Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051518\ Data File : VX001719.D Acq On : 14 May 2018 19:36 Operator : JC/MD Sample : VSTDICV050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 15 Sample Multiplier: 1 Quant Time: May 15 05:48:12 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 329960 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 438645 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 379452 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 253000 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 221604 50.11 ug/l 0.00 Spiked Amount 50.000 Recovery = 100.22% 35) Dibromofluoromethane 5.51 113 188930 51.04 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.08% 50) Toluene-d8 8.72 98 710280 53.57 ug/l 0.00 Spiked Amount 50.000 Recovery = 107.14% 62) 4-Bromofluorobenzene 11.14 95 243429 51.00 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.00% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 160889 48.59 ug/l 99 3) Chloromethane 1.32 50 195109 54.55 ug/l 99 4) Vinyl Chloride 1.40 62 193743 50.10 ug/l 99 5) Bromomethane 1.64 94 87035 53.71 ug/l 98 6) Chloroethane 1.72 64 121673 49.95 ug/l 98 7) Trichlorofluoromethane 1.93 101 273585 48.69 ug/l 98 8) Diethyl Ether 2.19 74 116456 50.35 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.38 101 160551 47.46 ug/l 99 10) Methyl Iodide 2.51 142 118043 37.93 ug/l 99 11) Tert butyl alcohol 3.09 59 195665 249.19 ug/l 100 12) 1,1-Dichloroethene 2.37 96 159437 48.89 ug/l 99 13) Acrolein 2.30 56 156312 280.68 ug/l 99 14) Allyl chloride 2.73 41 305599 50.69 ug/l 98 15) Acrylonitrile 3.15 53 501447 254.26 ug/l 100 16) Acetone 2.45 43 416668 239.86 ug/l 99 17) Carbon Disulfide 2.57 76 431957 50.78 ug/l 99 18) Methyl Acetate 2.78 43 264149 52.01 ug/l 98 19) Methyl tert-butyl Ether 3.21 73 559501 50.90 ug/l 99 20) Methylene Chloride 2.86 84 179145 48.18 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 176107 49.02 ug/l 97 22) Diisopropyl ether 3.88 45 586764 50.74 ug/l 99 23) Vinyl Acetate 3.83 43 2019171 242.34 ug/l 100 24) 1,1-Dichloroethane 3.70 63 312116 49.21 ug/l 99 25) 2-Butanone 4.72 43 693620 260.81 ug/l 97 26) 2,2-Dichloropropane 4.59 77 246705 48.32 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 206363 50.48 ug/l 99 28) Bromochloromethane 5.03 49 151479 53.77 ug/l 100 29) Tetrahydrofuran 5.17 42 453907 261.83 ug/l 99 30) Chloroform 5.22 83 329782 49.50 ug/l 100 31) Cyclohexane 5.57 56 285542 51.36 ug/l 99 32) 1,1,1-Trichloroethane 5.50 97 293880 51.05 ug/l 99 36) 1,1-Dichloropropene 5.81 75 249498 49.41 ug/l 99 37) Ethyl Acetate 4.87 43 269781 51.27 ug/l 100 38) Carbon Tetrachloride 5.79 117 266924 50.46 ug/l 99 39) Methylcyclohexane 7.46 83 298138 50.53 ug/l 99 40) Benzene 6.15 78 747849 50.27 ug/l 100 41) Methacrylonitrile 5.07 41 154266 50.69 ug/l 99 42) 1,2-Dichloroethane 6.20 62 263739 49.02 ug/l 99 43) Isopropyl Acetate 6.48 43 434344 52.74 ug/l 99 44) Trichloroethene 7.22 130 231743 50.19 ug/l 97 45) 1,2-Dichloropropane 7.53 63 183568 50.28 ug/l 98 46) Dibromomethane 7.67 93 125949 49.13 ug/l 98 47) Bromodichloromethane 7.90 83 247392 52.01 ug/l 98 48) Methyl methacrylate 7.79 41 229108 52.85 ug/l 99 49) 1,4-Dioxane 7.76 88 92817 1111.97 ug/l 97 51) 4-Methyl-2-Pentanone 8.66 43 1396887 267.63 ug/l 100 52) Toluene 8.79 92 489460 51.20 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 301619 53.89 ug/l 98 54) cis-1,3-Dichloropropene 9.05 75 256454 51.98 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 179484 49.12 ug/l 98 56) Ethyl methacrylate 9.19 69 274789 53.03 ug/l 98 57) 1,3-Dichloropropane 9.38 76 297371 48.61 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 728821 273.41 ug/l 99 59) 2-Hexanone 9.51 43 976369 261.31 ug/l 99 60) Dibromochloromethane 9.59 129 198214 52.97 ug/l 99 61) 1,2-Dibromoethane 9.68 107 193171 50.49 ug/l 100 64) Tetrachloroethene 9.34 164 239136 48.41 ug/l 98 65) Chlorobenzene 10.15 112 514957 49.34 ug/l 98 66) 1,1,1,2-Tetrachloroethane 10.23 131 191079 51.83 ug/l 98 67) Ethyl Benzene 10.26 91 856383 51.34 ug/l 100 68) m/p-Xylenes 10.37 106 677491 102.94 ug/l 99 69) o-Xylene 10.71 106 330306 52.41 ug/l 99 70) Styrene 10.72 104 554302 53.32 ug/l 99 71) Bromoform 10.87 173 163420 47.77 ug/l # 100 73) Isopropylbenzene 11.02 105 878155 52.70 ug/l 100 74) N-amyl acetate 6.48 43 434344 54.38 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 256101 51.24 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 251368m 52.25 ug/l 77) Bromobenzene 11.26 156 252524 51.58 ug/l 100 78) n-propylbenzene 11.37 91 983538 52.40 ug/l 100 79) 2-Chlorotoluene 11.43 91 580663 51.72 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 726283 53.13 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 76693 47.67 ug/l 98 82) 4-Chlorotoluene 11.52 91 683252 51.66 ug/l 100 83) tert-Butylbenzene 11.77 119 739015 54.33 ug/l 98 84) 1,2,4-Trimethylbenzene 11.81 105 754794 53.32 ug/l 100 85) sec-Butylbenzene 11.95 105 887111 52.83 ug/l 100 86) p-Isopropyltoluene 12.07 119 818335 52.67 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 458351 50.62 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 467115 49.89 ug/l 100 89) n-Butylbenzene 12.40 91 698779 52.00 ug/l 100 90) Hexachloroethane 12.60 117 130311 54.00 ug/l 98 91) 1,2-Dichlorobenzene 12.40 146 454714 50.40 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 58742 55.07 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 376401 52.34 ug/l 99 94) Hexachlorobutadiene 13.79 225 191463 49.59 ug/l 99 95) Naphthalene 13.84 128 1026125 54.90 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 373680 51.61 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed