1,1,1-Trichloroethane 5.50 97 6107 0.92 ug/l # 51 36) 1,1-Dichloropropene 5.80 75 6059 1.07 ug/l 96 37) Ethyl Acetate 4.87 43 5560 0.90 ug/l 99 38) Carbon Tetrachloride 5.78 117 5793 0.97 ug/l 85 39) Methylcyclohexane 7.46 83 6315 0.94 ug/l 98 40) Benzene 6.15 78 16354 0.99 ug/l 98 41) Methacrylonitrile 5.06 41 3279 0.93 ug/l 92 42) 1,2-Dichloroethane 6.20 62 5898 0.94 ug/l 99 43) Isopropyl Acetate 6.47 43 7976 0.84 ug/l 99 44) Trichloroethene 7.21 130 5320 1.05 ug/l 88 45) 1,2-Dichloropropane 7.52 63 3822 0.93 ug/l 89 46) Dibromomethane 7.67 93 2894 1.00 ug/l 96 47) Bromodichloromethane 7.90 83 4752 0.88 ug/l 93 48) Methyl methacrylate 7.79 41 4081 0.79 ug/l 97 49) 1,4-Dioxane 7.76 88 1537 14.16 ug/l 96 51) 4-Methyl-2-Pentanone 8.65 43 22606 3.61 ug/l 99 52) Toluene 8.79 92 9624 0.89 ug/l 97 53) t-1,3-Dichloropropene 8.44 75 5026 0.82 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 4604 0.84 ug/l 95 55) 1,1,2-Trichloroethane 9.22 97 4076 0.95 ug/l 92 56) Ethyl methacrylate 9.18 69 4464 0.72 ug/l 93 57) 1,3-Dichloropropane 9.38 76 6683 0.94 ug/l 97 58) 2-Chloroethyl Vinyl ether 8.32 63 11994 3.91 ug/l 93 59) 2-Hexanone 9.50 43 16191 3.42 ug/l 96 60) Dibromochloromethane 9.59 129 3516 0.80 ug/l 94 61) 1,2-Dibromoethane 9.68 107 3946 0.87 ug/l 99 64) Tetrachloroethene 9.34 164 5920 1.09 ug/l 96 65) Chlorobenzene 10.14 112 11939 1.04 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 3734 0.91 ug/l # 64 67) Ethyl Benzene 10.26 91 17722 0.94 ug/l 99 68) m/p-Xylenes 10.37 106 13443 1.81 ug/l 99 69) o-Xylene 10.70 106 6214 0.86 ug/l 95 70) Styrene 10.71 104 9783 0.84 ug/l 98 71) Bromoform 10.86 173 2550 0.76 ug/l # 96 73) Isopropylbenzene 11.02 105 16884 0.94 ug/l 100 74) N-amyl acetate 6.47 43 7976 0.97 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 5313 1.01 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 4767m 0.91 ug/l 77) Bromobenzene 11.26 156 5305 1.02 ug/l 97 78) n-propylbenzene 11.37 91 19746 1.01 ug/l 97 79) 2-Chlorotoluene 11.43 91 11935 1.00 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 12844 0.86 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 1063 0.77 ug/l # 67 82) 4-Chlorotoluene 11.52 91 14068 1.02 ug/l 98 83) tert-Butylbenzene 11.77 119 13250 0.90 ug/l 97 84) 1,2,4-Trimethylbenzene 11.81 105 13336 0.87 ug/l 99 85) sec-Butylbenzene 11.95 105 16872 0.95 ug/l 99 86) p-Isopropyltoluene 12.07 119 15388 0.95 ug/l 93 87) 1,3-Dichlorobenzene 12.03 146 10288 1.10 ug/l 98 88) 1,4-Dichlorobenzene 12.10 146 11331m 1.19 ug/l 89) n-Butylbenzene 12.40 91 14424 1.06 ug/l 98 90) Hexachloroethane 12.60 117 2149 0.87 ug/l 91 91) 1,2-Dichlorobenzene 12.40 146 10265 1.09 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 933 0.81 ug/l 92 93) 1,2,4-Trichlorobenzene 13.65 180 8341 1.19 ug/l 96 94) Hexachlorobutadiene 13.79 225 4575 1.20 ug/l 98 95) Naphthalene 13.84 128 18563 0.97 ug/l 98 96) 1,2,3-Trichlorobenzene 14.02 180 8545 1.20 ug/l 97 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed