Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051518\ Data File : VX001750.D Acq On : 15 May 2018 17:22 Operator : JC/MD Sample : VX0515WBSD03 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 17 Sample Multiplier: 1 Quant Time: May 16 05:28:42 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 286686 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 382494 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 339650 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 209306 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.08 65 212420 55.28 ug/l 0.00 Spiked Amount 50.000 Recovery = 110.56% 35) Dibromofluoromethane 5.51 113 175658 54.42 ug/l 0.00 Spiked Amount 50.000 Recovery = 108.84% 50) Toluene-d8 8.72 98 594801 51.45 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.90% 62) 4-Bromofluorobenzene 11.15 95 208597 50.11 ug/l 0.00 Spiked Amount 50.000 Recovery = 100.22% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 57333 19.93 ug/l 100 3) Chloromethane 1.32 50 67612 21.76 ug/l 100 4) Vinyl Chloride 1.40 62 72018 21.43 ug/l 100 5) Bromomethane 1.64 94 35437 23.37 ug/l 99 6) Chloroethane 1.72 64 48503 22.92 ug/l 96 7) Trichlorofluoromethane 1.93 101 99436 20.37 ug/l 99 8) Diethyl Ether 2.19 74 45166 22.47 ug/l 97 9) 1,1,2-Trichlorotrifluoroet 2.39 101 56204 19.12 ug/l 99 10) Methyl Iodide 2.51 142 60489 22.37 ug/l 100 11) Tert butyl alcohol 3.09 59 90669 132.90 ug/l 100 12) 1,1-Dichloroethene 2.37 96 58341 20.59 ug/l 98 13) Acrolein 2.30 56 61914 127.96 ug/l 100 14) Allyl chloride 2.73 41 114880 21.93 ug/l 97 15) Acrylonitrile 3.15 53 205941 120.18 ug/l 99 16) Acetone 2.45 43 182358 120.82 ug/l 98 17) Carbon Disulfide 2.57 76 141834 19.19 ug/l 99 18) Methyl Acetate 2.78 43 113088 25.63 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 214653 22.48 ug/l 98 20) Methylene Chloride 2.86 84 70253 21.75 ug/l 95 21) trans-1,2-Dichloroethene 3.17 96 64480 20.66 ug/l 98 22) Diisopropyl ether 3.88 45 224313 22.33 ug/l 98 23) Vinyl Acetate 3.83 43 766517 105.88 ug/l 99 24) 1,1-Dichloroethane 3.70 63 121858 22.11 ug/l 99 25) 2-Butanone 4.73 43 287040 124.22 ug/l 97 26) 2,2-Dichloropropane 4.59 77 76996 17.36 ug/l 98 27) cis-1,2-Dichloroethene 4.60 96 73746 20.76 ug/l 97 28) Bromochloromethane 5.03 49 60254 24.62 ug/l 98 29) Tetrahydrofuran 5.18 42 181763 120.68 ug/l 99 30) Chloroform 5.22 83 127339 22.00 ug/l 97 31) Cyclohexane 5.57 56 89015 18.43 ug/l 97 32) 1,1,1-Trichloroethane 5.50 97 107505 21.49 ug/l 99 36) 1,1-Dichloropropene 5.80 75 83678 19.00 ug/l 100 37) Ethyl Acetate 4.88 43 106581 23.23 ug/l 99 38) Carbon Tetrachloride 5.79 117 93411 20.25 ug/l 99 39) Methylcyclohexane 7.46 83 91006 17.69 ug/l 99 40) Benzene 6.15 78 272636 21.02 ug/l 98 41) Methacrylonitrile 5.07 41 58830 22.17 ug/l 99 42) 1,2-Dichloroethane 6.21 62 103459 22.05 ug/l 99 43) Isopropyl Acetate 6.48 43 157694 21.96 ug/l 100 44) Trichloroethene 7.22 130 81090 20.14 ug/l 98 45) 1,2-Dichloropropane 7.52 63 68685 21.58 ug/l 100 46) Dibromomethane 7.67 93 48399 21.65 ug/l 99 47) Bromodichloromethane 7.91 83 89491 21.58 ug/l 100 48) Methyl methacrylate 7.79 41 84184 22.27 ug/l 99 49) 1,4-Dioxane 7.77 88 39522 542.99 ug/l 98 51) 4-Methyl-2-Pentanone 8.66 43 527073 115.81 ug/l 100 52) Toluene 8.79 92 166306 19.95 ug/l 100 53) t-1,3-Dichloropropene 8.45 75 95110 19.49 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 83619 19.44 ug/l 99 55) 1,1,2-Trichloroethane 9.23 97 70743 22.20 ug/l 97 56) Ethyl methacrylate 9.19 69 97505 21.58 ug/l 99 57) 1,3-Dichloropropane 9.38 76 115397 21.63 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 259711 111.73 ug/l 99 59) 2-Hexanone 9.51 43 403427 123.82 ug/l 99 60) Dibromochloromethane 9.59 129 71382 21.88 ug/l 99 61) 1,2-Dibromoethane 9.68 107 74570 22.35 ug/l 98 64) Tetrachloroethene 9.34 164 87831 19.86 ug/l 97 65) Chlorobenzene 10.15 112 187096 20.03 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 71255 21.59 ug/l 98 67) Ethyl Benzene 10.26 91 292505 19.59 ug/l 100 68) m/p-Xylenes 10.37 106 233987 39.72 ug/l 99 69) o-Xylene 10.71 106 115100 20.40 ug/l 99 70) Styrene 10.72 104 190844 20.51 ug/l 100 71) Bromoform 10.87 173 56089 20.12 ug/l # 98 73) Isopropylbenzene 11.02 105 299119 21.70 ug/l 100 74) N-amyl acetate 6.48 43 157694 23.86 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 99451 24.05 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 96582m 24.27 ug/l 77) Bromobenzene 11.26 156 90096 22.24 ug/l 100 78) n-propylbenzene 11.37 91 318216 20.49 ug/l 100 79) 2-Chlorotoluene 11.43 91 202924 21.85 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 248225 21.95 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 22657 19.15 ug/l 93 82) 4-Chlorotoluene 11.52 91 229808 21.00 ug/l 99 83) tert-Butylbenzene 11.77 119 244215 21.70 ug/l 98 84) 1,2,4-Trimethylbenzene 11.81 105 259335 22.15 ug/l 100 85) sec-Butylbenzene 11.95 105 285589 20.56 ug/l 100 86) p-Isopropyltoluene 12.07 119 262395 20.41 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 153202 20.45 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 156608 20.22 ug/l 99 89) n-Butylbenzene 12.40 91 200168 18.01 ug/l 99 90) Hexachloroethane 12.60 117 41237 20.66 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 161457 21.63 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 21984 24.91 ug/l 99 93) 1,2,4-Trichlorobenzene 13.65 180 111013 18.66 ug/l 99 94) Hexachlorobutadiene 13.79 225 58327 18.26 ug/l 100 95) Naphthalene 13.84 128 341016 22.05 ug/l 99 96) 1,2,3-Trichlorobenzene 14.03 180 119344 19.92 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed