Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051718\ Data File : VX001803.D Acq On : 17 May 2018 20:54 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 23 Sample Multiplier: 1 Quant Time: May 18 04:59:23 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 294110 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 385157 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 311867 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 204139 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 184035 46.68 ug/l 0.00 Spiked Amount 50.000 Recovery = 93.36% 35) Dibromofluoromethane 5.51 113 162857 50.10 ug/l 0.00 Spiked Amount 50.000 Recovery = 100.20% 50) Toluene-d8 8.72 98 575159 49.41 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.82% 62) 4-Bromofluorobenzene 11.14 95 191079 45.59 ug/l 0.00 Spiked Amount 50.000 Recovery = 91.18% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 135353 45.86 ug/l 98 3) Chloromethane 1.32 50 156599 49.12 ug/l 100 4) Vinyl Chloride 1.40 62 168423 48.86 ug/l 100 5) Bromomethane 1.64 94 64630 44.18 ug/l 98 6) Chloroethane 1.72 64 109265 50.33 ug/l 99 7) Trichlorofluoromethane 1.92 101 236205 47.16 ug/l 99 8) Diethyl Ether 2.19 74 101732 49.34 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.38 101 143219 47.50 ug/l 99 10) Methyl Iodide 2.51 142 191367 68.98 ug/l 98 11) Tert butyl alcohol 3.09 59 194403 277.76 ug/l 100 12) 1,1-Dichloroethene 2.37 96 137358 47.25 ug/l 97 13) Acrolein 2.30 56 109054 219.69 ug/l 100 14) Allyl chloride 2.73 41 268296 49.93 ug/l 96 15) Acrylonitrile 3.15 53 467683 266.04 ug/l 100 16) Acetone 2.45 43 404396 261.18 ug/l 99 17) Carbon Disulfide 2.57 76 326189 43.02 ug/l 100 18) Methyl Acetate 2.78 43 258250 57.05 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 485971 49.60 ug/l 100 20) Methylene Chloride 2.86 84 157757 47.60 ug/l 98 21) trans-1,2-Dichloroethene 3.17 96 147034 45.91 ug/l 97 22) Diisopropyl ether 3.88 45 512907 49.76 ug/l 98 23) Vinyl Acetate 3.83 43 1723253 232.04 ug/l 99 24) 1,1-Dichloroethane 3.70 63 280381 49.60 ug/l 100 25) 2-Butanone 4.72 43 665037 280.54 ug/l 96 26) 2,2-Dichloropropane 4.59 77 190588 41.88 ug/l 98 27) cis-1,2-Dichloroethene 4.60 96 180906 49.64 ug/l 98 28) Bromochloromethane 5.03 49 141197 56.23 ug/l 98 29) Tetrahydrofuran 5.18 42 430534 278.62 ug/l 100 30) Chloroform 5.22 83 296171 49.88 ug/l 99 31) Cyclohexane 5.57 56 245851 49.62 ug/l 99 32) 1,1,1-Trichloroethane 5.50 97 256841 50.05 ug/l 99 36) 1,1-Dichloropropene 5.80 75 210214 47.41 ug/l 99 37) Ethyl Acetate 4.87 43 244829 52.99 ug/l 99 38) Carbon Tetrachloride 5.78 117 229662 49.45 ug/l 99 39) Methylcyclohexane 7.46 83 256637 49.54 ug/l 99 40) Benzene 6.15 78 664773 50.89 ug/l 99 41) Methacrylonitrile 5.07 41 142981 53.51 ug/l 98 42) 1,2-Dichloroethane 6.21 62 226117 47.86 ug/l 98 43) Isopropyl Acetate 6.48 43 377026 52.13 ug/l 99 44) Trichloroethene 7.22 130 202656 49.98 ug/l 96 45) 1,2-Dichloropropane 7.53 63 166220 51.85 ug/l 98 46) Dibromomethane 7.67 93 113028 50.22 ug/l 99 47) Bromodichloromethane 7.90 83 218854 52.40 ug/l 98 48) Methyl methacrylate 7.79 41 202439 53.18 ug/l 97 49) 1,4-Dioxane 7.77 88 92218 1258.22 ug/l 96 51) 4-Methyl-2-Pentanone 8.66 43 1278329 278.93 ug/l 98 52) Toluene 8.79 92 424914 50.62 ug/l 100 53) t-1,3-Dichloropropene 8.45 75 254209 51.73 ug/l 100 54) cis-1,3-Dichloropropene 9.05 75 199668 46.09 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 155178 48.36 ug/l 99 56) Ethyl methacrylate 9.19 69 222979 49.00 ug/l 99 57) 1,3-Dichloropropane 9.38 76 251440 46.81 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 652782 278.89 ug/l 100 59) 2-Hexanone 9.51 43 865282 263.74 ug/l 99 60) Dibromochloromethane 9.59 129 166906 50.80 ug/l 99 61) 1,2-Dibromoethane 9.68 107 160312 47.73 ug/l 100 64) Tetrachloroethene 9.34 164 208692 51.40 ug/l 98 65) Chlorobenzene 10.15 112 429183 50.03 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 161463 53.29 ug/l 99 67) Ethyl Benzene 10.26 91 700643 51.11 ug/l 99 68) m/p-Xylenes 10.37 106 564537 104.37 ug/l 100 69) o-Xylene 10.71 106 273863 52.87 ug/l 99 70) Styrene 10.72 104 456399 53.42 ug/l 99 71) Bromoform 10.87 173 136304 48.44 ug/l 98 73) Isopropylbenzene 11.02 105 729984 54.30 ug/l 100 74) N-amyl acetate 6.48 43 377026 58.50 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 217445 53.92 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 210135m 54.13 ug/l 77) Bromobenzene 11.26 156 207724 52.58 ug/l 99 78) n-propylbenzene 11.37 91 802526 52.99 ug/l 100 79) 2-Chlorotoluene 11.43 91 479174 52.90 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 606086 54.95 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 60522 46.70 ug/l 97 82) 4-Chlorotoluene 11.52 91 550475 51.58 ug/l 99 83) tert-Butylbenzene 11.77 119 596876 54.38 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 627268 54.92 ug/l 100 85) sec-Butylbenzene 11.95 105 733380 54.13 ug/l 100 86) p-Isopropyltoluene 12.07 119 669845 53.43 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 370252 50.68 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 370285 49.02 ug/l 100 89) n-Butylbenzene 12.40 91 539860 49.79 ug/l 100 90) Hexachloroethane 12.60 117 108655 55.81 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 381296 52.38 ug/l 98 92) 1,2-Dibromo-3-Chloropropan 13.01 75 50369 58.52 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 283539 48.87 ug/l 99 94) Hexachlorobutadiene 13.79 225 152655 49.01 ug/l 98 95) Naphthalene 13.84 128 831355 55.12 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 295671 50.61 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed