Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051518\ Data File : VX001714.D Acq On : 14 May 2018 17:23 Operator : JC/MD Sample : VSTDICC005 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 10 Sample Multiplier: 1 Quant Time: May 15 01:20:35 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:02:23 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 313813 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 414468 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 376766 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 247205 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 20593 4.64 ug/l 0.00 Spiked Amount 50.000 Recovery = 9.28% 35) Dibromofluoromethane 5.51 113 16342 4.49 ug/l 0.00 Spiked Amount 50.000 Recovery = 8.98% 50) Toluene-d8 8.72 98 55529 4.17 ug/l 0.00 Spiked Amount 50.000 Recovery = 8.34% 62) 4-Bromofluorobenzene 11.14 95 21410 4.26 ug/l 0.00 Spiked Amount 50.000 Recovery = 8.52% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 15416 3.83 ug/l 100 3) Chloromethane 1.32 50 16701 4.18 ug/l 98 4) Vinyl Chloride 1.40 62 18191 4.34 ug/l 100 5) Bromomethane 1.64 94 8251 3.38 ug/l 95 6) Chloroethane 1.72 64 11986 4.35 ug/l 100 7) Trichlorofluoromethane 1.93 101 26102 4.16 ug/l 95 8) Diethyl Ether 2.19 74 11244 4.54 ug/l 93 9) 1,1,2-Trichlorotrifluoroet 2.39 101 16031 4.35 ug/l 96 10) Methyl Iodide 2.51 142 12380 2.50 ug/l 98 11) Tert butyl alcohol 3.08 59 19688 21.70 ug/l 97 12) 1,1-Dichloroethene 2.37 96 15381 4.52 ug/l 99 13) Acrolein 2.30 56 14231 50.24 ug/l 99 14) Allyl chloride 2.73 41 27088 4.26 ug/l 96 15) Acrylonitrile 3.15 53 45625 21.68 ug/l 97 16) Acetone 2.45 43 41837 21.07 ug/l 97 17) Carbon Disulfide 2.57 76 35584 4.11 ug/l 97 18) Methyl Acetate 2.78 43 22964 4.31 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 51319 4.33 ug/l 97 20) Methylene Chloride 2.86 84 17766 4.47 ug/l 92 21) trans-1,2-Dichloroethene 3.17 96 16190 4.25 ug/l 88 22) Diisopropyl ether 3.88 45 53548 4.49 ug/l 98 23) Vinyl Acetate 3.83 43 221156 22.96 ug/l 98 24) 1,1-Dichloroethane 3.70 63 30471 4.60 ug/l 97 25) 2-Butanone 4.71 43 60284 20.78 ug/l 96 26) 2,2-Dichloropropane 4.59 77 22904 4.45 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 17937 4.38 ug/l 94 28) Bromochloromethane 5.03 49 11811 4.05 ug/l 97 29) Tetrahydrofuran 5.17 42 38722 20.80 ug/l 99 30) Chloroform 5.22 83 31646 4.61 ug/l 99 31) Cyclohexane 5.58 56 24351 4.24 ug/l 98 32) 1,1,1-Trichloroethane 5.50 97 25926 4.33 ug/l 98 36) 1,1-Dichloropropene 5.81 75 22158 4.27 ug/l 98 37) Ethyl Acetate 4.87 43 23832 4.22 ug/l 99 38) Carbon Tetrachloride 5.78 117 23254 4.22 ug/l 94 39) Methylcyclohexane 7.46 83 24366 3.97 ug/l 96 40) Benzene 6.15 78 68041 4.49 ug/l 98 41) Methacrylonitrile 5.07 41 13836 4.26 ug/l 97 42) 1,2-Dichloroethane 6.20 62 26059 4.51 ug/l 100 43) Isopropyl Acetate 6.48 43 35929 4.14 ug/l 99 44) Trichloroethene 7.21 130 21074 4.52 ug/l 99 45) 1,2-Dichloropropane 7.52 63 16695 4.41 ug/l 99 46) Dibromomethane 7.67 93 11762 4.41 ug/l 97 47) Bromodichloromethane 7.90 83 20043 4.06 ug/l 95 48) Methyl methacrylate 7.78 41 18772 3.98 ug/l 97 49) 1,4-Dioxane 7.76 88 7230 72.53 ug/l 99 51) 4-Methyl-2-Pentanone 8.66 43 116457 20.24 ug/l 99 52) Toluene 8.79 92 43901 4.43 ug/l 98 53) t-1,3-Dichloropropene 8.44 75 22567 4.03 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 19951 3.96 ug/l 97 55) 1,1,2-Trichloroethane 9.22 97 17089 4.32 ug/l 95 56) Ethyl methacrylate 9.19 69 21566 3.79 ug/l 98 57) 1,3-Dichloropropane 9.38 76 29497 4.51 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 61119 21.70 ug/l 100 59) 2-Hexanone 9.51 43 85113 19.56 ug/l 96 60) Dibromochloromethane 9.59 129 15191 3.77 ug/l 99 61) 1,2-Dibromoethane 9.68 107 17373 4.19 ug/l 99 64) Tetrachloroethene 9.34 164 24130 4.65 ug/l 98 65) Chlorobenzene 10.15 112 49929 4.57 ug/l 98 66) 1,1,1,2-Tetrachloroethane 10.23 131 16353 4.20 ug/l 100 67) Ethyl Benzene 10.26 91 76281 4.26 ug/l 99 68) m/p-Xylenes 10.37 106 60079 8.51 ug/l 99 69) o-Xylene 10.71 106 28698 4.19 ug/l 100 70) Styrene 10.72 104 45903 4.12 ug/l 99 71) Bromoform 10.86 173 11568 3.63 ug/l # 97 73) Isopropylbenzene 11.02 105 77759 4.55 ug/l 98 74) N-amyl acetate 6.48 43 35929 4.58 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 23779 4.72 ug/l 98 76) 1,2,3-Trichloropropane 11.30 75 23031m 4.59 ug/l 77) Bromobenzene 11.26 156 22825 4.58 ug/l 97 78) n-propylbenzene 11.37 91 85917 4.61 ug/l 98 79) 2-Chlorotoluene 11.43 91 52781 4.62 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 63317 4.46 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 4935 3.73 ug/l # 74 82) 4-Chlorotoluene 11.52 91 61983 4.70 ug/l 100 83) tert-Butylbenzene 11.77 119 60352 4.29 ug/l 98 84) 1,2,4-Trimethylbenzene 11.81 105 64800 4.44 ug/l 100 85) sec-Butylbenzene 11.95 105 76071 4.48 ug/l 98 86) p-Isopropyltoluene 12.07 119 70360 4.53 ug/l 98 87) 1,3-Dichlorobenzene 12.03 146 41849 4.71 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 43835 4.83 ug/l 93 89) n-Butylbenzene 12.40 91 58352 4.50 ug/l 99 90) Hexachloroethane 12.60 117 9910 4.19 ug/l 94 91) 1,2-Dichlorobenzene 12.40 146 41918 4.65 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 4418 4.01 ug/l 99 93) 1,2,4-Trichlorobenzene 13.65 180 31722 4.75 ug/l 99 94) Hexachlorobutadiene 13.79 225 17387 4.76 ug/l 98 95) Naphthalene 13.84 128 78706 4.29 ug/l 99 96) 1,2,3-Trichlorobenzene 14.02 180 32105 4.70 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed