Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051518\ Data File : VX001737.D Acq On : 15 May 2018 11:34 Operator : JC/MD Sample : VX0515WBS02 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 4 Sample Multiplier: 1 Quant Time: May 16 04:24:52 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 356609 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 452431 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 403203 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 269504 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 245459 51.35 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.70% 35) Dibromofluoromethane 5.51 113 206767 54.15 ug/l 0.00 Spiked Amount 50.000 Recovery = 108.30% 50) Toluene-d8 8.72 98 786610 57.52 ug/l 0.00 Spiked Amount 50.000 Recovery = 115.04% 62) 4-Bromofluorobenzene 11.14 95 268950 54.63 ug/l 0.00 Spiked Amount 50.000 Recovery = 109.26% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 80657 22.54 ug/l 97 3) Chloromethane 1.32 50 81204 21.01 ug/l 100 4) Vinyl Chloride 1.40 62 92036 22.02 ug/l 98 5) Bromomethane 1.64 94 45558 24.27 ug/l 99 6) Chloroethane 1.72 64 59113 22.46 ug/l 98 7) Trichlorofluoromethane 1.93 101 136790 22.52 ug/l 99 8) Diethyl Ether 2.19 74 54832 21.93 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.39 101 82806 22.65 ug/l 100 10) Methyl Iodide 2.51 142 46413 13.80 ug/l 98 11) Tert butyl alcohol 3.07 59 95490 112.52 ug/l 99 12) 1,1-Dichloroethene 2.37 96 76254 21.63 ug/l 98 13) Acrolein 2.29 56 63512 105.52 ug/l 99 14) Allyl chloride 2.73 41 144370 22.16 ug/l 99 15) Acrylonitrile 3.15 53 230150 107.98 ug/l 99 16) Acetone 2.45 43 216650 115.40 ug/l 98 17) Carbon Disulfide 2.57 76 194523 21.16 ug/l 98 18) Methyl Acetate 2.78 43 123763 22.55 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 261836 22.04 ug/l 99 20) Methylene Chloride 2.86 84 87265 21.72 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 83492 21.50 ug/l 99 22) Diisopropyl ether 3.88 45 265566 21.25 ug/l 98 23) Vinyl Acetate 3.83 43 916719 101.80 ug/l 100 24) 1,1-Dichloroethane 3.70 63 150401 21.94 ug/l 100 25) 2-Butanone 4.71 43 322200 112.10 ug/l 99 26) 2,2-Dichloropropane 4.59 77 123595 22.40 ug/l 100 27) cis-1,2-Dichloroethene 4.60 96 95613 21.64 ug/l 98 28) Bromochloromethane 5.02 49 69243 22.74 ug/l 99 29) Tetrahydrofuran 5.17 42 202254 107.95 ug/l 100 30) Chloroform 5.22 83 158304 21.99 ug/l 99 31) Cyclohexane 5.58 56 137762 22.93 ug/l 98 32) 1,1,1-Trichloroethane 5.50 97 139595 22.44 ug/l 99 36) 1,1-Dichloropropene 5.81 75 119530 22.95 ug/l 99 37) Ethyl Acetate 4.87 43 120320 22.17 ug/l 100 38) Carbon Tetrachloride 5.79 117 127299 23.33 ug/l 97 39) Methylcyclohexane 7.46 83 148391 24.39 ug/l 99 40) Benzene 6.15 78 352725 22.99 ug/l 99 41) Methacrylonitrile 5.06 41 69682 22.20 ug/l 99 42) 1,2-Dichloroethane 6.20 62 126289 22.76 ug/l 100 43) Isopropyl Acetate 6.47 43 190949 22.48 ug/l 99 44) Trichloroethene 7.21 130 110229 23.14 ug/l 99 45) 1,2-Dichloropropane 7.52 63 87923 23.35 ug/l 99 46) Dibromomethane 7.67 93 59439 22.48 ug/l 99 47) Bromodichloromethane 7.90 83 114763 23.39 ug/l 99 48) Methyl methacrylate 7.78 41 100680 22.52 ug/l 99 49) 1,4-Dioxane 7.76 88 42512 493.78 ug/l 99 51) 4-Methyl-2-Pentanone 8.65 43 634178 117.80 ug/l 99 52) Toluene 8.79 92 236928 24.03 ug/l 98 53) t-1,3-Dichloropropene 8.44 75 135755 23.52 ug/l 100 54) cis-1,3-Dichloropropene 9.05 75 119034 23.39 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 86404 22.92 ug/l 99 56) Ethyl methacrylate 9.19 69 121385 22.71 ug/l 99 57) 1,3-Dichloropropane 9.38 76 143371 22.72 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 333950 121.46 ug/l 99 59) 2-Hexanone 9.50 43 454529 117.94 ug/l 100 60) Dibromochloromethane 9.59 129 89658 23.23 ug/l 99 61) 1,2-Dibromoethane 9.68 107 91893 23.29 ug/l 99 64) Tetrachloroethene 9.34 164 120536 22.96 ug/l 98 65) Chlorobenzene 10.15 112 250670 22.60 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 90413 23.08 ug/l 98 67) Ethyl Benzene 10.26 91 411131 23.20 ug/l 100 68) m/p-Xylenes 10.37 106 332037 47.48 ug/l 99 69) o-Xylene 10.71 106 157751 23.55 ug/l 100 70) Styrene 10.72 104 262193 23.74 ug/l 100 71) Bromoform 10.86 173 72570 21.67 ug/l # 99 73) Isopropylbenzene 11.02 105 428777 24.16 ug/l 99 74) N-amyl acetate 6.47 43 190949 22.44 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 118393 22.24 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 118585m 23.14 ug/l 77) Bromobenzene 11.26 156 121311 23.26 ug/l 100 78) n-propylbenzene 11.37 91 487942 24.40 ug/l 99 79) 2-Chlorotoluene 11.43 91 283445 23.70 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 358825 24.64 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 31921 20.64 ug/l 94 82) 4-Chlorotoluene 11.52 91 334154 23.72 ug/l 99 83) tert-Butylbenzene 11.77 119 348619 24.06 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 369465 24.50 ug/l 100 85) sec-Butylbenzene 11.95 105 438126 24.49 ug/l 99 86) p-Isopropyltoluene 12.07 119 407158 24.60 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 221631 22.98 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 225323 22.59 ug/l 99 89) n-Butylbenzene 12.40 91 343568 24.00 ug/l 100 90) Hexachloroethane 12.60 117 60123 23.39 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 220972 22.99 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 25943 22.83 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 177428 23.16 ug/l 99 94) Hexachlorobutadiene 13.79 225 94672 23.02 ug/l 100 95) Naphthalene 13.84 128 461942 23.20 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 176904 22.93 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed