Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX052218\ Data File : VX001899.D Acq On : 22 May 2018 17:50 Operator : JC/MD Sample : J2988-03MS Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 10 Sample Multiplier: 1 Quant Time: May 23 08:25:34 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 249094 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 325208 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 280306 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 184113 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 170733 51.14 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.28% 35) Dibromofluoromethane 5.51 113 144117 52.51 ug/l 0.00 Spiked Amount 50.000 Recovery = 105.02% 50) Toluene-d8 8.72 98 516851 52.58 ug/l 0.00 Spiked Amount 50.000 Recovery = 105.16% 62) 4-Bromofluorobenzene 11.14 95 172878 48.85 ug/l 0.00 Spiked Amount 50.000 Recovery = 97.70% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 110579 44.24 ug/l 100 3) Chloromethane 1.32 50 131094 48.55 ug/l 100 4) Vinyl Chloride 1.40 62 136004 46.59 ug/l 99 5) Bromomethane 1.64 94 58341 47.31 ug/l 94 6) Chloroethane 1.72 64 94761 51.53 ug/l 99 7) Trichlorofluoromethane 1.92 101 207055 48.81 ug/l 100 8) Diethyl Ether 2.19 74 88250 50.54 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.38 101 123738 48.45 ug/l 99 10) Methyl Iodide 2.51 142 167190 71.16 ug/l 98 11) Tert butyl alcohol 3.09 59 189604 319.86 ug/l 99 12) 1,1-Dichloroethene 2.37 96 113910 46.27 ug/l 98 13) Acrolein 2.30 56 70273 167.15 ug/l 99 14) Allyl chloride 2.73 41 241866 53.15 ug/l 98 15) Acrylonitrile 3.15 53 427021 286.81 ug/l 99 16) Acetone 2.45 43 379650 289.50 ug/l 98 17) Carbon Disulfide 2.57 76 250604 39.02 ug/l 98 18) Methyl Acetate 2.78 43 239470 62.46 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 436927 52.65 ug/l 100 20) Methylene Chloride 2.86 84 138510 49.34 ug/l 96 21) trans-1,2-Dichloroethene 3.17 96 125126 46.13 ug/l 98 22) Diisopropyl ether 3.88 45 464209 53.17 ug/l 99 23) Vinyl Acetate 3.83 43 1552860 246.88 ug/l 98 24) 1,1-Dichloroethane 3.70 63 248591 51.92 ug/l 100 25) 2-Butanone 4.72 43 637497 317.52 ug/l 100 26) 2,2-Dichloropropane 4.59 77 190781 49.50 ug/l 100 27) cis-1,2-Dichloroethene 4.60 96 162764 52.74 ug/l 97 28) Bromochloromethane 5.03 49 136561 64.21 ug/l 96 29) Tetrahydrofuran 5.18 42 411042 314.08 ug/l 98 30) Chloroform 5.22 83 271475 53.98 ug/l 100 31) Cyclohexane 5.57 56 205446 48.95 ug/l 98 32) 1,1,1-Trichloroethane 5.49 97 232561 53.51 ug/l 99 36) 1,1-Dichloropropene 5.80 75 184554 49.30 ug/l 99 37) Ethyl Acetate 4.87 43 231591 59.36 ug/l 99 38) Carbon Tetrachloride 5.79 117 209862 53.51 ug/l 99 39) Methylcyclohexane 7.46 83 214175 48.96 ug/l 97 40) Benzene 6.15 78 582939 52.85 ug/l 100 41) Methacrylonitrile 5.07 41 136724 60.60 ug/l 97 42) 1,2-Dichloroethane 6.21 62 218391 54.75 ug/l 99 43) Isopropyl Acetate 6.48 43 351619 57.58 ug/l 99 44) Trichloroethene 7.22 130 183996 53.74 ug/l 98 45) 1,2-Dichloropropane 7.52 63 148724 54.95 ug/l 96 46) Dibromomethane 7.67 93 102594 53.98 ug/l 99 47) Bromodichloromethane 7.91 83 202594 57.45 ug/l 97 48) Methyl methacrylate 7.79 41 193867 60.32 ug/l 98 49) 1,4-Dioxane 7.77 88 85914 1388.29 ug/l 99 51) 4-Methyl-2-Pentanone 8.66 43 1245188 321.78 ug/l 98 52) Toluene 8.79 92 378571 53.41 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 223658 53.90 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 188262 51.47 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 147205 54.33 ug/l 98 56) Ethyl methacrylate 9.19 69 213670 55.62 ug/l 98 57) 1,3-Dichloropropane 9.38 76 238848 52.66 ug/l 100 59) 2-Hexanone 9.51 43 877154 316.65 ug/l 99 60) Dibromochloromethane 9.59 129 158197 57.02 ug/l 99 61) 1,2-Dibromoethane 9.68 107 151370 53.37 ug/l 99 64) Tetrachloroethene 9.34 164 236440 64.80 ug/l 99 65) Chlorobenzene 10.15 112 395087 51.24 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 154335 56.67 ug/l 98 67) Ethyl Benzene 10.26 91 648252 52.61 ug/l 99 68) m/p-Xylenes 10.37 106 519947 106.95 ug/l 100 69) o-Xylene 10.71 106 253603 54.47 ug/l 100 70) Styrene 10.72 104 407581 53.08 ug/l 100 71) Bromoform 10.87 173 131691 51.85 ug/l 100 73) Isopropylbenzene 11.02 105 680603 56.13 ug/l 100 74) N-amyl acetate 6.48 43 351619 60.49 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 212541 58.44 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 209357m 59.80 ug/l 77) Bromobenzene 11.26 156 194488 54.59 ug/l 99 78) n-propylbenzene 11.37 91 744922 54.53 ug/l 99 79) 2-Chlorotoluene 11.43 91 450069 55.09 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 560777 56.38 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 59312 50.45 ug/l 98 82) 4-Chlorotoluene 11.52 91 516595 53.68 ug/l 99 83) tert-Butylbenzene 11.77 119 575406 58.13 ug/l 98 84) 1,2,4-Trimethylbenzene 11.81 105 583624 56.66 ug/l 100 85) sec-Butylbenzene 11.95 105 678879 55.56 ug/l 100 86) p-Isopropyltoluene 12.07 119 620153 54.85 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 343811 52.18 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 344097 50.51 ug/l 100 89) n-Butylbenzene 12.40 91 491748 50.29 ug/l 100 90) Hexachloroethane 12.60 117 102102 58.14 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 355521 54.15 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 49719 64.05 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 259081 49.51 ug/l 99 94) Hexachlorobutadiene 13.79 225 139629 49.70 ug/l 99 95) Naphthalene 13.84 128 783933 57.63 ug/l 100 96) 1,2,3-Trichlorobenzene 14.03 180 276412 52.46 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed