Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051718\ Data File : VX001784.D Acq On : 17 May 2018 12:26 Operator : JC/MD Sample : VX0517WBS01 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 4 Sample Multiplier: 1 Quant Time: May 18 04:25:46 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 346424 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 430015 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 357530 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 232351 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 217242 46.78 ug/l 0.00 Spiked Amount 50.000 Recovery = 93.56% 35) Dibromofluoromethane 5.51 113 192146 52.95 ug/l 0.00 Spiked Amount 50.000 Recovery = 105.90% 50) Toluene-d8 8.72 98 719673 55.37 ug/l 0.00 Spiked Amount 50.000 Recovery = 110.74% 62) 4-Bromofluorobenzene 11.14 95 230512 49.26 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.52% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 67820 19.51 ug/l 98 3) Chloromethane 1.32 50 73883 19.67 ug/l 100 4) Vinyl Chloride 1.40 62 80068 19.72 ug/l 98 5) Bromomethane 1.64 94 41201 22.36 ug/l 94 6) Chloroethane 1.72 64 51530 20.15 ug/l 99 7) Trichlorofluoromethane 1.93 101 116346 19.72 ug/l 98 8) Diethyl Ether 2.19 74 47800 19.68 ug/l 100 9) 1,1,2-Trichlorotrifluoroet 2.39 101 74079 20.86 ug/l 99 10) Methyl Iodide 2.51 142 77604 23.75 ug/l 98 11) Tert butyl alcohol 3.07 59 86594 105.04 ug/l 99 12) 1,1-Dichloroethene 2.37 96 65355 19.09 ug/l 99 13) Acrolein 2.29 56 44244 75.67 ug/l 99 14) Allyl chloride 2.73 41 125683 19.86 ug/l 98 15) Acrylonitrile 3.15 53 204740 98.88 ug/l 99 16) Acetone 2.45 43 197624 108.36 ug/l 99 17) Carbon Disulfide 2.57 76 153384 17.17 ug/l 99 18) Methyl Acetate 2.78 43 112392 21.08 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 226150 19.60 ug/l 100 20) Methylene Chloride 2.86 84 75409 19.32 ug/l 96 21) trans-1,2-Dichloroethene 3.17 96 71219 18.88 ug/l 98 22) Diisopropyl ether 3.87 45 234061 19.28 ug/l 98 23) Vinyl Acetate 3.82 43 796359 91.04 ug/l 100 24) 1,1-Dichloroethane 3.70 63 133829 20.10 ug/l 99 25) 2-Butanone 4.71 43 290136 103.91 ug/l 99 26) 2,2-Dichloropropane 4.59 77 107009 19.96 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 83652 19.49 ug/l 100 28) Bromochloromethane 5.02 49 60785 20.55 ug/l 100 29) Tetrahydrofuran 5.17 42 179780 98.78 ug/l 99 30) Chloroform 5.22 83 138802 19.85 ug/l 100 31) Cyclohexane 5.57 56 119285 20.44 ug/l 98 32) 1,1,1-Trichloroethane 5.49 97 119444 19.76 ug/l 99 36) 1,1-Dichloropropene 5.80 75 101176 20.44 ug/l 99 37) Ethyl Acetate 4.86 43 106539 20.65 ug/l 99 38) Carbon Tetrachloride 5.79 117 108769 20.97 ug/l 98 39) Methylcyclohexane 7.46 83 127119 21.98 ug/l 98 40) Benzene 6.15 78 308076 21.12 ug/l 100 41) Methacrylonitrile 5.06 41 62135 20.83 ug/l 99 42) 1,2-Dichloroethane 6.20 62 107795 20.44 ug/l 99 43) Isopropyl Acetate 6.47 43 160912 19.93 ug/l 99 44) Trichloroethene 7.21 130 95329 21.06 ug/l 99 45) 1,2-Dichloropropane 7.52 63 75397 21.07 ug/l 98 46) Dibromomethane 7.67 93 51227 20.38 ug/l 98 47) Bromodichloromethane 7.90 83 96923 20.78 ug/l 97 48) Methyl methacrylate 7.78 41 86640 20.39 ug/l 98 49) 1,4-Dioxane 7.76 88 39619 484.17 ug/l 96 51) 4-Methyl-2-Pentanone 8.65 43 557675 108.99 ug/l 99 52) Toluene 8.79 92 203646 21.73 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 115856 21.12 ug/l 98 54) cis-1,3-Dichloropropene 9.05 75 99761 20.63 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 79955 22.32 ug/l 99 56) Ethyl methacrylate 9.19 69 109714 21.60 ug/l 100 57) 1,3-Dichloropropane 9.38 76 118300 19.72 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 256158 98.02 ug/l 99 59) 2-Hexanone 9.50 43 378283 103.28 ug/l 100 60) Dibromochloromethane 9.59 129 74066 20.19 ug/l 99 61) 1,2-Dibromoethane 9.68 107 74268 19.80 ug/l 99 64) Tetrachloroethene 9.34 164 101703 21.85 ug/l 98 65) Chlorobenzene 10.14 112 204007 20.74 ug/l 97 66) 1,1,1,2-Tetrachloroethane 10.23 131 75191 21.65 ug/l 99 67) Ethyl Benzene 10.26 91 333888 21.24 ug/l 100 68) m/p-Xylenes 10.37 106 270545 43.63 ug/l 100 69) o-Xylene 10.70 106 128394 21.62 ug/l 100 70) Styrene 10.72 104 212601 21.71 ug/l 100 71) Bromoform 10.86 173 58185 19.87 ug/l 99 73) Isopropylbenzene 11.02 105 350742 22.92 ug/l 100 74) N-amyl acetate 6.47 43 160912 21.93 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 97594 21.26 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 96412m 21.82 ug/l 77) Bromobenzene 11.26 156 98262 21.85 ug/l 99 78) n-propylbenzene 11.37 91 390193 22.63 ug/l 100 79) 2-Chlorotoluene 11.43 91 232286 22.53 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 292061 23.27 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 26148 19.78 ug/l 96 82) 4-Chlorotoluene 11.52 91 270004 22.23 ug/l 99 83) tert-Butylbenzene 11.77 119 286028 22.90 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 300761 23.14 ug/l 100 85) sec-Butylbenzene 11.95 105 353988 22.96 ug/l 100 86) p-Isopropyltoluene 12.07 119 327758 22.97 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 177741 21.38 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 179885 20.92 ug/l 99 89) n-Butylbenzene 12.40 91 260783 21.13 ug/l 100 90) Hexachloroethane 12.60 117 49164 22.19 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 179092 21.62 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 20678 21.11 ug/l 99 93) 1,2,4-Trichlorobenzene 13.65 180 135685 20.55 ug/l 100 94) Hexachlorobutadiene 13.79 225 76664 21.62 ug/l 99 95) Naphthalene 13.84 128 365352 21.28 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 138244 20.79 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed