Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051718\ Data File : VX001782.D Acq On : 17 May 2018 10:18 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 2 Sample Multiplier: 1 Quant Time: May 18 04:11:31 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 325712 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 402988 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 331354 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 220981 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 200717 45.97 ug/l 0.00 Spiked Amount 50.000 Recovery = 91.94% 35) Dibromofluoromethane 5.51 113 179955 52.91 ug/l 0.00 Spiked Amount 50.000 Recovery = 105.82% 50) Toluene-d8 8.72 98 671658 55.14 ug/l 0.00 Spiked Amount 50.000 Recovery = 110.28% 62) 4-Bromofluorobenzene 11.14 95 216127 49.28 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.56% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 153105 46.84 ug/l 100 3) Chloromethane 1.32 50 172151 48.76 ug/l 99 4) Vinyl Chloride 1.40 62 179801 47.10 ug/l 100 5) Bromomethane 1.64 94 71905 44.40 ug/l 97 6) Chloroethane 1.72 64 116283 48.36 ug/l 98 7) Trichlorofluoromethane 1.93 101 265784 47.92 ug/l 99 8) Diethyl Ether 2.19 74 110138 48.24 ug/l 97 9) 1,1,2-Trichlorotrifluoroet 2.39 101 166480 49.86 ug/l 99 10) Methyl Iodide 2.51 142 209198 68.09 ug/l 99 11) Tert butyl alcohol 3.07 59 183422 236.64 ug/l 99 12) 1,1-Dichloroethene 2.37 96 149046 46.30 ug/l 99 13) Acrolein 2.29 56 118564 215.68 ug/l 100 14) Allyl chloride 2.73 41 288759 48.53 ug/l 99 15) Acrylonitrile 3.15 53 454513 233.47 ug/l 99 16) Acetone 2.45 43 447287 260.85 ug/l 99 17) Carbon Disulfide 2.57 76 371330 44.22 ug/l 99 18) Methyl Acetate 2.78 43 246277 49.13 ug/l 98 19) Methyl tert-butyl Ether 3.21 73 517088 47.65 ug/l 99 20) Methylene Chloride 2.85 84 170713 46.51 ug/l 100 21) trans-1,2-Dichloroethene 3.17 96 163006 45.96 ug/l 97 22) Diisopropyl ether 3.87 45 550995 48.27 ug/l 99 23) Vinyl Acetate 3.82 43 1852073 225.19 ug/l 99 24) 1,1-Dichloroethane 3.70 63 300007 47.92 ug/l 100 25) 2-Butanone 4.71 43 655883 249.83 ug/l 98 26) 2,2-Dichloropropane 4.59 77 249944 49.59 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 192983 47.82 ug/l 99 28) Bromochloromethane 5.03 49 146339 52.62 ug/l 100 29) Tetrahydrofuran 5.17 42 403388 235.73 ug/l 100 30) Chloroform 5.21 83 315250 47.94 ug/l 97 31) Cyclohexane 5.58 56 277542 50.58 ug/l 100 32) 1,1,1-Trichloroethane 5.49 97 275907 48.55 ug/l 100 36) 1,1-Dichloropropene 5.80 75 235692 50.81 ug/l 100 37) Ethyl Acetate 4.87 43 240624 49.77 ug/l 100 38) Carbon Tetrachloride 5.78 117 250753 51.60 ug/l 100 39) Methylcyclohexane 7.46 83 301187 55.57 ug/l 99 40) Benzene 6.15 78 715270 52.33 ug/l 99 41) Methacrylonitrile 5.06 41 139262 49.81 ug/l 98 42) 1,2-Dichloroethane 6.20 62 242819 49.12 ug/l 98 43) Isopropyl Acetate 6.47 43 379320 50.13 ug/l 99 44) Trichloroethene 7.21 130 217055 51.16 ug/l 99 45) 1,2-Dichloropropane 7.52 63 178485 53.22 ug/l 98 46) Dibromomethane 7.67 93 119469 50.73 ug/l 98 47) Bromodichloromethane 7.90 83 232035 53.10 ug/l 97 48) Methyl methacrylate 7.78 41 203707 51.15 ug/l 97 49) 1,4-Dioxane 7.76 88 88665 1156.21 ug/l 96 51) 4-Methyl-2-Pentanone 8.65 43 1262078 263.19 ug/l 99 52) Toluene 8.79 92 469243 53.43 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 282469 54.94 ug/l 99 54) cis-1,3-Dichloropropene 9.04 75 253167 55.86 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 184028 54.82 ug/l 99 56) Ethyl methacrylate 9.18 69 268051 56.30 ug/l 99 57) 1,3-Dichloropropane 9.38 76 306670 54.56 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 639574 261.16 ug/l 99 59) 2-Hexanone 9.50 43 980599 285.67 ug/l 100 60) Dibromochloromethane 9.59 129 202556 58.92 ug/l 100 61) 1,2-Dibromoethane 9.68 107 193958 55.19 ug/l 99 64) Tetrachloroethene 9.34 164 259496 60.16 ug/l 98 65) Chlorobenzene 10.14 112 462666 50.76 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 173612 53.93 ug/l 98 67) Ethyl Benzene 10.26 91 770719 52.91 ug/l 100 68) m/p-Xylenes 10.37 106 616986 107.36 ug/l 100 69) o-Xylene 10.70 106 298515 54.24 ug/l 100 70) Styrene 10.72 104 493743 54.39 ug/l 100 71) Bromoform 10.86 173 144200 48.24 ug/l 99 73) Isopropylbenzene 11.02 105 803590 55.22 ug/l 100 74) N-amyl acetate 6.47 43 379320 54.37 ug/l # 98 75) 1,1,2,2-Tetrachloroethane 11.27 83 221954 50.84 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 217539m 51.77 ug/l 77) Bromobenzene 11.26 156 226093 52.87 ug/l 99 78) n-propylbenzene 11.37 91 902383 55.04 ug/l 99 79) 2-Chlorotoluene 11.43 91 526513 53.69 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 676047 56.63 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 66682 47.47 ug/l 99 82) 4-Chlorotoluene 11.52 91 618850 53.57 ug/l 100 83) tert-Butylbenzene 11.77 119 660656 55.61 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 697662 56.43 ug/l 100 85) sec-Butylbenzene 11.95 105 828286 56.48 ug/l 100 86) p-Isopropyltoluene 12.07 119 766329 56.47 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 413625 52.30 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 417642 51.07 ug/l 99 89) n-Butylbenzene 12.40 91 638126 54.37 ug/l 100 90) Hexachloroethane 12.60 117 120881 57.35 ug/l 97 91) 1,2-Dichlorobenzene 12.40 146 413057 52.42 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 48976 52.56 ug/l 97 93) 1,2,4-Trichlorobenzene 13.65 180 330251 52.58 ug/l 100 94) Hexachlorobutadiene 13.79 225 178765 53.01 ug/l 99 95) Naphthalene 13.84 128 873009 53.47 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 330562 52.27 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed