Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051518\ Data File : VX001735.D Acq On : 15 May 2018 10:12 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 2 Sample Multiplier: 1 Quant Time: May 16 04:14:49 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 342483 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 429533 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 376090 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 257394 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 212050 46.19 ug/l 0.00 Spiked Amount 50.000 Recovery = 92.38% 35) Dibromofluoromethane 5.51 113 180171 49.70 ug/l 0.00 Spiked Amount 50.000 Recovery = 99.40% 50) Toluene-d8 8.72 98 685457 52.80 ug/l 0.00 Spiked Amount 50.000 Recovery = 105.60% 62) 4-Bromofluorobenzene 11.14 95 237231 50.75 ug/l 0.00 Spiked Amount 50.000 Recovery = 101.50% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 186329 54.21 ug/l 99 3) Chloromethane 1.32 50 183037 49.30 ug/l 100 4) Vinyl Chloride 1.40 62 205941 51.31 ug/l 99 5) Bromomethane 1.64 94 82636 48.84 ug/l 99 6) Chloroethane 1.72 64 130524 51.63 ug/l 98 7) Trichlorofluoromethane 1.93 101 310965 53.32 ug/l 99 8) Diethyl Ether 2.19 74 122683 51.10 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.39 101 189685 54.02 ug/l 100 10) Methyl Iodide 2.51 142 109769 33.98 ug/l 100 11) Tert butyl alcohol 3.07 59 193987 238.02 ug/l 100 12) 1,1-Dichloroethene 2.37 96 172491 50.96 ug/l 99 13) Acrolein 2.29 56 157147 271.86 ug/l 100 14) Allyl chloride 2.73 41 323383 51.68 ug/l 99 15) Acrylonitrile 3.15 53 492341 240.51 ug/l 100 16) Acetone 2.45 43 494800 274.43 ug/l 100 17) Carbon Disulfide 2.57 76 455604 51.60 ug/l 99 18) Methyl Acetate 2.78 43 262030 49.71 ug/l 98 19) Methyl tert-butyl Ether 3.21 73 581135 50.93 ug/l 100 20) Methylene Chloride 2.86 84 191115 49.52 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 188469 50.54 ug/l 98 22) Diisopropyl ether 3.87 45 609710 50.80 ug/l 97 23) Vinyl Acetate 3.82 43 2081726 240.71 ug/l 100 24) 1,1-Dichloroethane 3.70 63 337595 51.28 ug/l 100 25) 2-Butanone 4.71 43 706037 255.77 ug/l 98 26) 2,2-Dichloropropane 4.59 77 287430 54.24 ug/l 100 27) cis-1,2-Dichloroethene 4.60 96 214704 50.60 ug/l 99 28) Bromochloromethane 5.03 49 160930 55.04 ug/l 99 29) Tetrahydrofuran 5.17 42 437193 242.97 ug/l 100 30) Chloroform 5.22 83 353897 51.18 ug/l 99 31) Cyclohexane 5.57 56 320044 55.47 ug/l 99 32) 1,1,1-Trichloroethane 5.49 97 317964 53.21 ug/l 100 36) 1,1-Dichloropropene 5.80 75 274504 55.51 ug/l 100 37) Ethyl Acetate 4.87 43 265618 51.55 ug/l 100 38) Carbon Tetrachloride 5.79 117 292766 56.52 ug/l 99 39) Methylcyclohexane 7.46 83 349407 60.48 ug/l 100 40) Benzene 6.15 78 795251 54.59 ug/l 99 41) Methacrylonitrile 5.07 41 155027 52.02 ug/l 99 42) 1,2-Dichloroethane 6.20 62 279622 53.07 ug/l 100 43) Isopropyl Acetate 6.47 43 429248 53.22 ug/l 100 44) Trichloroethene 7.21 130 248059 54.86 ug/l 98 45) 1,2-Dichloropropane 7.52 63 196305 54.91 ug/l 99 46) Dibromomethane 7.67 93 133237 53.08 ug/l 98 47) Bromodichloromethane 7.90 83 267416 57.41 ug/l 97 48) Methyl methacrylate 7.78 41 230351 54.26 ug/l 99 49) 1,4-Dioxane 7.76 88 90465 1106.78 ug/l 98 51) 4-Methyl-2-Pentanone 8.66 43 1384241 270.83 ug/l 100 52) Toluene 8.79 92 530243 56.64 ug/l 99 53) t-1,3-Dichloropropene 8.44 75 321382 58.64 ug/l 100 54) cis-1,3-Dichloropropene 9.05 75 296759 61.43 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 196819 55.00 ug/l 99 56) Ethyl methacrylate 9.19 69 298497 58.82 ug/l 100 57) 1,3-Dichloropropane 9.38 76 314275 52.46 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 778968 298.42 ug/l 100 59) 2-Hexanone 9.50 43 996851 272.46 ug/l 100 60) Dibromochloromethane 9.59 129 211599 57.75 ug/l 99 61) 1,2-Dibromoethane 9.68 107 200374 53.49 ug/l 99 64) Tetrachloroethene 9.34 164 271343 55.42 ug/l 98 65) Chlorobenzene 10.15 112 556681 53.81 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 205519 56.25 ug/l 99 67) Ethyl Benzene 10.26 91 935056 56.56 ug/l 99 68) m/p-Xylenes 10.37 106 751926 115.27 ug/l 100 69) o-Xylene 10.70 106 359041 57.47 ug/l 99 70) Styrene 10.72 104 595793 57.83 ug/l 100 71) Bromoform 10.86 173 171847 50.50 ug/l 99 73) Isopropylbenzene 11.02 105 962819 56.80 ug/l 100 74) N-amyl acetate 6.47 43 429248 52.82 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 261428 51.41 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 261016m 53.33 ug/l 77) Bromobenzene 11.26 156 272342 54.68 ug/l 99 78) n-propylbenzene 11.37 91 1108713 58.06 ug/l 99 79) 2-Chlorotoluene 11.43 91 634845 55.58 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 806964 58.03 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 80514 49.09 ug/l 98 82) 4-Chlorotoluene 11.52 91 750093 55.75 ug/l 99 83) tert-Butylbenzene 11.77 119 790834 57.15 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 837946 58.19 ug/l 100 85) sec-Butylbenzene 11.95 105 999174 58.49 ug/l 100 86) p-Isopropyltoluene 12.07 119 933143 59.03 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 506105 54.94 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 513164 53.88 ug/l 99 89) n-Butylbenzene 12.40 91 813989 59.54 ug/l 100 90) Hexachloroethane 12.60 117 146798 59.80 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 495727 54.01 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 59053 54.41 ug/l 99 93) 1,2,4-Trichlorobenzene 13.65 180 418486 57.20 ug/l 100 94) Hexachlorobutadiene 13.79 225 223132 56.81 ug/l 100 95) Naphthalene 13.84 128 1063060 55.90 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 410771 55.76 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed