Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051718\ Data File : VX001790.D Acq On : 17 May 2018 15:06 Operator : JC/MD Sample : J2853-19MS Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 10 Sample Multiplier: 1 Quant Time: May 18 04:35:19 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 290342 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 399467 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 336139 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 212802 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 201895 51.88 ug/l 0.00 Spiked Amount 50.000 Recovery = 103.76% 35) Dibromofluoromethane 5.51 113 178383 52.91 ug/l 0.00 Spiked Amount 50.000 Recovery = 105.82% 50) Toluene-d8 8.72 98 651232 53.94 ug/l 0.00 Spiked Amount 50.000 Recovery = 107.88% 62) 4-Bromofluorobenzene 11.14 95 201217 46.29 ug/l 0.00 Spiked Amount 50.000 Recovery = 92.58% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 140688 48.29 ug/l 99 3) Chloromethane 1.32 50 171189 54.39 ug/l 99 4) Vinyl Chloride 1.40 62 266936 78.45 ug/l 99 5) Bromomethane 1.64 94 66985 46.56 ug/l 98 6) Chloroethane 1.72 64 114467 53.41 ug/l 98 7) Trichlorofluoromethane 1.93 101 246340 49.82 ug/l 99 8) Diethyl Ether 2.19 74 107924 53.03 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.38 101 139922 47.01 ug/l 99 10) Methyl Iodide 2.51 142 195910 71.53 ug/l 99 11) Tert butyl alcohol 3.09 59 178468 258.30 ug/l 98 12) 1,1-Dichloroethene 2.37 96 143507 50.01 ug/l 99 13) Acrolein 2.30 56 136038 277.61 ug/l 100 14) Allyl chloride 2.73 41 233862 44.09 ug/l 96 15) Acrylonitrile 3.15 53 466913 269.05 ug/l 100 16) Acetone 2.45 43 398837 260.93 ug/l 99 17) Carbon Disulfide 2.57 76 348856 46.60 ug/l 99 18) Methyl Acetate 2.78 43 242607 54.29 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 511792 52.91 ug/l 100 20) Methylene Chloride 2.86 84 166802 50.98 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 152967 48.39 ug/l 98 22) Diisopropyl ether 3.88 45 544709 53.53 ug/l 98 23) Vinyl Acetate 3.83 43 1752085 238.98 ug/l 99 24) 1,1-Dichloroethane 3.70 63 294866 52.84 ug/l 99 25) 2-Butanone 4.72 43 649076 277.36 ug/l 98 26) 2,2-Dichloropropane 4.59 77 35984 8.01 ug/l # 56 27) cis-1,2-Dichloroethene 4.60 96 222487 61.85 ug/l 92 28) Bromochloromethane 5.03 49 145627 58.75 ug/l 99 29) Tetrahydrofuran 5.18 42 421920 276.59 ug/l 100 30) Chloroform 5.22 83 309344 52.77 ug/l 99 31) Cyclohexane 5.57 56 254571 52.04 ug/l 99 32) 1,1,1-Trichloroethane 5.50 97 266629 52.64 ug/l 100 36) 1,1-Dichloropropene 5.80 75 215490 46.86 ug/l 99 37) Ethyl Acetate 4.87 43 240616 50.21 ug/l 99 38) Carbon Tetrachloride 5.79 117 238923 49.60 ug/l 98 39) Methylcyclohexane 7.46 83 246631 45.90 ug/l 98 40) Benzene 6.15 78 698949 51.59 ug/l 100 41) Methacrylonitrile 5.07 41 143752 51.87 ug/l 99 42) 1,2-Dichloroethane 6.20 62 241079 49.20 ug/l 99 43) Isopropyl Acetate 6.48 43 377592 50.34 ug/l 99 44) Trichloroethene 7.22 130 203800 48.46 ug/l 98 45) 1,2-Dichloropropane 7.53 63 174401 52.46 ug/l 97 46) Dibromomethane 7.67 93 119403 51.15 ug/l 99 47) Bromodichloromethane 7.90 83 227377 52.49 ug/l 99 48) Methyl methacrylate 7.79 41 208520 52.82 ug/l 97 49) 1,4-Dioxane 7.76 88 82843 1089.82 ug/l 96 51) 4-Methyl-2-Pentanone 8.66 43 1302535 274.03 ug/l 98 52) Toluene 8.79 92 447991 51.46 ug/l 99 53) t-1,3-Dichloropropene 8.44 75 200532 39.34 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 160879 35.81 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 162204 48.74 ug/l 99 56) Ethyl methacrylate 9.19 69 238955 50.63 ug/l 98 57) 1,3-Dichloropropane 9.38 76 265232 47.60 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.27 63 527 0.22 ug/l # 43 59) 2-Hexanone 9.51 43 865188 254.27 ug/l 100 60) Dibromochloromethane 9.59 129 175274 51.43 ug/l 99 61) 1,2-Dibromoethane 9.68 107 169212 48.57 ug/l 100 64) Tetrachloroethene 9.34 164 201820 46.12 ug/l 99 65) Chlorobenzene 10.15 112 444566 48.08 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 170027 52.07 ug/l 99 67) Ethyl Benzene 10.26 91 728310 49.29 ug/l 99 68) m/p-Xylenes 10.37 106 572584 98.21 ug/l 99 69) o-Xylene 10.71 106 285046 51.05 ug/l 99 70) Styrene 10.72 104 468437 50.87 ug/l 100 71) Bromoform 10.87 173 141916 46.89 ug/l 99 73) Isopropylbenzene 11.02 105 741749 52.93 ug/l 100 74) N-amyl acetate 6.48 43 377592 56.20 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 226914 53.98 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 201725m 49.85 ug/l 77) Bromobenzene 11.26 156 216939 52.68 ug/l 98 78) n-propylbenzene 11.37 91 792567 50.20 ug/l 100 79) 2-Chlorotoluene 11.43 91 489934 51.88 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 609644 53.03 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 34159 26.80 ug/l 98 82) 4-Chlorotoluene 11.52 91 559420 50.29 ug/l 99 83) tert-Butylbenzene 11.77 119 630082 55.07 ug/l 97 84) 1,2,4-Trimethylbenzene 11.81 105 634204 53.27 ug/l 100 85) sec-Butylbenzene 11.95 105 715019 50.63 ug/l 100 86) p-Isopropyltoluene 12.07 119 648825 49.65 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 370985 48.71 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 373477 47.43 ug/l 100 89) n-Butylbenzene 12.40 91 486957 43.08 ug/l 99 90) Hexachloroethane 12.60 117 112343 55.35 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 387592 51.08 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 50303 56.06 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 274050 45.31 ug/l 100 94) Hexachlorobutadiene 13.79 225 124267 38.27 ug/l 99 95) Naphthalene 13.84 128 841970 53.56 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 293750 48.23 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed