Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051518\ Data File : VX001716.D Acq On : 14 May 2018 18:16 Operator : JC/MD Sample : VSTDICCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 12 Sample Multiplier: 1 Quant Time: May 15 01:24:43 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:02:23 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 325648 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 425864 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 375967 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 252748 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 208360 45.27 ug/l 0.00 Spiked Amount 50.000 Recovery = 90.54% 35) Dibromofluoromethane 5.51 113 175735 46.95 ug/l 0.00 Spiked Amount 50.000 Recovery = 93.90% 50) Toluene-d8 8.72 98 660241 48.20 ug/l 0.00 Spiked Amount 50.000 Recovery = 96.40% 62) 4-Bromofluorobenzene 11.14 95 231889 44.95 ug/l 0.00 Spiked Amount 50.000 Recovery = 89.90% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 161015 38.53 ug/l 100 3) Chloromethane 1.32 50 165398 39.91 ug/l 100 4) Vinyl Chloride 1.40 62 184039 42.28 ug/l 100 5) Bromomethane 1.64 94 79748 31.50 ug/l 100 6) Chloroethane 1.72 64 118644 41.52 ug/l 100 7) Trichlorofluoromethane 1.93 101 269382 41.38 ug/l 100 8) Diethyl Ether 2.19 74 108646 42.28 ug/l 100 9) 1,1,2-Trichlorotrifluoroet 2.39 101 158172 41.33 ug/l 100 10) Methyl Iodide 2.51 142 156794 30.52 ug/l 100 11) Tert butyl alcohol 3.08 59 182548 193.92 ug/l 100 12) 1,1-Dichloroethene 2.37 96 152664 43.24 ug/l 100 13) Acrolein 2.30 56 126374 429.91 ug/l 100 14) Allyl chloride 2.73 41 290072 43.99 ug/l 100 15) Acrylonitrile 3.15 53 470747 215.54 ug/l 100 16) Acetone 2.45 43 399549 193.92 ug/l 100 17) Carbon Disulfide 2.57 76 394850 43.99 ug/l 100 18) Methyl Acetate 2.78 43 248912 45.05 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 529981 43.10 ug/l 100 20) Methylene Chloride 2.86 84 170010 41.24 ug/l 100 21) trans-1,2-Dichloroethene 3.17 96 167655 42.46 ug/l 100 22) Diisopropyl ether 3.88 45 552151 44.59 ug/l 100 23) Vinyl Acetate 3.83 43 1887134 188.82 ug/l 100 24) 1,1-Dichloroethane 3.70 63 297701 43.29 ug/l 100 25) 2-Butanone 4.71 43 647867 215.18 ug/l 100 26) 2,2-Dichloropropane 4.59 77 246337 46.13 ug/l 100 27) cis-1,2-Dichloroethene 4.60 96 194216 45.68 ug/l 100 28) Bromochloromethane 5.03 49 145644 48.13 ug/l 100 29) Tetrahydrofuran 5.17 42 423927 219.43 ug/l 100 30) Chloroform 5.22 83 320024 44.94 ug/l 100 31) Cyclohexane 5.58 56 276493 46.40 ug/l 100 32) 1,1,1-Trichloroethane 5.50 97 285448 45.93 ug/l 100 36) 1,1-Dichloropropene 5.81 75 239960 44.96 ug/l 100 37) Ethyl Acetate 4.87 43 251215 43.25 ug/l 100 38) Carbon Tetrachloride 5.79 117 256920 45.42 ug/l 100 39) Methylcyclohexane 7.46 83 291296 46.16 ug/l 100 40) Benzene 6.15 78 713540 45.78 ug/l 100 41) Methacrylonitrile 5.07 41 143358 43.01 ug/l 100 42) 1,2-Dichloroethane 6.20 62 253865 42.80 ug/l 100 43) Isopropyl Acetate 6.48 43 404657 45.34 ug/l 100 44) Trichloroethene 7.22 130 221095 46.16 ug/l 100 45) 1,2-Dichloropropane 7.53 63 175431 45.12 ug/l 100 46) Dibromomethane 7.67 93 122149 44.55 ug/l 100 47) Bromodichloromethane 7.90 83 236890 46.72 ug/l 100 48) Methyl methacrylate 7.79 41 215753 44.54 ug/l 100 49) 1,4-Dioxane 7.76 88 79362 774.86 ug/l 100 51) 4-Methyl-2-Pentanone 8.66 43 1310355 221.63 ug/l 100 52) Toluene 8.79 92 470850 46.21 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 286202 49.70 ug/l 100 54) cis-1,3-Dichloropropene 9.05 75 243495 47.09 ug/l 100 55) 1,1,2-Trichloroethane 9.22 97 174609 42.91 ug/l 100 56) Ethyl methacrylate 9.19 69 261529 44.75 ug/l 100 57) 1,3-Dichloropropane 9.38 76 289975 43.18 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 698316 241.30 ug/l 100 59) 2-Hexanone 9.50 43 935754 209.28 ug/l 100 60) Dibromochloromethane 9.59 129 190737 46.08 ug/l 100 61) 1,2-Dibromoethane 9.68 107 186849 43.88 ug/l 100 64) Tetrachloroethene 9.34 164 242587 46.86 ug/l 100 65) Chlorobenzene 10.15 112 504298 46.25 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 184934 47.56 ug/l 100 67) Ethyl Benzene 10.26 91 835869 46.82 ug/l 100 68) m/p-Xylenes 10.37 106 667881 94.77 ug/l 100 69) o-Xylene 10.71 106 321020 46.99 ug/l 100 70) Styrene 10.72 104 536425 48.24 ug/l 100 71) Bromoform 10.86 173 156779 49.30 ug/l 100 73) Isopropylbenzene 11.02 105 854405 48.94 ug/l 100 74) N-amyl acetate 6.48 43 404657 50.48 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 242487 47.07 ug/l 100 76) 1,2,3-Trichloropropane 11.30 75 246688m 48.13 ug/l 77) Bromobenzene 11.26 156 244565 48.03 ug/l 100 78) n-propylbenzene 11.37 91 955428 50.16 ug/l 100 79) 2-Chlorotoluene 11.43 91 562078 48.13 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 711400 49.03 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 74228 54.91 ug/l 100 82) 4-Chlorotoluene 11.52 91 660885 49.02 ug/l 100 83) tert-Butylbenzene 11.77 119 694701 48.28 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 736776 49.39 ug/l 100 85) sec-Butylbenzene 11.95 105 862052 49.70 ug/l 100 86) p-Isopropyltoluene 12.07 119 792743 49.93 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 441891 48.62 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 447638 48.27 ug/l 100 89) n-Butylbenzene 12.40 91 681083 51.43 ug/l 100 90) Hexachloroethane 12.60 117 126685 52.42 ug/l 100 91) 1,2-Dichlorobenzene 12.40 146 440252 47.73 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 56185 49.84 ug/l 100 93) 1,2,4-Trichlorobenzene 13.65 180 358326 52.47 ug/l 100 94) Hexachlorobutadiene 13.79 225 188771 50.57 ug/l 100 95) Naphthalene 13.84 128 980216 52.25 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 357463 51.24 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed