Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051518\ Data File : VX001721.D Acq On : 14 May 2018 20:56 Operator : JC/MD Sample : VX0515WBS01 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 18 Sample Multiplier: 1 Quant Time: May 15 05:54:19 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 312469 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 427265 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 380502 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 247630 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 218152 52.09 ug/l 0.00 Spiked Amount 50.000 Recovery = 104.18% 35) Dibromofluoromethane 5.51 113 177974 49.36 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.72% 50) Toluene-d8 8.72 98 660133 51.12 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.24% 62) 4-Bromofluorobenzene 11.14 95 232337 49.97 ug/l 0.00 Spiked Amount 50.000 Recovery = 99.94% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 62519 19.94 ug/l 100 3) Chloromethane 1.32 50 72087 21.28 ug/l 97 4) Vinyl Chloride 1.40 62 77338 21.12 ug/l 100 5) Bromomethane 1.64 94 48316 30.08 ug/l 97 6) Chloroethane 1.73 64 50237 21.78 ug/l 99 7) Trichlorofluoromethane 1.93 101 108214 20.34 ug/l 100 8) Diethyl Ether 2.19 74 48327 22.06 ug/l 95 9) 1,1,2-Trichlorotrifluoroet 2.39 101 62544 19.52 ug/l 99 10) Methyl Iodide 2.51 142 30472 10.34 ug/l 99 11) Tert butyl alcohol 3.08 59 85347 114.78 ug/l 99 12) 1,1-Dichloroethene 2.37 96 63742 20.64 ug/l 96 13) Acrolein 2.30 56 54530 103.40 ug/l 98 14) Allyl chloride 2.73 41 120112 21.04 ug/l 99 15) Acrylonitrile 3.15 53 205696 110.14 ug/l 100 16) Acetone 2.45 43 172659 104.96 ug/l 99 17) Carbon Disulfide 2.57 76 159740 19.83 ug/l 99 18) Methyl Acetate 2.78 43 108754 22.61 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 226997 21.81 ug/l 99 20) Methylene Chloride 2.86 84 73809 20.96 ug/l 100 21) trans-1,2-Dichloroethene 3.17 96 69975 20.57 ug/l 97 22) Diisopropyl ether 3.88 45 230916 21.09 ug/l 99 23) Vinyl Acetate 3.83 43 783184 99.26 ug/l 100 24) 1,1-Dichloroethane 3.70 63 124996 20.81 ug/l 99 25) 2-Butanone 4.71 43 278298 110.50 ug/l 98 26) 2,2-Dichloropropane 4.59 77 93522 19.34 ug/l 100 27) cis-1,2-Dichloroethene 4.60 96 81526 21.06 ug/l 99 28) Bromochloromethane 5.03 49 54899 20.58 ug/l 99 29) Tetrahydrofuran 5.18 42 179990 109.64 ug/l 99 30) Chloroform 5.22 83 134450 21.31 ug/l 98 31) Cyclohexane 5.57 56 103790 19.72 ug/l 99 32) 1,1,1-Trichloroethane 5.50 97 114362 20.98 ug/l 99 36) 1,1-Dichloropropene 5.81 75 94388 19.19 ug/l 99 37) Ethyl Acetate 4.87 43 106878 20.85 ug/l 99 38) Carbon Tetrachloride 5.79 117 101168 19.63 ug/l 98 39) Methylcyclohexane 7.46 83 107028 18.62 ug/l 96 40) Benzene 6.15 78 293920 20.28 ug/l 98 41) Methacrylonitrile 5.07 41 61570 20.77 ug/l 99 42) 1,2-Dichloroethane 6.20 62 110011 20.99 ug/l 100 43) Isopropyl Acetate 6.48 43 166541 20.76 ug/l 100 44) Trichloroethene 7.22 130 88414 19.66 ug/l 96 45) 1,2-Dichloropropane 7.52 63 73411 20.64 ug/l 99 46) Dibromomethane 7.67 93 50516 20.23 ug/l 99 47) Bromodichloromethane 7.90 83 94942 20.49 ug/l 98 48) Methyl methacrylate 7.79 41 89792 21.26 ug/l 99 49) 1,4-Dioxane 7.76 88 36889 453.71 ug/l 99 51) 4-Methyl-2-Pentanone 8.66 43 556109 109.38 ug/l 99 52) Toluene 8.79 92 190263 20.43 ug/l 99 53) t-1,3-Dichloropropene 8.44 75 113741 20.86 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 100489 20.91 ug/l 97 55) 1,1,2-Trichloroethane 9.22 97 76378 21.46 ug/l 97 56) Ethyl methacrylate 9.19 69 111364 22.06 ug/l 98 57) 1,3-Dichloropropane 9.38 76 122248 20.51 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 280900 108.18 ug/l 100 59) 2-Hexanone 9.51 43 400070 109.93 ug/l 99 60) Dibromochloromethane 9.59 129 75899 20.82 ug/l 100 61) 1,2-Dibromoethane 9.68 107 79120 21.23 ug/l 100 64) Tetrachloroethene 9.34 164 95753 19.33 ug/l 98 65) Chlorobenzene 10.15 112 206855 19.76 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 74394 20.12 ug/l 99 67) Ethyl Benzene 10.26 91 327545 19.58 ug/l 99 68) m/p-Xylenes 10.37 106 262005 39.70 ug/l 99 69) o-Xylene 10.71 106 127570 20.18 ug/l 100 70) Styrene 10.72 104 213699 20.50 ug/l 100 71) Bromoform 10.86 173 61129 19.66 ug/l 99 73) Isopropylbenzene 11.02 105 335614 20.58 ug/l 99 74) N-amyl acetate 6.48 43 166541 21.30 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 104283 21.32 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 103184m 21.91 ug/l 77) Bromobenzene 11.26 156 100226 20.92 ug/l 99 78) n-propylbenzene 11.37 91 369772 20.13 ug/l 100 79) 2-Chlorotoluene 11.43 91 224880 20.47 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 277635 20.75 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 26591 19.02 ug/l 93 82) 4-Chlorotoluene 11.52 91 265881 20.54 ug/l 100 83) tert-Butylbenzene 11.77 119 278700 20.93 ug/l 98 84) 1,2,4-Trimethylbenzene 11.81 105 289945 20.93 ug/l 100 85) sec-Butylbenzene 11.95 105 332920 20.26 ug/l 100 86) p-Isopropyltoluene 12.07 119 306823 20.18 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 181401 20.47 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 184101 20.09 ug/l 99 89) n-Butylbenzene 12.40 91 256961 19.54 ug/l 100 90) Hexachloroethane 12.60 117 45491 19.26 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 179765 20.36 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 22742 21.78 ug/l 99 93) 1,2,4-Trichlorobenzene 13.65 180 140244 19.93 ug/l 99 94) Hexachlorobutadiene 13.79 225 72247 19.12 ug/l 99 95) Naphthalene 13.84 128 393112 21.49 ug/l 99 96) 1,2,3-Trichlorobenzene 14.02 180 143204 20.21 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed