Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX052218\ Data File : VX001901.D Acq On : 22 May 2018 18:43 Operator : JC/MD Sample : VX0522WBSD01 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 12 Sample Multiplier: 1 Quant Time: May 23 02:09:17 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 256420 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 337898 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 286849 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 180754 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 181415 52.78 ug/l 0.00 Spiked Amount 50.000 Recovery = 105.56% 35) Dibromofluoromethane 5.51 113 151155 53.01 ug/l 0.00 Spiked Amount 50.000 Recovery = 106.02% 50) Toluene-d8 8.72 98 546975 53.56 ug/l 0.00 Spiked Amount 50.000 Recovery = 107.12% 62) 4-Bromofluorobenzene 11.14 95 177704 48.33 ug/l 0.00 Spiked Amount 50.000 Recovery = 96.66% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 47821 18.58 ug/l 99 3) Chloromethane 1.32 50 55079 19.81 ug/l 99 4) Vinyl Chloride 1.40 62 58553 19.48 ug/l 99 5) Bromomethane 1.64 94 34246 25.52 ug/l 94 6) Chloroethane 1.72 64 43785 23.13 ug/l 97 7) Trichlorofluoromethane 1.93 101 89089 20.40 ug/l 97 8) Diethyl Ether 2.19 74 36599 20.36 ug/l 96 9) 1,1,2-Trichlorotrifluoroet 2.39 101 52959 20.15 ug/l 99 10) Methyl Iodide 2.51 142 67720 28.00 ug/l 99 11) Tert butyl alcohol 3.08 59 74439 121.99 ug/l 100 12) 1,1-Dichloroethene 2.37 96 48602 19.18 ug/l 97 13) Acrolein 2.29 56 30211 69.81 ug/l 98 14) Allyl chloride 2.73 41 100259 21.40 ug/l 99 15) Acrylonitrile 3.15 53 176846 115.39 ug/l 99 16) Acetone 2.45 43 160652 119.01 ug/l 98 17) Carbon Disulfide 2.57 76 103539 15.66 ug/l 99 18) Methyl Acetate 2.78 43 102584 25.99 ug/l 98 19) Methyl tert-butyl Ether 3.21 73 184018 21.54 ug/l 99 20) Methylene Chloride 2.86 84 58268 20.16 ug/l 98 21) trans-1,2-Dichloroethene 3.17 96 53385 19.12 ug/l 97 22) Diisopropyl ether 3.88 45 194147 21.60 ug/l 99 23) Vinyl Acetate 3.83 43 655663 101.26 ug/l 98 24) 1,1-Dichloroethane 3.70 63 104111 21.12 ug/l 99 25) 2-Butanone 4.72 43 261130 126.35 ug/l 100 26) 2,2-Dichloropropane 4.59 77 74548 18.79 ug/l 100 27) cis-1,2-Dichloroethene 4.60 96 66582 20.96 ug/l 97 28) Bromochloromethane 5.03 49 55079 25.16 ug/l 98 29) Tetrahydrofuran 5.18 42 166335 123.47 ug/l 97 30) Chloroform 5.22 83 113431 21.91 ug/l 97 31) Cyclohexane 5.57 56 86628 20.05 ug/l 98 32) 1,1,1-Trichloroethane 5.50 97 97423 21.78 ug/l 99 36) 1,1-Dichloropropene 5.80 75 76040 19.55 ug/l 99 37) Ethyl Acetate 4.88 43 95594 23.58 ug/l 99 38) Carbon Tetrachloride 5.79 117 85688 21.03 ug/l 99 39) Methylcyclohexane 7.46 83 87433 19.24 ug/l 97 40) Benzene 6.15 78 240625 21.00 ug/l 100 41) Methacrylonitrile 5.07 41 54649 23.31 ug/l 98 42) 1,2-Dichloroethane 6.21 62 91319 22.03 ug/l 100 43) Isopropyl Acetate 6.48 43 141270 22.27 ug/l 100 44) Trichloroethene 7.22 130 72451 20.37 ug/l 96 45) 1,2-Dichloropropane 7.52 63 62594 22.26 ug/l 100 46) Dibromomethane 7.67 93 42057 21.30 ug/l 100 47) Bromodichloromethane 7.91 83 81783 22.32 ug/l 97 48) Methyl methacrylate 7.79 41 75766 22.69 ug/l 99 49) 1,4-Dioxane 7.77 88 33051 514.02 ug/l 99 51) 4-Methyl-2-Pentanone 8.66 43 501871 124.82 ug/l 98 52) Toluene 8.79 92 155947 21.18 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 90678 21.03 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 74924 19.72 ug/l 97 55) 1,1,2-Trichloroethane 9.22 97 61002 21.67 ug/l 97 56) Ethyl methacrylate 9.19 69 83059 20.81 ug/l 98 57) 1,3-Dichloropropane 9.38 76 99024 21.01 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 230947 112.47 ug/l 98 59) 2-Hexanone 9.51 43 349604 121.47 ug/l 98 60) Dibromochloromethane 9.59 129 61337 21.28 ug/l 100 61) 1,2-Dibromoethane 9.68 107 62626 21.25 ug/l 99 64) Tetrachloroethene 9.34 164 75685 20.27 ug/l 97 65) Chlorobenzene 10.15 112 163719 20.75 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 62090 22.28 ug/l 99 67) Ethyl Benzene 10.26 91 260260 20.64 ug/l 99 68) m/p-Xylenes 10.37 106 207226 41.65 ug/l 98 69) o-Xylene 10.71 106 101401 21.28 ug/l 98 70) Styrene 10.72 104 167952 21.37 ug/l 100 71) Bromoform 10.87 173 48378 20.49 ug/l 99 73) Isopropylbenzene 11.02 105 277388 23.30 ug/l 99 74) N-amyl acetate 6.48 43 141270 24.75 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 87393 24.47 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 84607m 24.62 ug/l 77) Bromobenzene 11.26 156 79581 22.75 ug/l 99 78) n-propylbenzene 11.37 91 298537 22.26 ug/l 99 79) 2-Chlorotoluene 11.43 91 183555 22.89 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 226122 23.16 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 20732 20.09 ug/l 88 82) 4-Chlorotoluene 11.52 91 209215 22.14 ug/l 99 83) tert-Butylbenzene 11.77 119 232696 23.94 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 234032 23.14 ug/l 100 85) sec-Butylbenzene 11.95 105 271917 22.67 ug/l 100 86) p-Isopropyltoluene 12.07 119 246440 22.20 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 138441 21.40 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 141351 21.13 ug/l 100 89) n-Butylbenzene 12.40 91 186342 19.41 ug/l 99 90) Hexachloroethane 12.60 117 39664 23.01 ug/l 100 91) 1,2-Dichlorobenzene 12.40 146 145028 22.50 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 19474 25.55 ug/l 95 93) 1,2,4-Trichlorobenzene 13.65 180 100685 19.60 ug/l 100 94) Hexachlorobutadiene 13.79 225 55510 20.13 ug/l 99 95) Naphthalene 13.84 128 300527 22.50 ug/l 99 96) 1,2,3-Trichlorobenzene 14.02 180 108374 20.95 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed