Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051518\ Data File : VX001733.D Acq On : 15 May 2018 02:16 Operator : JC/MD Sample : J2856-05MSD Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 30 Sample Multiplier: 1 Quant Time: May 15 06:53:41 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 302310 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 409681 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 360711 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 242598 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 207551 51.22 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.44% 35) Dibromofluoromethane 5.51 113 178591 51.66 ug/l 0.00 Spiked Amount 50.000 Recovery = 103.32% 50) Toluene-d8 8.72 98 662768 53.53 ug/l 0.00 Spiked Amount 50.000 Recovery = 107.06% 62) 4-Bromofluorobenzene 11.14 95 226744 50.86 ug/l 0.00 Spiked Amount 50.000 Recovery = 101.72% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 148663 49.00 ug/l 99 3) Chloromethane 1.32 50 164533 50.21 ug/l 99 4) Vinyl Chloride 1.40 62 183602 51.82 ug/l 100 5) Bromomethane 1.64 94 79402 53.47 ug/l 95 6) Chloroethane 1.72 64 119339 53.48 ug/l 99 7) Trichlorofluoromethane 1.93 101 258180 50.15 ug/l 99 8) Diethyl Ether 2.19 74 109430 51.64 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.39 101 145051 46.80 ug/l 99 10) Methyl Iodide 2.51 142 100713 35.32 ug/l 99 11) Tert butyl alcohol 3.08 59 184626 256.63 ug/l 99 12) 1,1-Dichloroethene 2.37 96 150218 50.27 ug/l 98 13) Acrolein 2.30 56 131613 257.95 ug/l 100 14) Allyl chloride 2.73 41 279677 50.64 ug/l 99 15) Acrylonitrile 3.15 53 465339 257.53 ug/l 100 16) Acetone 2.45 43 390438 245.32 ug/l 100 17) Carbon Disulfide 2.57 76 392398 50.34 ug/l 99 18) Methyl Acetate 2.78 43 231174 49.69 ug/l 98 19) Methyl tert-butyl Ether 3.21 73 519540 51.59 ug/l 99 20) Methylene Chloride 2.86 84 171189 50.25 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 165687 50.34 ug/l 99 22) Diisopropyl ether 3.88 45 544264 51.37 ug/l 99 23) Vinyl Acetate 3.83 43 1748551 229.06 ug/l 100 24) 1,1-Dichloroethane 3.70 63 293049 50.43 ug/l 99 25) 2-Butanone 4.71 43 634567 260.43 ug/l 97 26) 2,2-Dichloropropane 4.59 77 190058 40.63 ug/l 98 27) cis-1,2-Dichloroethene 4.60 96 192098 51.29 ug/l 97 28) Bromochloromethane 5.03 49 143779 55.70 ug/l 99 29) Tetrahydrofuran 5.17 42 415201 261.41 ug/l 100 30) Chloroform 5.22 83 314650 51.55 ug/l 99 31) Cyclohexane 5.58 56 257979 50.65 ug/l 99 32) 1,1,1-Trichloroethane 5.50 97 276392 52.40 ug/l 100 36) 1,1-Dichloropropene 5.81 75 229033 48.56 ug/l 100 37) Ethyl Acetate 4.87 43 233023 47.41 ug/l 99 38) Carbon Tetrachloride 5.79 117 245506 49.69 ug/l 98 39) Methylcyclohexane 7.46 83 261625 47.48 ug/l 98 40) Benzene 6.15 78 702767 50.58 ug/l 100 41) Methacrylonitrile 5.07 41 142904 50.28 ug/l 99 42) 1,2-Dichloroethane 6.20 62 248902 49.53 ug/l 100 43) Isopropyl Acetate 6.48 43 380341 49.44 ug/l 100 44) Trichloroethene 7.22 130 210438 48.79 ug/l 100 45) 1,2-Dichloropropane 7.52 63 173372 50.85 ug/l 100 46) Dibromomethane 7.67 93 120153 50.19 ug/l 98 47) Bromodichloromethane 7.90 83 234225 52.72 ug/l 98 48) Methyl methacrylate 7.79 41 212970 52.60 ug/l 99 49) 1,4-Dioxane 7.76 88 84592 1085.08 ug/l 97 51) 4-Methyl-2-Pentanone 8.66 43 1291854 265.00 ug/l 100 52) Toluene 8.79 92 463701 51.93 ug/l 99 53) t-1,3-Dichloropropene 8.44 75 268098 51.29 ug/l 100 54) cis-1,3-Dichloropropene 9.05 75 244919 53.15 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 172747 50.61 ug/l 99 56) Ethyl methacrylate 9.19 69 252513 52.17 ug/l 99 57) 1,3-Dichloropropane 9.38 76 283024 49.53 ug/l 100 59) 2-Hexanone 9.51 43 905489 259.48 ug/l 100 60) Dibromochloromethane 9.59 129 187248 53.58 ug/l 100 61) 1,2-Dibromoethane 9.68 107 181870 50.90 ug/l 99 64) Tetrachloroethene 9.34 164 216707 46.15 ug/l 97 65) Chlorobenzene 10.14 112 486730 49.06 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 179364 51.18 ug/l 99 67) Ethyl Benzene 10.26 91 798513 50.36 ug/l 100 68) m/p-Xylenes 10.37 106 639848 102.27 ug/l 100 69) o-Xylene 10.71 106 310115 51.76 ug/l 99 70) Styrene 10.72 104 519739 52.60 ug/l 100 71) Bromoform 10.87 173 153675 47.29 ug/l 100 73) Isopropylbenzene 11.02 105 815330 51.03 ug/l 100 74) N-amyl acetate 6.48 43 380341 49.66 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 242724 50.65 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 234624m 50.86 ug/l 77) Bromobenzene 11.26 156 239598 51.04 ug/l 99 78) n-propylbenzene 11.37 91 914618 50.81 ug/l 100 79) 2-Chlorotoluene 11.43 91 541658 50.32 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 679225 51.82 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 64949 42.49 ug/l 98 82) 4-Chlorotoluene 11.52 91 636305 50.18 ug/l 100 83) tert-Butylbenzene 11.77 119 690771 52.96 ug/l 97 84) 1,2,4-Trimethylbenzene 11.81 105 704359 51.89 ug/l 100 85) sec-Butylbenzene 11.95 105 820356 50.95 ug/l 100 86) p-Isopropyltoluene 12.07 119 753314 50.56 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 430062 49.54 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 435697 48.53 ug/l 99 89) n-Butylbenzene 12.40 91 630476 48.93 ug/l 99 90) Hexachloroethane 12.60 117 122028 52.74 ug/l 100 91) 1,2-Dichlorobenzene 12.40 146 430129 49.72 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 54319 53.10 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 340805 49.43 ug/l 99 94) Hexachlorobutadiene 13.79 225 167771 45.32 ug/l 99 95) Naphthalene 13.84 128 955894 53.33 ug/l 100 96) 1,2,3-Trichlorobenzene 14.03 180 345672 49.78 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed