Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051518\ Data File : VX001732.D Acq On : 15 May 2018 01:50 Operator : JC/MD Sample : J2856-04MS Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 29 Sample Multiplier: 1 Quant Time: May 15 06:50:34 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 309453 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 412853 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 375111 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 250078 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 215569 51.97 ug/l 0.00 Spiked Amount 50.000 Recovery = 103.94% 35) Dibromofluoromethane 5.51 113 184366 52.92 ug/l 0.00 Spiked Amount 50.000 Recovery = 105.84% 50) Toluene-d8 8.72 98 689071 55.22 ug/l 0.00 Spiked Amount 50.000 Recovery = 110.44% 62) 4-Bromofluorobenzene 11.14 95 237294 52.82 ug/l 0.00 Spiked Amount 50.000 Recovery = 105.64% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 145448 46.84 ug/l 97 3) Chloromethane 1.32 50 154330 46.01 ug/l 99 4) Vinyl Chloride 1.40 62 177599 48.97 ug/l 99 5) Bromomethane 1.64 94 70656 46.04 ug/l 99 6) Chloroethane 1.72 64 118725 51.97 ug/l 98 7) Trichlorofluoromethane 1.93 101 258041 48.96 ug/l 98 8) Diethyl Ether 2.19 74 109697 50.57 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.39 101 143851 45.34 ug/l 99 10) Methyl Iodide 2.51 142 71927 24.64 ug/l 98 11) Tert butyl alcohol 3.08 59 178275 242.09 ug/l 100 12) 1,1-Dichloroethene 2.37 96 146989 48.06 ug/l 95 13) Acrolein 2.30 56 125792 240.85 ug/l 100 14) Allyl chloride 2.73 41 279524 49.44 ug/l 99 15) Acrylonitrile 3.15 53 459993 248.70 ug/l 99 16) Acetone 2.45 43 395077 242.51 ug/l 100 17) Carbon Disulfide 2.57 76 390547 48.95 ug/l 98 18) Methyl Acetate 2.78 43 227172 47.70 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 513453 49.81 ug/l 100 20) Methylene Chloride 2.86 84 169465 48.60 ug/l 98 21) trans-1,2-Dichloroethene 3.17 96 164659 48.87 ug/l 100 22) Diisopropyl ether 3.88 45 537698 49.58 ug/l 99 23) Vinyl Acetate 3.83 43 1690082 216.29 ug/l 100 24) 1,1-Dichloroethane 3.70 63 293638 49.37 ug/l 99 25) 2-Butanone 4.71 43 624739 250.47 ug/l 97 26) 2,2-Dichloropropane 4.59 77 188967 39.46 ug/l 98 27) cis-1,2-Dichloroethene 4.60 96 188554 49.18 ug/l 97 28) Bromochloromethane 5.03 49 145792 55.18 ug/l 99 29) Tetrahydrofuran 5.17 42 409383 251.80 ug/l 99 30) Chloroform 5.22 83 314178 50.29 ug/l 99 31) Cyclohexane 5.58 56 256520 49.20 ug/l 98 32) 1,1,1-Trichloroethane 5.50 97 274938 50.93 ug/l 99 36) 1,1-Dichloropropene 5.81 75 228425 48.06 ug/l 99 37) Ethyl Acetate 4.87 43 228782 46.19 ug/l 99 38) Carbon Tetrachloride 5.79 117 247889 49.79 ug/l 98 39) Methylcyclohexane 7.46 83 259105 46.66 ug/l 99 40) Benzene 6.15 78 694576 49.60 ug/l 100 41) Methacrylonitrile 5.07 41 141406 49.37 ug/l 99 42) 1,2-Dichloroethane 6.20 62 250224 49.41 ug/l 99 43) Isopropyl Acetate 6.48 43 374133 48.26 ug/l 100 44) Trichloroethene 7.22 130 211058 48.56 ug/l 97 45) 1,2-Dichloropropane 7.52 63 173674 50.55 ug/l 99 46) Dibromomethane 7.67 93 119110 49.37 ug/l 99 47) Bromodichloromethane 7.90 83 230741 51.54 ug/l 97 48) Methyl methacrylate 7.79 41 209665 51.38 ug/l 100 49) 1,4-Dioxane 7.76 88 83426 1061.90 ug/l 97 51) 4-Methyl-2-Pentanone 8.66 43 1282619 261.09 ug/l 100 52) Toluene 8.79 92 462397 51.39 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 262850 49.90 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 242796 52.29 ug/l 100 55) 1,1,2-Trichloroethane 9.22 97 172096 50.04 ug/l 99 56) Ethyl methacrylate 9.19 69 251805 51.63 ug/l 100 57) 1,3-Dichloropropane 9.38 76 284602 49.43 ug/l 100 59) 2-Hexanone 9.51 43 911709 259.25 ug/l 100 60) Dibromochloromethane 9.59 129 185801 52.75 ug/l 100 61) 1,2-Dibromoethane 9.68 107 180742 50.20 ug/l 99 64) Tetrachloroethene 9.34 164 221596 45.38 ug/l 97 65) Chlorobenzene 10.15 112 492357 47.72 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 181059 49.68 ug/l 98 67) Ethyl Benzene 10.26 91 810206 49.13 ug/l 100 68) m/p-Xylenes 10.37 106 647603 99.54 ug/l 100 69) o-Xylene 10.70 106 313144 50.26 ug/l 100 70) Styrene 10.72 104 518069 50.41 ug/l 100 71) Bromoform 10.87 173 154448 45.80 ug/l 100 73) Isopropylbenzene 11.02 105 829759 50.38 ug/l 100 74) N-amyl acetate 6.48 43 374133 47.39 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 242690 49.12 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 233083m 49.01 ug/l 77) Bromobenzene 11.26 156 237288 49.03 ug/l 100 78) n-propylbenzene 11.37 91 924020 49.80 ug/l 100 79) 2-Chlorotoluene 11.43 91 549411 49.51 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 687785 50.91 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 64570 41.09 ug/l 98 82) 4-Chlorotoluene 11.52 91 639400 48.91 ug/l 100 83) tert-Butylbenzene 11.77 119 698920 51.98 ug/l 97 84) 1,2,4-Trimethylbenzene 11.81 105 717497 51.28 ug/l 99 85) sec-Butylbenzene 11.95 105 832125 50.14 ug/l 100 86) p-Isopropyltoluene 12.07 119 767738 49.99 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 433690 48.46 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 435370 47.05 ug/l 100 89) n-Butylbenzene 12.40 91 641270 48.28 ug/l 100 90) Hexachloroethane 12.60 117 121475 50.93 ug/l 98 91) 1,2-Dichlorobenzene 12.40 146 429910 48.21 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 54784 51.96 ug/l 99 93) 1,2,4-Trichlorobenzene 13.65 180 343778 48.37 ug/l 100 94) Hexachlorobutadiene 13.79 225 170732 44.74 ug/l 99 95) Naphthalene 13.84 128 953403 51.60 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 344813 48.18 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed