Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051518\ Data File : VX001715.D Acq On : 14 May 2018 17:50 Operator : JC/MD Sample : VSTDICC020 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 11 Sample Multiplier: 1 Quant Time: May 15 01:22:35 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:02:23 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 322329 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 423191 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 375244 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 252797 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 90113 19.78 ug/l 0.00 Spiked Amount 50.000 Recovery = 39.56% 35) Dibromofluoromethane 5.51 113 74186 19.94 ug/l 0.00 Spiked Amount 50.000 Recovery = 39.88% 50) Toluene-d8 8.72 98 278154 20.44 ug/l 0.00 Spiked Amount 50.000 Recovery = 40.88% 62) 4-Bromofluorobenzene 11.14 95 95930 18.71 ug/l 0.00 Spiked Amount 50.000 Recovery = 37.42% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 67221 16.25 ug/l 99 3) Chloromethane 1.32 50 71252 17.37 ug/l 100 4) Vinyl Chloride 1.40 62 77918 18.08 ug/l 98 5) Bromomethane 1.64 94 44003 17.56 ug/l 98 6) Chloroethane 1.73 64 50837 17.97 ug/l 100 7) Trichlorofluoromethane 1.93 101 115072 17.86 ug/l 99 8) Diethyl Ether 2.19 74 46690 18.36 ug/l 97 9) 1,1,2-Trichlorotrifluoroet 2.39 101 67997 17.95 ug/l 99 10) Methyl Iodide 2.51 142 55593 10.93 ug/l 99 11) Tert butyl alcohol 3.08 59 76490 82.09 ug/l 99 12) 1,1-Dichloroethene 2.37 96 65406 18.71 ug/l 98 13) Acrolein 2.29 56 54029 185.69 ug/l 99 14) Allyl chloride 2.73 41 119848 18.36 ug/l 100 15) Acrylonitrile 3.15 53 198899 92.01 ug/l 100 16) Acetone 2.45 43 174835 85.73 ug/l 99 17) Carbon Disulfide 2.57 76 158855 17.88 ug/l 98 18) Methyl Acetate 2.78 43 104354 19.08 ug/l 98 19) Methyl tert-butyl Ether 3.21 73 223124 18.33 ug/l 99 20) Methylene Chloride 2.86 84 72667 17.81 ug/l 97 21) trans-1,2-Dichloroethene 3.17 96 69838 17.87 ug/l 96 22) Diisopropyl ether 3.88 45 226087 18.45 ug/l 99 23) Vinyl Acetate 3.83 43 763721 77.20 ug/l 100 24) 1,1-Dichloroethane 3.70 63 125030 18.37 ug/l 99 25) 2-Butanone 4.71 43 268410 90.07 ug/l 99 26) 2,2-Dichloropropane 4.59 77 101962 19.29 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 79513 18.89 ug/l 99 28) Bromochloromethane 5.03 49 59848 19.98 ug/l 98 29) Tetrahydrofuran 5.17 42 171122 89.49 ug/l 100 30) Chloroform 5.22 83 134055 19.02 ug/l 99 31) Cyclohexane 5.58 56 111471 18.90 ug/l 98 32) 1,1,1-Trichloroethane 5.50 97 116837 18.99 ug/l 99 36) 1,1-Dichloropropene 5.81 75 97652 18.41 ug/l 100 37) Ethyl Acetate 4.87 43 103710 17.97 ug/l 99 38) Carbon Tetrachloride 5.79 117 104871 18.66 ug/l 98 39) Methylcyclohexane 7.46 83 116744 18.62 ug/l 98 40) Benzene 6.15 78 296402 19.14 ug/l 100 41) Methacrylonitrile 5.07 41 59848 18.07 ug/l 98 42) 1,2-Dichloroethane 6.20 62 109209 18.53 ug/l 100 43) Isopropyl Acetate 6.48 43 161965 18.26 ug/l 100 44) Trichloroethene 7.22 130 89761 18.86 ug/l 98 45) 1,2-Dichloropropane 7.52 63 73558 19.04 ug/l 99 46) Dibromomethane 7.67 93 50315 18.47 ug/l 99 47) Bromodichloromethane 7.90 83 94001 18.66 ug/l 97 48) Methyl methacrylate 7.78 41 85657 17.80 ug/l 98 49) 1,4-Dioxane 7.76 88 32542 319.73 ug/l 99 51) 4-Methyl-2-Pentanone 8.66 43 534010 90.89 ug/l 99 52) Toluene 8.79 92 194234 19.18 ug/l 99 53) t-1,3-Dichloropropene 8.44 75 111902 19.55 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 95368 18.56 ug/l 100 55) 1,1,2-Trichloroethane 9.22 97 73257 18.12 ug/l 98 56) Ethyl methacrylate 9.19 69 104107 17.93 ug/l 99 57) 1,3-Dichloropropane 9.38 76 122987 18.43 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 272927 94.90 ug/l 100 59) 2-Hexanone 9.50 43 387325 87.17 ug/l 99 60) Dibromochloromethane 9.59 129 74246 18.05 ug/l 100 61) 1,2-Dibromoethane 9.68 107 78458 18.54 ug/l 100 64) Tetrachloroethene 9.34 164 101401 19.63 ug/l 99 65) Chlorobenzene 10.15 112 211991 19.48 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 76809 19.79 ug/l 97 67) Ethyl Benzene 10.26 91 344259 19.32 ug/l 98 68) m/p-Xylenes 10.37 106 274842 39.08 ug/l 99 69) o-Xylene 10.71 106 130954 19.21 ug/l 98 70) Styrene 10.72 104 219246 19.76 ug/l 99 71) Bromoform 10.87 173 58939 18.57 ug/l 99 73) Isopropylbenzene 11.02 105 353753 20.26 ug/l 100 74) N-amyl acetate 6.48 43 161965 20.20 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 102243 19.84 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 100810m 19.66 ug/l 77) Bromobenzene 11.26 156 101572 19.94 ug/l 99 78) n-propylbenzene 11.37 91 398135 20.90 ug/l 99 79) 2-Chlorotoluene 11.43 91 236529 20.25 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 293957 20.25 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 27368 20.24 ug/l 92 82) 4-Chlorotoluene 11.52 91 278387 20.64 ug/l 99 83) tert-Butylbenzene 11.77 119 281838 19.58 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 305212 20.46 ug/l 99 85) sec-Butylbenzene 11.95 105 355686 20.50 ug/l 100 86) p-Isopropyltoluene 12.07 119 330024 20.78 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 184959 20.35 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 187526 20.22 ug/l 99 89) n-Butylbenzene 12.40 91 275974 20.83 ug/l 100 90) Hexachloroethane 12.60 117 47925 19.82 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 184447 19.99 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 21742 19.28 ug/l 100 93) 1,2,4-Trichlorobenzene 13.65 180 140242 20.53 ug/l 99 94) Hexachlorobutadiene 13.79 225 76543 20.50 ug/l 99 95) Naphthalene 13.84 128 385920 20.57 ug/l 99 96) 1,2,3-Trichlorobenzene 14.02 180 143941 20.63 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed