Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX052218\ Data File : VX001891.D Acq On : 22 May 2018 13:54 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 2 Sample Multiplier: 1 Quant Time: May 23 07:56:50 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 278416 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 353092 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 302758 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 201339 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 186848 50.07 ug/l 0.00 Spiked Amount 50.000 Recovery = 100.14% 35) Dibromofluoromethane 5.51 113 158358 53.14 ug/l 0.00 Spiked Amount 50.000 Recovery = 106.28% 50) Toluene-d8 8.72 98 577693 54.13 ug/l 0.00 Spiked Amount 50.000 Recovery = 108.26% 62) 4-Bromofluorobenzene 11.14 95 195202 50.80 ug/l 0.00 Spiked Amount 50.000 Recovery = 101.60% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 126481 45.27 ug/l 100 3) Chloromethane 1.32 50 143057 47.40 ug/l 100 4) Vinyl Chloride 1.40 62 148573 45.53 ug/l 100 5) Bromomethane 1.64 94 61946 44.78 ug/l 97 6) Chloroethane 1.71 64 97797 47.58 ug/l 98 7) Trichlorofluoromethane 1.92 101 231593 48.84 ug/l 98 8) Diethyl Ether 2.19 74 93535 47.92 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.38 101 140308 49.16 ug/l 99 10) Methyl Iodide 2.51 142 180214 68.62 ug/l 99 11) Tert butyl alcohol 3.08 59 163370 246.58 ug/l 99 12) 1,1-Dichloroethene 2.37 96 125191 45.49 ug/l 97 13) Acrolein 2.29 56 71610 152.39 ug/l 100 14) Allyl chloride 2.73 41 254151 49.97 ug/l 98 15) Acrylonitrile 3.15 53 418196 251.30 ug/l 99 16) Acetone 2.45 43 368720 251.56 ug/l 99 17) Carbon Disulfide 2.57 76 284688 39.66 ug/l 98 18) Methyl Acetate 2.78 43 239611 55.92 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 464532 50.08 ug/l 99 20) Methylene Chloride 2.86 84 147657 47.06 ug/l 96 21) trans-1,2-Dichloroethene 3.16 96 135802 44.80 ug/l 97 22) Diisopropyl ether 3.87 45 497248 50.96 ug/l 97 23) Vinyl Acetate 3.83 43 1672484 237.89 ug/l 99 24) 1,1-Dichloroethane 3.70 63 264716 49.47 ug/l 100 25) 2-Butanone 4.71 43 606385 270.22 ug/l 100 26) 2,2-Dichloropropane 4.59 77 200180 46.47 ug/l 100 27) cis-1,2-Dichloroethene 4.60 96 168488 48.84 ug/l 98 28) Bromochloromethane 5.03 49 144590 60.83 ug/l 98 29) Tetrahydrofuran 5.17 42 389561 266.32 ug/l 98 30) Chloroform 5.21 83 291341 51.83 ug/l 98 31) Cyclohexane 5.57 56 233302 49.74 ug/l 96 32) 1,1,1-Trichloroethane 5.49 97 249171 51.30 ug/l 98 36) 1,1-Dichloropropene 5.80 75 204915 50.41 ug/l 99 37) Ethyl Acetate 4.87 43 229668 54.22 ug/l 99 38) Carbon Tetrachloride 5.78 117 229083 53.80 ug/l 98 39) Methylcyclohexane 7.46 83 249707 52.58 ug/l 99 40) Benzene 6.15 78 628252 52.46 ug/l 99 41) Methacrylonitrile 5.07 41 135433 55.29 ug/l 98 42) 1,2-Dichloroethane 6.20 62 231591 53.47 ug/l 99 43) Isopropyl Acetate 6.47 43 361901 54.59 ug/l 99 44) Trichloroethene 7.21 130 191403 51.49 ug/l 98 45) 1,2-Dichloropropane 7.52 63 157621 53.64 ug/l 99 46) Dibromomethane 7.67 93 108515 52.59 ug/l 100 47) Bromodichloromethane 7.90 83 217870 56.90 ug/l 95 48) Methyl methacrylate 7.78 41 196977 56.45 ug/l 99 49) 1,4-Dioxane 7.76 88 80420 1196.89 ug/l 97 51) 4-Methyl-2-Pentanone 8.66 43 1232327 293.31 ug/l 98 52) Toluene 8.79 92 412339 53.58 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 246688 54.76 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 224345 56.49 ug/l 97 55) 1,1,2-Trichloroethane 9.22 97 158856 54.00 ug/l 99 56) Ethyl methacrylate 9.19 69 242807 58.21 ug/l 97 57) 1,3-Dichloropropane 9.38 76 255294 51.84 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 630382 293.78 ug/l 99 59) 2-Hexanone 9.50 43 846817 281.56 ug/l 99 60) Dibromochloromethane 9.59 129 169223 56.18 ug/l 100 61) 1,2-Dibromoethane 9.68 107 160239 52.04 ug/l 100 64) Tetrachloroethene 9.34 164 206999 52.52 ug/l 98 65) Chlorobenzene 10.14 112 432564 51.94 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 163671 55.65 ug/l 100 67) Ethyl Benzene 10.26 91 716762 53.86 ug/l 99 68) m/p-Xylenes 10.37 106 566542 107.89 ug/l 98 69) o-Xylene 10.70 106 276111 54.91 ug/l 99 70) Styrene 10.72 104 460481 55.52 ug/l 100 71) Bromoform 10.86 173 140260 51.17 ug/l 99 73) Isopropylbenzene 11.02 105 747132 56.35 ug/l 100 74) N-amyl acetate 6.47 43 361901 56.93 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 215184 54.10 ug/l 98 76) 1,2,3-Trichloropropane 11.30 75 214105m 55.92 ug/l 77) Bromobenzene 11.26 156 211370 54.25 ug/l 99 78) n-propylbenzene 11.37 91 832108 55.70 ug/l 99 79) 2-Chlorotoluene 11.43 91 493798 55.27 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 623491 57.32 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 62376 48.65 ug/l 97 82) 4-Chlorotoluene 11.52 91 569952 54.15 ug/l 99 83) tert-Butylbenzene 11.77 119 622264 57.48 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 643024 57.08 ug/l 99 85) sec-Butylbenzene 11.95 105 760030 56.88 ug/l 100 86) p-Isopropyltoluene 12.07 119 701989 56.77 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 377655 52.41 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 382319 51.31 ug/l 100 89) n-Butylbenzene 12.40 91 571387 53.43 ug/l 99 90) Hexachloroethane 12.60 117 115376 60.08 ug/l 100 91) 1,2-Dichlorobenzene 12.40 146 386321 53.81 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 50391 59.36 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 294264 51.42 ug/l 99 94) Hexachlorobutadiene 13.79 225 163340 53.17 ug/l 100 95) Naphthalene 13.84 128 819968 55.13 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 305226 52.97 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed