Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051518\ Data File : VX001740.D Acq On : 15 May 2018 12:54 Operator : JC/MD Sample : VX0515WBS03 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 7 Sample Multiplier: 1 Quant Time: May 16 04:48:22 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 312632 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 414833 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 364582 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 232030 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 212917 50.81 ug/l 0.00 Spiked Amount 50.000 Recovery = 101.62% 35) Dibromofluoromethane 5.51 113 178877 51.10 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.20% 50) Toluene-d8 8.72 98 660856 52.71 ug/l 0.00 Spiked Amount 50.000 Recovery = 105.42% 62) 4-Bromofluorobenzene 11.14 95 221236 49.01 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.02% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 63276 20.17 ug/l 98 3) Chloromethane 1.32 50 69380 20.47 ug/l 99 4) Vinyl Chloride 1.40 62 74935 20.45 ug/l 99 5) Bromomethane 1.64 94 40258 24.49 ug/l 100 6) Chloroethane 1.72 64 49112 21.28 ug/l 100 7) Trichlorofluoromethane 1.93 101 107570 20.20 ug/l 97 8) Diethyl Ether 2.19 74 44572 20.34 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.39 101 64925 20.26 ug/l 98 10) Methyl Iodide 2.51 142 53865 18.27 ug/l 99 11) Tert butyl alcohol 3.08 59 83961 112.85 ug/l 100 12) 1,1-Dichloroethene 2.37 96 59892 19.38 ug/l 98 13) Acrolein 2.29 56 60829 115.28 ug/l 98 14) Allyl chloride 2.73 41 116733 20.44 ug/l 99 15) Acrylonitrile 3.15 53 196595 105.21 ug/l 100 16) Acetone 2.45 43 181648 110.37 ug/l 99 17) Carbon Disulfide 2.57 76 149549 18.55 ug/l 99 18) Methyl Acetate 2.78 43 104032 21.62 ug/l 97 19) Methyl tert-butyl Ether 3.21 73 212813 20.43 ug/l 99 20) Methylene Chloride 2.86 84 70008 19.87 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 66908 19.66 ug/l 98 22) Diisopropyl ether 3.88 45 215574 19.67 ug/l 98 23) Vinyl Acetate 3.83 43 737070 93.37 ug/l 100 24) 1,1-Dichloroethane 3.70 63 122577 20.40 ug/l 99 25) 2-Butanone 4.72 43 274884 109.09 ug/l 98 26) 2,2-Dichloropropane 4.59 77 97272 20.11 ug/l 100 27) cis-1,2-Dichloroethene 4.60 96 77860 20.10 ug/l 96 28) Bromochloromethane 5.03 49 58998 22.10 ug/l 99 29) Tetrahydrofuran 5.18 42 172782 105.19 ug/l 100 30) Chloroform 5.22 83 128109 20.30 ug/l 99 31) Cyclohexane 5.58 56 106572 20.23 ug/l 99 32) 1,1,1-Trichloroethane 5.50 97 112223 20.58 ug/l 99 36) 1,1-Dichloropropene 5.80 75 90826 19.02 ug/l 100 37) Ethyl Acetate 4.87 43 102826 20.66 ug/l 100 38) Carbon Tetrachloride 5.79 117 100987 20.19 ug/l 98 39) Methylcyclohexane 7.46 83 110418 19.79 ug/l 98 40) Benzene 6.15 78 284548 20.22 ug/l 100 41) Methacrylonitrile 5.07 41 58928 20.48 ug/l 98 42) 1,2-Dichloroethane 6.20 62 104217 20.48 ug/l 100 43) Isopropyl Acetate 6.48 43 155978 20.03 ug/l 100 44) Trichloroethene 7.22 130 87013 19.93 ug/l 98 45) 1,2-Dichloropropane 7.52 63 71240 20.63 ug/l 99 46) Dibromomethane 7.67 93 47971 19.79 ug/l 99 47) Bromodichloromethane 7.90 83 91050 20.24 ug/l 97 48) Methyl methacrylate 7.79 41 82531 20.13 ug/l 98 49) 1,4-Dioxane 7.76 88 37371 473.41 ug/l 98 51) 4-Methyl-2-Pentanone 8.66 43 531156 107.60 ug/l 99 52) Toluene 8.79 92 183761 20.33 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 105612 19.95 ug/l 98 54) cis-1,3-Dichloropropene 9.05 75 87285 18.71 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 69496 20.11 ug/l 96 56) Ethyl methacrylate 9.19 69 98232 20.04 ug/l 99 57) 1,3-Dichloropropane 9.38 76 115212 19.91 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 275818 109.41 ug/l 100 59) 2-Hexanone 9.51 43 386975 109.51 ug/l 99 60) Dibromochloromethane 9.59 129 71189 20.12 ug/l 99 61) 1,2-Dibromoethane 9.68 107 73646 20.36 ug/l 100 64) Tetrachloroethene 9.34 164 93001 19.60 ug/l 99 65) Chlorobenzene 10.15 112 198144 19.76 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 72685 20.52 ug/l 99 67) Ethyl Benzene 10.26 91 321911 20.09 ug/l 99 68) m/p-Xylenes 10.37 106 257395 40.70 ug/l 99 69) o-Xylene 10.71 106 124312 20.53 ug/l 99 70) Styrene 10.72 104 203469 20.37 ug/l 100 71) Bromoform 10.87 173 56245 18.99 ug/l # 98 73) Isopropylbenzene 11.02 105 334069 21.86 ug/l 99 74) N-amyl acetate 6.48 43 155978 21.29 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 99198 21.64 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 95671m 21.68 ug/l 77) Bromobenzene 11.26 156 94206 20.98 ug/l 100 78) n-propylbenzene 11.37 91 363502 21.11 ug/l 100 79) 2-Chlorotoluene 11.43 91 219360 21.31 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 276129 22.03 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 25205 19.20 ug/l 95 82) 4-Chlorotoluene 11.52 91 253839 20.93 ug/l 100 83) tert-Butylbenzene 11.77 119 270587 21.69 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 284651 21.93 ug/l 100 85) sec-Butylbenzene 11.95 105 328711 21.35 ug/l 100 86) p-Isopropyltoluene 12.07 119 301008 21.12 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 166922 20.10 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 168602 19.64 ug/l 99 89) n-Butylbenzene 12.40 91 236592 19.20 ug/l 99 90) Hexachloroethane 12.60 117 45820 20.70 ug/l 98 91) 1,2-Dichlorobenzene 12.40 146 169313 20.46 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 21564 22.04 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 122096 18.51 ug/l 99 94) Hexachlorobutadiene 13.79 225 67981 19.20 ug/l 100 95) Naphthalene 13.84 128 351922 20.53 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 128557 19.36 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed