Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051518\ Data File : VX001717.D Acq On : 14 May 2018 18:43 Operator : JC/MD Sample : VSTDICC100 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 13 Sample Multiplier: 1 Quant Time: May 15 01:26:41 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:02:23 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 332719 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 441862 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 383795 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 265600 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 420713 89.46 ug/l 0.00 Spiked Amount 50.000 Recovery = 178.92% 35) Dibromofluoromethane 5.51 113 364524 93.86 ug/l 0.00 Spiked Amount 50.000 Recovery = 187.72% 50) Toluene-d8 8.72 98 1382278 97.27 ug/l 0.00 Spiked Amount 50.000 Recovery = 194.54% 62) 4-Bromofluorobenzene 11.14 95 476898 89.09 ug/l 0.00 Spiked Amount 50.000 Recovery = 178.18% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 325436 76.23 ug/l 100 3) Chloromethane 1.32 50 332898 78.62 ug/l 100 4) Vinyl Chloride 1.40 62 379529 85.33 ug/l 100 5) Bromomethane 1.64 94 158671 61.35 ug/l 97 6) Chloroethane 1.71 64 237583 81.37 ug/l 99 7) Trichlorofluoromethane 1.92 101 543990 81.78 ug/l 98 8) Diethyl Ether 2.19 74 227777 86.75 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.38 101 321156 82.13 ug/l 99 10) Methyl Iodide 2.51 142 347533 66.21 ug/l 99 11) Tert butyl alcohol 3.09 59 380116 395.21 ug/l 100 12) 1,1-Dichloroethene 2.37 96 313273 86.84 ug/l 98 13) Acrolein 2.30 56 271199 902.97 ug/l 99 14) Allyl chloride 2.73 41 603957 89.65 ug/l 99 15) Acrylonitrile 3.16 53 977124 437.88 ug/l 99 16) Acetone 2.45 43 815937 387.60 ug/l 99 17) Carbon Disulfide 2.56 76 842877 91.91 ug/l 99 18) Methyl Acetate 2.78 43 518634 91.88 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 1083262 86.23 ug/l 99 20) Methylene Chloride 2.85 84 349193 82.90 ug/l 99 21) trans-1,2-Dichloroethene 3.16 96 342409 84.87 ug/l 98 22) Diisopropyl ether 3.88 45 1159829 91.68 ug/l 99 23) Vinyl Acetate 3.83 43 3966342 388.42 ug/l 100 24) 1,1-Dichloroethane 3.70 63 610529 86.89 ug/l 100 25) 2-Butanone 4.72 43 1361590 442.63 ug/l 98 26) 2,2-Dichloropropane 4.59 77 512155 93.86 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 403659 92.93 ug/l 99 28) Bromochloromethane 5.03 49 277984 89.91 ug/l 99 29) Tetrahydrofuran 5.18 42 887618 449.69 ug/l 99 30) Chloroform 5.22 83 650800 89.45 ug/l 99 31) Cyclohexane 5.57 56 569016 93.47 ug/l 99 32) 1,1,1-Trichloroethane 5.50 97 587192 92.48 ug/l 99 36) 1,1-Dichloropropene 5.80 75 495117 89.40 ug/l 100 37) Ethyl Acetate 4.87 43 528320 87.66 ug/l 100 38) Carbon Tetrachloride 5.79 117 532215 90.68 ug/l 100 39) Methylcyclohexane 7.46 83 611957 93.46 ug/l 99 40) Benzene 6.15 78 1471064 90.96 ug/l 99 41) Methacrylonitrile 5.07 41 304820 88.13 ug/l 99 42) 1,2-Dichloroethane 6.20 62 514346 83.57 ug/l 100 43) Isopropyl Acetate 6.48 43 864959 93.41 ug/l 99 44) Trichloroethene 7.22 130 451887 90.93 ug/l 98 45) 1,2-Dichloropropane 7.52 63 363012 89.98 ug/l 99 46) Dibromomethane 7.67 93 249946 87.85 ug/l 98 47) Bromodichloromethane 7.90 83 501534 95.33 ug/l 98 48) Methyl methacrylate 7.79 41 458611 91.25 ug/l 98 49) 1,4-Dioxane 7.77 88 181722 1710.02 ug/l 97 51) 4-Methyl-2-Pentanone 8.66 43 2767276 451.10 ug/l 99 52) Toluene 8.79 92 974333 92.17 ug/l 99 53) t-1,3-Dichloropropene 8.45 75 615429 103.00 ug/l 100 54) cis-1,3-Dichloropropene 9.05 75 524977 97.86 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 351336 83.22 ug/l 99 56) Ethyl methacrylate 9.19 69 550103 90.73 ug/l 99 57) 1,3-Dichloropropane 9.38 76 589714 84.64 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 1457263 485.31 ug/l 100 59) 2-Hexanone 9.51 43 1949051 420.13 ug/l 99 60) Dibromochloromethane 9.59 129 403372 93.92 ug/l 100 61) 1,2-Dibromoethane 9.68 107 381901 86.43 ug/l 99 64) Tetrachloroethene 9.34 164 472104 89.34 ug/l 99 65) Chlorobenzene 10.15 112 1031098 92.63 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 385070 97.01 ug/l 99 67) Ethyl Benzene 10.26 91 1701037 93.33 ug/l 99 68) m/p-Xylenes 10.37 106 1359055 188.92 ug/l 99 69) o-Xylene 10.71 106 661456 94.85 ug/l 99 70) Styrene 10.72 104 1106858 97.51 ug/l 100 71) Bromoform 10.87 173 351018 108.13 ug/l 99 73) Isopropylbenzene 11.02 105 1743659 95.04 ug/l 100 74) N-amyl acetate 6.48 43 864959 102.69 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 517349 95.57 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 501576m 93.12 ug/l 77) Bromobenzene 11.26 156 503979 94.19 ug/l 100 78) n-propylbenzene 11.37 91 1955884 97.72 ug/l 100 79) 2-Chlorotoluene 11.43 91 1155695 94.18 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 1458655 95.66 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 170800 120.23 ug/l 95 82) 4-Chlorotoluene 11.52 91 1358866 95.91 ug/l 100 83) tert-Butylbenzene 11.77 119 1496663 98.98 ug/l 97 84) 1,2,4-Trimethylbenzene 11.81 105 1516197 96.72 ug/l 100 85) sec-Butylbenzene 11.95 105 1781675 97.75 ug/l 100 86) p-Isopropyltoluene 12.07 119 1656651 99.29 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 929918 97.36 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 936217 96.06 ug/l 100 89) n-Butylbenzene 12.40 91 1437079 103.26 ug/l 99 90) Hexachloroethane 12.60 117 280868 110.59 ug/l 98 91) 1,2-Dichlorobenzene 12.40 146 922384 95.15 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 122126 103.08 ug/l 97 93) 1,2,4-Trichlorobenzene 13.65 180 749544 104.45 ug/l 99 94) Hexachlorobutadiene 13.79 225 396404 101.05 ug/l 100 95) Naphthalene 13.84 128 2037055 103.32 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 742438 101.27 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed