Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX052218\ Data File : VX001900.D Acq On : 22 May 2018 18:17 Operator : JC/MD Sample : J2988-04MSD Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 11 Sample Multiplier: 1 Quant Time: May 23 08:27:27 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 244865 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 323439 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 272558 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 178142 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 167502 51.03 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.06% 35) Dibromofluoromethane 5.51 113 144507 52.94 ug/l 0.00 Spiked Amount 50.000 Recovery = 105.88% 50) Toluene-d8 8.72 98 507832 51.95 ug/l 0.00 Spiked Amount 50.000 Recovery = 103.90% 62) 4-Bromofluorobenzene 11.14 95 169956 48.29 ug/l 0.00 Spiked Amount 50.000 Recovery = 96.58% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 107656 43.81 ug/l 99 3) Chloromethane 1.32 50 133690 50.36 ug/l 100 4) Vinyl Chloride 1.40 62 137749 48.00 ug/l 99 5) Bromomethane 1.64 94 60424 50.03 ug/l 99 6) Chloroethane 1.72 64 97521 53.95 ug/l 98 7) Trichlorofluoromethane 1.92 101 203895 48.89 ug/l 98 8) Diethyl Ether 2.19 74 89888 52.37 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.38 101 119398 47.56 ug/l 100 10) Methyl Iodide 2.51 142 172944 74.88 ug/l 99 11) Tert butyl alcohol 3.09 59 191868 329.27 ug/l 99 12) 1,1-Dichloroethene 2.37 96 113256 46.80 ug/l 98 13) Acrolein 2.30 56 70843 171.42 ug/l 97 14) Allyl chloride 2.73 41 242023 54.10 ug/l 98 15) Acrylonitrile 3.15 53 434647 296.98 ug/l 100 16) Acetone 2.45 43 380994 295.55 ug/l 98 17) Carbon Disulfide 2.57 76 250823 39.73 ug/l 98 18) Methyl Acetate 2.78 43 241758 64.15 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 442920 54.30 ug/l 100 20) Methylene Chloride 2.86 84 138913 50.34 ug/l 97 21) trans-1,2-Dichloroethene 3.16 96 126143 47.31 ug/l 98 22) Diisopropyl ether 3.88 45 471225 54.91 ug/l 97 23) Vinyl Acetate 3.83 43 1566072 253.28 ug/l 98 24) 1,1-Dichloroethane 3.70 63 248864 52.88 ug/l 99 25) 2-Butanone 4.72 43 644764 326.69 ug/l 98 26) 2,2-Dichloropropane 4.59 77 186865 49.32 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 166595 54.91 ug/l 99 28) Bromochloromethane 5.03 49 132508 63.38 ug/l 97 29) Tetrahydrofuran 5.18 42 412284 320.47 ug/l 98 30) Chloroform 5.22 83 273379 55.30 ug/l 99 31) Cyclohexane 5.57 56 203556 49.34 ug/l 97 32) 1,1,1-Trichloroethane 5.50 97 232513 54.43 ug/l 99 36) 1,1-Dichloropropene 5.80 75 181655 48.79 ug/l 99 37) Ethyl Acetate 4.88 43 230682 59.45 ug/l 99 38) Carbon Tetrachloride 5.79 117 206450 52.93 ug/l 97 39) Methylcyclohexane 7.46 83 207707 47.75 ug/l 99 40) Benzene 6.15 78 584990 53.33 ug/l 100 41) Methacrylonitrile 5.07 41 136677 60.91 ug/l 98 42) 1,2-Dichloroethane 6.21 62 217787 54.89 ug/l 100 43) Isopropyl Acetate 6.48 43 355854 58.60 ug/l 99 44) Trichloroethene 7.22 130 181941 53.44 ug/l 99 45) 1,2-Dichloropropane 7.52 63 151844 56.41 ug/l 99 46) Dibromomethane 7.67 93 102771 54.37 ug/l 99 47) Bromodichloromethane 7.90 83 203781 58.10 ug/l 100 48) Methyl methacrylate 7.79 41 196111 61.35 ug/l 98 49) 1,4-Dioxane 7.77 88 87660 1424.25 ug/l 99 51) 4-Methyl-2-Pentanone 8.66 43 1239567 322.08 ug/l 100 52) Toluene 8.79 92 382255 54.23 ug/l 99 53) t-1,3-Dichloropropene 8.45 75 226819 54.96 ug/l 98 54) cis-1,3-Dichloropropene 9.05 75 202993 55.80 ug/l 94 55) 1,1,2-Trichloroethane 9.22 97 145736 54.09 ug/l 98 56) Ethyl methacrylate 9.19 69 214948 56.25 ug/l 99 57) 1,3-Dichloropropane 9.38 76 239078 53.00 ug/l 100 59) 2-Hexanone 9.51 43 876496 318.14 ug/l 99 60) Dibromochloromethane 9.59 129 156400 56.68 ug/l 100 61) 1,2-Dibromoethane 9.68 107 150725 53.43 ug/l 99 64) Tetrachloroethene 9.34 164 228153 64.30 ug/l 96 65) Chlorobenzene 10.15 112 392901 52.41 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 152217 57.49 ug/l 99 67) Ethyl Benzene 10.26 91 644145 53.76 ug/l 99 68) m/p-Xylenes 10.37 106 513005 108.52 ug/l 100 69) o-Xylene 10.71 106 253370 55.97 ug/l 100 70) Styrene 10.72 104 405029 54.24 ug/l 99 71) Bromoform 10.87 173 130452 52.76 ug/l 100 73) Isopropylbenzene 11.02 105 674679 57.51 ug/l 100 74) N-amyl acetate 6.48 43 355854 63.27 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 212907 60.50 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 206852m 61.06 ug/l 77) Bromobenzene 11.26 156 193203 56.04 ug/l 99 78) n-propylbenzene 11.37 91 734636 55.58 ug/l 99 79) 2-Chlorotoluene 11.43 91 445983 56.42 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 556293 57.80 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 58157 51.09 ug/l 97 82) 4-Chlorotoluene 11.52 91 511840 54.96 ug/l 99 83) tert-Butylbenzene 11.77 119 574590 59.99 ug/l 97 84) 1,2,4-Trimethylbenzene 11.81 105 577876 57.98 ug/l 100 85) sec-Butylbenzene 11.95 105 668192 56.52 ug/l 100 86) p-Isopropyltoluene 12.07 119 617526 56.45 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 342958 53.80 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 345847 52.46 ug/l 100 89) n-Butylbenzene 12.40 91 484254 51.18 ug/l 100 90) Hexachloroethane 12.60 117 101440 59.70 ug/l 98 91) 1,2-Dichlorobenzene 12.40 146 356134 56.07 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 50067 66.66 ug/l 99 93) 1,2,4-Trichlorobenzene 13.65 180 258511 51.06 ug/l 100 94) Hexachlorobutadiene 13.79 225 132526 48.75 ug/l 98 95) Naphthalene 13.84 128 778054 59.12 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 274873 53.91 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed