Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051518\ Data File : VX001758.D Acq On : 15 May 2018 20:58 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 25 Sample Multiplier: 1 Quant Time: May 16 05:49:03 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 291758 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 387682 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 339247 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 218147 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 199559 51.03 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.06% 35) Dibromofluoromethane 5.51 113 171191 52.33 ug/l 0.00 Spiked Amount 50.000 Recovery = 104.66% 50) Toluene-d8 8.72 98 629074 53.69 ug/l 0.00 Spiked Amount 50.000 Recovery = 107.38% 62) 4-Bromofluorobenzene 11.15 95 210733 49.95 ug/l 0.00 Spiked Amount 50.000 Recovery = 99.90% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 145130 49.57 ug/l 99 3) Chloromethane 1.32 50 162035 51.23 ug/l 99 4) Vinyl Chloride 1.40 62 174151 50.93 ug/l 99 5) Bromomethane 1.64 94 65325 45.08 ug/l 97 6) Chloroethane 1.71 64 116295 54.00 ug/l 99 7) Trichlorofluoromethane 1.92 101 247755 49.86 ug/l 98 8) Diethyl Ether 2.19 74 104818 51.25 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.38 101 143973 48.13 ug/l 99 10) Methyl Iodide 2.51 142 183629 66.73 ug/l 99 11) Tert butyl alcohol 3.09 59 204961 295.21 ug/l 99 12) 1,1-Dichloroethene 2.37 96 142703 49.49 ug/l 99 13) Acrolein 2.30 56 133413 270.93 ug/l 99 14) Allyl chloride 2.73 41 274013 51.41 ug/l 97 15) Acrylonitrile 3.15 53 484985 278.11 ug/l 100 16) Acetone 2.45 43 412254 268.40 ug/l 99 17) Carbon Disulfide 2.57 76 356590 47.40 ug/l 100 18) Methyl Acetate 2.78 43 259340 57.75 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 503887 51.84 ug/l 99 20) Methylene Chloride 2.85 84 165622 50.37 ug/l 97 21) trans-1,2-Dichloroethene 3.17 96 154287 48.57 ug/l 97 22) Diisopropyl ether 3.88 45 533701 52.19 ug/l 99 23) Vinyl Acetate 3.83 43 1812414 246.01 ug/l 100 24) 1,1-Dichloroethane 3.70 63 289370 51.60 ug/l 100 25) 2-Butanone 4.72 43 669037 284.50 ug/l 99 26) 2,2-Dichloropropane 4.59 77 173647 38.46 ug/l 97 27) cis-1,2-Dichloroethene 4.60 96 180286 49.87 ug/l 99 28) Bromochloromethane 5.03 49 138068 55.43 ug/l 99 29) Tetrahydrofuran 5.18 42 438757 286.23 ug/l 100 30) Chloroform 5.22 83 304246 51.65 ug/l 99 31) Cyclohexane 5.57 56 244919 49.83 ug/l 99 32) 1,1,1-Trichloroethane 5.49 97 265415 52.14 ug/l 99 36) 1,1-Dichloropropene 5.81 75 215027 48.18 ug/l 100 37) Ethyl Acetate 4.88 43 252711 54.34 ug/l 99 38) Carbon Tetrachloride 5.79 117 237350 50.77 ug/l 98 39) Methylcyclohexane 7.46 83 251804 48.29 ug/l 99 40) Benzene 6.15 78 674459 51.29 ug/l 99 41) Methacrylonitrile 5.07 41 144685 53.79 ug/l 99 42) 1,2-Dichloroethane 6.20 62 243786 51.26 ug/l 100 43) Isopropyl Acetate 6.48 43 389497 53.51 ug/l 99 44) Trichloroethene 7.22 130 203807 49.94 ug/l 99 45) 1,2-Dichloropropane 7.52 63 167097 51.79 ug/l 100 46) Dibromomethane 7.67 93 116147 51.27 ug/l 98 47) Bromodichloromethane 7.91 83 226870 53.96 ug/l 95 48) Methyl methacrylate 7.79 41 210730 55.00 ug/l 99 49) 1,4-Dioxane 7.77 88 94621 1282.60 ug/l 97 51) 4-Methyl-2-Pentanone 8.66 43 1338554 290.16 ug/l 100 52) Toluene 8.79 92 441185 52.22 ug/l 99 53) t-1,3-Dichloropropene 8.45 75 256110 51.78 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 212904 48.83 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 166811 51.65 ug/l 99 56) Ethyl methacrylate 9.19 69 245161 53.53 ug/l 99 57) 1,3-Dichloropropane 9.38 76 274791 50.82 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 640400 271.82 ug/l 100 59) 2-Hexanone 9.51 43 950809 287.93 ug/l 99 60) Dibromochloromethane 9.59 129 180278 54.51 ug/l 99 61) 1,2-Dibromoethane 9.68 107 176579 52.23 ug/l 100 64) Tetrachloroethene 9.34 164 238225 53.94 ug/l 100 65) Chlorobenzene 10.15 112 460249 49.32 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 174599 52.98 ug/l 99 67) Ethyl Benzene 10.26 91 756905 50.75 ug/l 99 68) m/p-Xylenes 10.37 106 604454 102.73 ug/l 100 69) o-Xylene 10.71 106 295071 52.36 ug/l 100 70) Styrene 10.72 104 489622 52.68 ug/l 100 71) Bromoform 10.87 173 149234 48.73 ug/l 99 73) Isopropylbenzene 11.02 105 780869 54.35 ug/l 100 74) N-amyl acetate 6.48 43 389497 56.55 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 235926 54.75 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 229097m 55.23 ug/l 77) Bromobenzene 11.26 156 222664 52.75 ug/l 99 78) n-propylbenzene 11.37 91 847782 52.38 ug/l 100 79) 2-Chlorotoluene 11.43 91 514839 53.19 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 643589 54.61 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 62787 45.43 ug/l 99 82) 4-Chlorotoluene 11.52 91 586119 51.40 ug/l 99 83) tert-Butylbenzene 11.77 119 639847 54.55 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 666231 54.59 ug/l 100 85) sec-Butylbenzene 11.95 105 768559 53.08 ug/l 100 86) p-Isopropyltoluene 12.07 119 704050 52.55 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 392847 50.32 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 393558 48.75 ug/l 100 89) n-Butylbenzene 12.40 91 564157 48.69 ug/l 100 90) Hexachloroethane 12.60 117 113477 54.54 ug/l 100 91) 1,2-Dichlorobenzene 12.40 146 401632 51.63 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 54213 58.94 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 298536 48.15 ug/l 100 94) Hexachlorobutadiene 13.79 225 154053 46.28 ug/l 99 95) Naphthalene 13.84 128 894651 55.51 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 315747 50.57 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed