Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051518\ Data File : VX001718.D Acq On : 14 May 2018 19:10 Operator : JC/MD Sample : VSTDICC150 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 14 Sample Multiplier: 1 Quant Time: May 15 01:29:06 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:02:23 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 323255 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 430731 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 372523 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 260621 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 598393 130.97 ug/l 0.00 Spiked Amount 50.000 Recovery = 261.94% 35) Dibromofluoromethane 5.51 113 518871 137.05 ug/l 0.00 Spiked Amount 50.000 Recovery = 274.10% 50) Toluene-d8 8.72 98 1923621 138.86 ug/l 0.00 Spiked Amount 50.000 Recovery = 277.72% 62) 4-Bromofluorobenzene 11.15 95 683123 130.92 ug/l 0.00 Spiked Amount 50.000 Recovery = 261.84% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.19 85 464040 111.88 ug/l 99 3) Chloromethane 1.32 50 513338 124.79 ug/l 99 4) Vinyl Chloride 1.40 62 544717 126.06 ug/l 100 5) Bromomethane 1.64 94 228309 90.86 ug/l 98 6) Chloroethane 1.70 64 303619 107.03 ug/l 100 7) Trichlorofluoromethane 1.92 101 767435 118.75 ug/l 99 8) Diethyl Ether 2.19 74 329171 129.04 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.37 101 458762 120.76 ug/l 99 10) Methyl Iodide 2.51 142 512723 100.53 ug/l 98 11) Tert butyl alcohol 3.10 59 603394 645.72 ug/l 98 12) 1,1-Dichloroethene 2.37 96 447486 127.67 ug/l 98 13) Acrolein 2.30 56 428212 1467.50 ug/l 100 14) Allyl chloride 2.73 41 862400 131.76 ug/l 98 15) Acrylonitrile 3.16 53 1454042 670.67 ug/l 100 16) Acetone 2.46 43 1195690 584.63 ug/l 100 17) Carbon Disulfide 2.56 76 1236608 138.78 ug/l 99 18) Methyl Acetate 2.78 43 750026 136.76 ug/l 98 19) Methyl tert-butyl Ether 3.21 73 1568392 128.50 ug/l 100 20) Methylene Chloride 2.85 84 505634 123.55 ug/l 98 21) trans-1,2-Dichloroethene 3.16 96 488432 124.60 ug/l 98 22) Diisopropyl ether 3.88 45 1675714 136.33 ug/l 99 23) Vinyl Acetate 3.83 43 5777456 582.35 ug/l 99 24) 1,1-Dichloroethane 3.70 63 881465 129.13 ug/l 100 25) 2-Butanone 4.72 43 2020512 676.07 ug/l 98 26) 2,2-Dichloropropane 4.59 77 727074 137.15 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 586457 138.96 ug/l 98 28) Bromochloromethane 5.03 49 391416 130.31 ug/l 98 29) Tetrahydrofuran 5.18 42 1317736 687.14 ug/l 99 30) Chloroform 5.23 83 932493 131.93 ug/l 99 31) Cyclohexane 5.57 56 815737 137.91 ug/l 99 32) 1,1,1-Trichloroethane 5.50 97 838356 135.90 ug/l 99 36) 1,1-Dichloropropene 5.80 75 706925 130.94 ug/l 100 37) Ethyl Acetate 4.88 43 785265 133.67 ug/l 100 38) Carbon Tetrachloride 5.79 117 762298 133.23 ug/l 99 39) Methylcyclohexane 7.46 83 880480 137.94 ug/l 99 40) Benzene 6.15 78 2107160 133.65 ug/l 100 41) Methacrylonitrile 5.07 41 451089 133.80 ug/l 99 42) 1,2-Dichloroethane 6.20 62 742423 123.75 ug/l 99 43) Isopropyl Acetate 6.48 43 1287808 142.67 ug/l 99 44) Trichloroethene 7.22 130 645496 133.24 ug/l 98 45) 1,2-Dichloropropane 7.52 63 534052 135.80 ug/l 98 46) Dibromomethane 7.67 93 364284 131.35 ug/l 98 47) Bromodichloromethane 7.90 83 729035 142.15 ug/l 98 48) Methyl methacrylate 7.79 41 682720 139.36 ug/l 98 49) 1,4-Dioxane 7.77 88 274992 2654.56 ug/l 97 51) 4-Methyl-2-Pentanone 8.66 43 4098317 685.35 ug/l 98 52) Toluene 8.79 92 1366106 132.57 ug/l 99 53) t-1,3-Dichloropropene 8.45 75 900650 154.63 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 844390 161.47 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 510451 124.03 ug/l 100 56) Ethyl methacrylate 9.19 69 875677 148.15 ug/l 99 57) 1,3-Dichloropropane 9.38 76 849528 125.08 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 1823424 622.95 ug/l 99 59) 2-Hexanone 9.51 43 2892966 639.71 ug/l 98 60) Dibromochloromethane 9.59 129 594752 142.05 ug/l 99 61) 1,2-Dibromoethane 9.68 107 550059 127.71 ug/l 100 64) Tetrachloroethene 9.34 164 649043 126.54 ug/l 99 65) Chlorobenzene 10.15 112 1475933 136.61 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 562413 145.98 ug/l 99 67) Ethyl Benzene 10.26 91 2447671 138.36 ug/l 100 68) m/p-Xylenes 10.37 106 1938706 277.65 ug/l 99 69) o-Xylene 10.71 106 947553 139.99 ug/l 99 70) Styrene 10.72 104 1602739 145.47 ug/l 100 71) Bromoform 10.87 173 535093 169.82 ug/l 99 73) Isopropylbenzene 11.02 105 2494135 138.54 ug/l 100 74) N-amyl acetate 6.48 43 1287808 155.81 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 777302 146.34 ug/l 100 76) 1,2,3-Trichloropropane 11.30 75 731248m 138.35 ug/l 77) Bromobenzene 11.26 156 732518 139.51 ug/l 100 78) n-propylbenzene 11.37 91 2791687 142.14 ug/l 99 79) 2-Chlorotoluene 11.43 91 1668179 138.54 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 2110107 141.02 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.09 75 266576 191.24 ug/l 93 82) 4-Chlorotoluene 11.52 91 1980029 142.42 ug/l 100 83) tert-Butylbenzene 11.78 119 2170527 146.29 ug/l 97 84) 1,2,4-Trimethylbenzene 11.82 105 2189287 142.32 ug/l 99 85) sec-Butylbenzene 11.95 105 2574778 143.97 ug/l 99 86) p-Isopropyltoluene 12.07 119 2413570 147.42 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 1351471 144.20 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 1370005 143.25 ug/l 99 89) n-Butylbenzene 12.40 91 2079346 152.26 ug/l 99 90) Hexachloroethane 12.60 117 423389 169.88 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 1342384 141.13 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 186728 160.62 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 1108138 157.38 ug/l 99 94) Hexachlorobutadiene 13.79 225 579325 150.50 ug/l 100 95) Naphthalene 13.84 128 3022358 156.23 ug/l 100 96) 1,2,3-Trichlorobenzene 14.03 180 1096160 152.37 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed