Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051718\ Data File : VX001791.D Acq On : 17 May 2018 15:33 Operator : JC/MD Sample : J2853-20MSD Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 11 Sample Multiplier: 1 Quant Time: May 18 04:35:51 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 236121 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 339924 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 257105 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 152747 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 183071 57.84 ug/l 0.00 Spiked Amount 50.000 Recovery = 115.68% 35) Dibromofluoromethane 5.51 113 158234 55.16 ug/l 0.00 Spiked Amount 50.000 Recovery = 110.32% 50) Toluene-d8 8.72 98 485518 47.26 ug/l 0.00 Spiked Amount 50.000 Recovery = 94.52% 62) 4-Bromofluorobenzene 11.14 95 150619 40.72 ug/l 0.00 Spiked Amount 50.000 Recovery = 81.44% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 110263 46.53 ug/l 98 3) Chloromethane 1.32 50 167585 65.47 ug/l 99 4) Vinyl Chloride 1.40 62 252597 91.28 ug/l 99 5) Bromomethane 1.64 94 66072 57.19 ug/l 96 6) Chloroethane 1.72 64 109130 62.61 ug/l 98 7) Trichlorofluoromethane 1.93 101 184578 45.90 ug/l 98 8) Diethyl Ether 2.19 74 106321 64.23 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.38 101 89303 36.89 ug/l 98 10) Methyl Iodide 2.51 142 189082 84.90 ug/l 98 11) Tert butyl alcohol 3.09 59 176671 314.42 ug/l 99 12) 1,1-Dichloroethene 2.37 96 118144 50.62 ug/l 99 13) Acrolein 2.30 56 125648 315.29 ug/l 100 14) Allyl chloride 2.73 41 216980 50.30 ug/l 95 15) Acrylonitrile 3.15 53 463296 328.27 ug/l 100 16) Acetone 2.45 43 394304 317.20 ug/l 98 17) Carbon Disulfide 2.57 76 285979 46.98 ug/l 99 18) Methyl Acetate 2.78 43 215369 59.26 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 501687 63.78 ug/l 99 20) Methylene Chloride 2.86 84 160851 60.45 ug/l 98 21) trans-1,2-Dichloroethene 3.17 96 134658 52.38 ug/l 97 22) Diisopropyl ether 3.88 45 525853 63.54 ug/l 98 23) Vinyl Acetate 3.83 43 1499380 251.47 ug/l 100 24) 1,1-Dichloroethane 3.70 63 270426 59.59 ug/l 100 25) 2-Butanone 4.72 43 639997 336.28 ug/l 97 26) 2,2-Dichloropropane 4.59 77 30918 8.46 ug/l # 50 27) cis-1,2-Dichloroethene 4.60 96 206862 70.71 ug/l 91 28) Bromochloromethane 5.03 49 138304 68.60 ug/l 99 29) Tetrahydrofuran 5.17 42 421909 340.10 ug/l 100 30) Chloroform 5.22 83 285041 59.79 ug/l 99 31) Cyclohexane 5.58 56 141969 35.69 ug/l 99 32) 1,1,1-Trichloroethane 5.50 97 217025 52.68 ug/l 100 36) 1,1-Dichloropropene 5.80 75 156311 39.95 ug/l 99 37) Ethyl Acetate 4.87 43 212644 52.14 ug/l 99 38) Carbon Tetrachloride 5.79 117 172188 42.00 ug/l 100 39) Methylcyclohexane 7.46 83 129480 28.32 ug/l 100 40) Benzene 6.15 78 606538 52.61 ug/l 100 41) Methacrylonitrile 5.07 41 141107 59.84 ug/l 99 42) 1,2-Dichloroethane 6.20 62 227051 54.45 ug/l 99 43) Isopropyl Acetate 6.48 43 348759 54.64 ug/l 99 44) Trichloroethene 7.22 130 159461 44.56 ug/l 99 45) 1,2-Dichloropropane 7.52 63 162030 57.27 ug/l 98 46) Dibromomethane 7.67 93 112360 56.56 ug/l 98 47) Bromodichloromethane 7.90 83 211168 57.29 ug/l 97 48) Methyl methacrylate 7.79 41 204491 60.87 ug/l 97 49) 1,4-Dioxane 7.76 88 83169 1285.75 ug/l 98 51) 4-Methyl-2-Pentanone 8.66 43 1281646 316.86 ug/l 98 52) Toluene 8.79 92 348689 47.07 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 181474 41.84 ug/l 100 54) cis-1,3-Dichloropropene 9.05 75 146489 38.32 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 151777 53.60 ug/l 99 56) Ethyl methacrylate 9.19 69 229543 57.16 ug/l 97 57) 1,3-Dichloropropane 9.38 76 247151 52.13 ug/l 100 59) 2-Hexanone 9.51 43 843945 291.47 ug/l 99 60) Dibromochloromethane 9.59 129 160379 55.31 ug/l 100 61) 1,2-Dibromoethane 9.68 107 158132 53.34 ug/l 99 64) Tetrachloroethene 9.34 164 132261 39.52 ug/l 99 65) Chlorobenzene 10.15 112 346520 49.00 ug/l 97 66) 1,1,1,2-Tetrachloroethane 10.23 131 145303 58.17 ug/l 99 67) Ethyl Benzene 10.26 91 500335 44.27 ug/l 99 68) m/p-Xylenes 10.37 106 402015 90.15 ug/l 99 69) o-Xylene 10.71 106 211602 49.55 ug/l 99 70) Styrene 10.72 104 357559 50.77 ug/l 100 71) Bromoform 10.87 173 133264 56.90 ug/l 100 73) Isopropylbenzene 11.02 105 483152 48.03 ug/l 100 74) N-amyl acetate 6.48 43 348759 72.32 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 219867 72.86 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 194278m 66.89 ug/l 77) Bromobenzene 11.26 156 169763 57.43 ug/l 98 78) n-propylbenzene 11.37 91 505208 44.58 ug/l 99 79) 2-Chlorotoluene 11.43 91 342634 50.55 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 408811 49.54 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 32073 34.04 ug/l 96 82) 4-Chlorotoluene 11.52 91 391005 48.97 ug/l 100 83) tert-Butylbenzene 11.77 119 414926 50.52 ug/l 95 84) 1,2,4-Trimethylbenzene 11.81 105 438597 51.32 ug/l 100 85) sec-Butylbenzene 11.95 105 438824 43.29 ug/l 100 86) p-Isopropyltoluene 12.07 119 412608 43.99 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 272768 49.90 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 275597 48.76 ug/l 100 89) n-Butylbenzene 12.40 91 303496 37.41 ug/l 100 90) Hexachloroethane 12.60 117 70419 48.34 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 298897 54.88 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 48694 75.61 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 206364 47.53 ug/l 99 94) Hexachlorobutadiene 13.79 225 81709 35.06 ug/l 99 95) Naphthalene 13.84 128 739588 65.54 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 233867 53.50 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed