Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051718\ Data File : VX001802.D Acq On : 17 May 2018 20:27 Operator : JC/MD Sample : VX0517WBSD01 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 22 Sample Multiplier: 1 Quant Time: May 18 04:58:54 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 271411 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 353393 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 293418 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 187656 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.08 65 179710 49.40 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.80% 35) Dibromofluoromethane 5.51 113 157305 52.75 ug/l 0.00 Spiked Amount 50.000 Recovery = 105.50% 50) Toluene-d8 8.72 98 584342 54.71 ug/l 0.00 Spiked Amount 50.000 Recovery = 109.42% 62) 4-Bromofluorobenzene 11.14 95 183955 47.83 ug/l 0.00 Spiked Amount 50.000 Recovery = 95.66% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 54982 20.19 ug/l 99 3) Chloromethane 1.32 50 62770 21.33 ug/l 100 4) Vinyl Chloride 1.40 62 66485 20.90 ug/l 99 5) Bromomethane 1.64 94 33715 23.50 ug/l 97 6) Chloroethane 1.72 64 43939 21.93 ug/l 100 7) Trichlorofluoromethane 1.93 101 96666 20.91 ug/l 99 8) Diethyl Ether 2.19 74 41341 21.73 ug/l 97 9) 1,1,2-Trichlorotrifluoroet 2.39 101 59149 21.26 ug/l 98 10) Methyl Iodide 2.51 142 63272 24.71 ug/l 100 11) Tert butyl alcohol 3.08 59 81929 126.85 ug/l 100 12) 1,1-Dichloroethene 2.37 96 55729 20.77 ug/l 100 13) Acrolein 2.30 56 42983 93.83 ug/l 99 14) Allyl chloride 2.73 41 106694 21.52 ug/l 97 15) Acrylonitrile 3.15 53 193136 119.06 ug/l 100 16) Acetone 2.45 43 169726 118.78 ug/l 97 17) Carbon Disulfide 2.57 76 125655 17.96 ug/l 96 18) Methyl Acetate 2.78 43 106155 25.41 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 196477 21.73 ug/l 99 20) Methylene Chloride 2.86 84 65601 21.45 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 60222 20.38 ug/l 96 22) Diisopropyl ether 3.88 45 205636 21.62 ug/l 98 23) Vinyl Acetate 3.83 43 689764 100.64 ug/l 100 24) 1,1-Dichloroethane 3.70 63 113901 21.83 ug/l 100 25) 2-Butanone 4.72 43 269174 123.05 ug/l 99 26) 2,2-Dichloropropane 4.59 77 75974 18.09 ug/l 97 27) cis-1,2-Dichloroethene 4.60 96 70995 21.11 ug/l 100 28) Bromochloromethane 5.03 49 54792 23.64 ug/l 99 29) Tetrahydrofuran 5.18 42 172288 120.82 ug/l 99 30) Chloroform 5.22 83 121535 22.18 ug/l 99 31) Cyclohexane 5.58 56 96067 21.01 ug/l 97 32) 1,1,1-Trichloroethane 5.50 97 103059 21.76 ug/l 99 36) 1,1-Dichloropropene 5.81 75 82655 20.32 ug/l 99 37) Ethyl Acetate 4.87 43 99968 23.58 ug/l 99 38) Carbon Tetrachloride 5.79 117 91145 21.39 ug/l 99 39) Methylcyclohexane 7.47 83 97606 20.53 ug/l 99 40) Benzene 6.15 78 263342 21.97 ug/l 98 41) Methacrylonitrile 5.07 41 56052 22.86 ug/l 98 42) 1,2-Dichloroethane 6.21 62 93550 21.58 ug/l 100 43) Isopropyl Acetate 6.48 43 145027 21.86 ug/l 99 44) Trichloroethene 7.22 130 80791 21.72 ug/l 96 45) 1,2-Dichloropropane 7.52 63 67266 22.87 ug/l 98 46) Dibromomethane 7.67 93 45383 21.97 ug/l 99 47) Bromodichloromethane 7.90 83 85197 22.23 ug/l 96 48) Methyl methacrylate 7.79 41 77482 22.18 ug/l 99 49) 1,4-Dioxane 7.77 88 36460 542.17 ug/l 98 51) 4-Methyl-2-Pentanone 8.66 43 514277 122.30 ug/l 100 52) Toluene 8.79 92 169797 22.05 ug/l 99 53) t-1,3-Dichloropropene 8.45 75 95280 21.13 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 74047 18.63 ug/l 98 55) 1,1,2-Trichloroethane 9.23 97 64154 21.79 ug/l 98 56) Ethyl methacrylate 9.19 69 85402 20.46 ug/l 99 57) 1,3-Dichloropropane 9.38 76 103221 20.94 ug/l 98 58) 2-Chloroethyl Vinyl ether 8.32 63 248453 115.69 ug/l 100 59) 2-Hexanone 9.51 43 352103 116.97 ug/l 99 60) Dibromochloromethane 9.59 129 63610 21.10 ug/l 99 61) 1,2-Dibromoethane 9.68 107 66631 21.62 ug/l 97 64) Tetrachloroethene 9.34 164 86982 22.77 ug/l 97 65) Chlorobenzene 10.15 112 172154 21.33 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 64892 22.76 ug/l 98 67) Ethyl Benzene 10.26 91 277129 21.49 ug/l 98 68) m/p-Xylenes 10.37 106 221589 43.54 ug/l 98 69) o-Xylene 10.71 106 108025 22.16 ug/l 99 70) Styrene 10.72 104 177051 22.03 ug/l 100 71) Bromoform 10.87 173 50929 21.00 ug/l # 99 73) Isopropylbenzene 11.02 105 291550 23.59 ug/l 99 74) N-amyl acetate 6.48 43 145027 24.48 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 88201 23.79 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 86694m 24.30 ug/l 77) Bromobenzene 11.26 156 83220 22.92 ug/l 100 78) n-propylbenzene 11.37 91 313990 22.55 ug/l 100 79) 2-Chlorotoluene 11.43 91 190478 22.88 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 239704 23.64 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 20870 19.58 ug/l 89 82) 4-Chlorotoluene 11.52 91 216513 22.07 ug/l 99 83) tert-Butylbenzene 11.77 119 233790 23.17 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 248559 23.67 ug/l 100 85) sec-Butylbenzene 11.95 105 285226 22.90 ug/l 100 86) p-Isopropyltoluene 12.07 119 259356 22.51 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 146168 21.77 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 146939 21.16 ug/l 100 89) n-Butylbenzene 12.39 91 195106 19.57 ug/l 100 90) Hexachloroethane 12.60 117 40842 22.82 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 151449 22.63 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 19373 24.48 ug/l 99 93) 1,2,4-Trichlorobenzene 13.65 180 104864 19.66 ug/l 99 94) Hexachlorobutadiene 13.79 225 58790 20.53 ug/l 99 95) Naphthalene 13.84 128 310843 22.42 ug/l 99 96) 1,2,3-Trichlorobenzene 14.02 180 112433 20.93 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed