Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX052218\ Data File : VX001893.D Acq On : 22 May 2018 15:10 Operator : JC/MD Sample : VX0522WBS01 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 4 Sample Multiplier: 1 Quant Time: May 23 01:43:55 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 314180 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 395929 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 343544 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 224326 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 212400 50.44 ug/l 0.00 Spiked Amount 50.000 Recovery = 100.88% 35) Dibromofluoromethane 5.51 113 177951 53.26 ug/l 0.00 Spiked Amount 50.000 Recovery = 106.52% 50) Toluene-d8 8.72 98 645639 53.95 ug/l 0.00 Spiked Amount 50.000 Recovery = 107.90% 62) 4-Bromofluorobenzene 11.14 95 218339 50.67 ug/l 0.00 Spiked Amount 50.000 Recovery = 101.34% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 61508 19.51 ug/l 99 3) Chloromethane 1.32 50 69210 20.32 ug/l 98 4) Vinyl Chloride 1.40 62 71111 19.31 ug/l 99 5) Bromomethane 1.64 94 36794 21.96 ug/l 97 6) Chloroethane 1.72 64 47566 20.51 ug/l 99 7) Trichlorofluoromethane 1.93 101 112780 21.08 ug/l 100 8) Diethyl Ether 2.19 74 45150 20.50 ug/l 96 9) 1,1,2-Trichlorotrifluoroet 2.39 101 69842 21.68 ug/l 99 10) Methyl Iodide 2.51 142 83549 28.19 ug/l 99 11) Tert butyl alcohol 3.08 59 85325 114.12 ug/l 99 12) 1,1-Dichloroethene 2.37 96 60395 19.45 ug/l 95 13) Acrolein 2.30 56 33264 62.73 ug/l 95 14) Allyl chloride 2.73 41 123995 21.60 ug/l 98 15) Acrylonitrile 3.15 53 207598 110.55 ug/l 99 16) Acetone 2.45 43 206993 125.14 ug/l 96 17) Carbon Disulfide 2.57 76 128762 15.90 ug/l 100 18) Methyl Acetate 2.78 43 118049 24.41 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 227303 21.72 ug/l 99 20) Methylene Chloride 2.85 84 71566 20.21 ug/l 96 21) trans-1,2-Dichloroethene 3.17 96 64812 18.95 ug/l 93 22) Diisopropyl ether 3.88 45 244308 22.19 ug/l 99 23) Vinyl Acetate 3.83 43 813629 102.56 ug/l 99 24) 1,1-Dichloroethane 3.70 63 130973 21.69 ug/l 99 25) 2-Butanone 4.71 43 307522 121.44 ug/l 99 26) 2,2-Dichloropropane 4.59 77 104344 21.46 ug/l 100 27) cis-1,2-Dichloroethene 4.60 96 81305 20.89 ug/l 96 28) Bromochloromethane 5.02 49 63077 23.51 ug/l 96 29) Tetrahydrofuran 5.17 42 189254 114.65 ug/l 98 30) Chloroform 5.22 83 141191 22.26 ug/l 97 31) Cyclohexane 5.57 56 111007 20.97 ug/l 98 32) 1,1,1-Trichloroethane 5.50 97 119973 21.89 ug/l 98 36) 1,1-Dichloropropene 5.80 75 95652 20.99 ug/l 99 37) Ethyl Acetate 4.87 43 111426 23.46 ug/l 99 38) Carbon Tetrachloride 5.79 117 108173 22.66 ug/l 99 39) Methylcyclohexane 7.46 83 117937 22.15 ug/l 96 40) Benzene 6.15 78 301692 22.47 ug/l 99 41) Methacrylonitrile 5.07 41 64689 23.55 ug/l 97 42) 1,2-Dichloroethane 6.20 62 113889 23.45 ug/l 99 43) Isopropyl Acetate 6.48 43 172057 23.14 ug/l 99 44) Trichloroethene 7.22 130 91879 22.04 ug/l 98 45) 1,2-Dichloropropane 7.52 63 78764 23.90 ug/l 97 46) Dibromomethane 7.67 93 52514 22.70 ug/l 99 47) Bromodichloromethane 7.90 83 101758 23.70 ug/l 93 48) Methyl methacrylate 7.79 41 92407 23.62 ug/l 98 49) 1,4-Dioxane 7.76 88 39020 517.90 ug/l 99 51) 4-Methyl-2-Pentanone 8.66 43 600867 127.54 ug/l 97 52) Toluene 8.79 92 198735 23.03 ug/l 99 53) t-1,3-Dichloropropene 8.44 75 116525 23.07 ug/l 100 54) cis-1,3-Dichloropropene 9.05 75 98593 22.14 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 76693 23.25 ug/l 97 56) Ethyl methacrylate 9.19 69 111254 23.79 ug/l 96 57) 1,3-Dichloropropane 9.38 76 126625 22.93 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 298904 124.23 ug/l 99 59) 2-Hexanone 9.50 43 423858 125.68 ug/l 98 60) Dibromochloromethane 9.59 129 78664 23.29 ug/l 99 61) 1,2-Dibromoethane 9.68 107 77878 22.55 ug/l 100 64) Tetrachloroethene 9.34 164 102366 22.89 ug/l 99 65) Chlorobenzene 10.14 112 209891 22.21 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 78705 23.58 ug/l 100 67) Ethyl Benzene 10.26 91 341587 22.62 ug/l 99 68) m/p-Xylenes 10.37 106 272867 45.79 ug/l 99 69) o-Xylene 10.70 106 132314 23.19 ug/l 100 70) Styrene 10.72 104 218508 23.22 ug/l 100 71) Bromoform 10.87 173 63270 22.10 ug/l # 100 73) Isopropylbenzene 11.02 105 361096 24.44 ug/l 100 74) N-amyl acetate 6.48 43 172057 24.29 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 107684 24.30 ug/l 98 76) 1,2,3-Trichloropropane 11.30 75 105724m 24.78 ug/l 77) Bromobenzene 11.26 156 100804 23.22 ug/l 99 78) n-propylbenzene 11.37 91 398489 23.94 ug/l 100 79) 2-Chlorotoluene 11.43 91 241476 24.26 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 302161 24.93 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 28313 21.78 ug/l 91 82) 4-Chlorotoluene 11.52 91 275292 23.48 ug/l 99 83) tert-Butylbenzene 11.77 119 297379 24.66 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 310982 24.78 ug/l 100 85) sec-Butylbenzene 11.95 105 364717 24.50 ug/l 99 86) p-Isopropyltoluene 12.07 119 334330 24.27 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 184354 22.96 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 187292 22.56 ug/l 99 89) n-Butylbenzene 12.40 91 266331 22.35 ug/l 100 90) Hexachloroethane 12.60 117 52897 24.72 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 185119 23.14 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 23697 25.05 ug/l 96 93) 1,2,4-Trichlorobenzene 13.65 180 138273 21.69 ug/l 100 94) Hexachlorobutadiene 13.79 225 77841 22.74 ug/l 99 95) Naphthalene 13.84 128 384217 23.18 ug/l 99 96) 1,2,3-Trichlorobenzene 14.02 180 143054 22.28 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed