Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX052218\ Data File : VX001912.D Acq On : 22 May 2018 23:38 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 23 Sample Multiplier: 1 Quant Time: May 23 03:11:48 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 248879 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 330247 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 282222 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 190171 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 174871 52.42 ug/l 0.00 Spiked Amount 50.000 Recovery = 104.84% 35) Dibromofluoromethane 5.51 113 150922 54.15 ug/l 0.00 Spiked Amount 50.000 Recovery = 108.30% 50) Toluene-d8 8.72 98 542960 54.40 ug/l 0.00 Spiked Amount 50.000 Recovery = 108.80% 62) 4-Bromofluorobenzene 11.14 95 180591 50.25 ug/l 0.00 Spiked Amount 50.000 Recovery = 100.50% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 109452 43.82 ug/l 99 3) Chloromethane 1.32 50 135757 50.32 ug/l 98 4) Vinyl Chloride 1.40 62 139582 47.85 ug/l 98 5) Bromomethane 1.64 94 57098 46.28 ug/l 99 6) Chloroethane 1.72 64 93032 50.64 ug/l 99 7) Trichlorofluoromethane 1.93 101 207849 49.04 ug/l 99 8) Diethyl Ether 2.19 74 90111 51.65 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.38 101 121960 47.80 ug/l 99 10) Methyl Iodide 2.51 142 149233 63.57 ug/l 99 11) Tert butyl alcohol 3.09 59 182790 308.63 ug/l 99 12) 1,1-Dichloroethene 2.37 96 116178 47.23 ug/l 98 13) Acrolein 2.30 56 59087 140.67 ug/l 99 14) Allyl chloride 2.73 41 238421 52.44 ug/l 98 15) Acrylonitrile 3.15 53 431998 290.41 ug/l 99 16) Acetone 2.45 43 378062 288.54 ug/l 97 17) Carbon Disulfide 2.57 76 252582 39.36 ug/l 99 18) Methyl Acetate 2.78 43 252371 65.89 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 445501 53.73 ug/l 100 20) Methylene Chloride 2.86 84 141142 50.33 ug/l 98 21) trans-1,2-Dichloroethene 3.17 96 125404 46.28 ug/l 97 22) Diisopropyl ether 3.88 45 493753 56.61 ug/l 99 23) Vinyl Acetate 3.83 43 1667973 265.41 ug/l 99 24) 1,1-Dichloroethane 3.70 63 252443 52.77 ug/l 100 25) 2-Butanone 4.72 43 637260 317.68 ug/l 100 26) 2,2-Dichloropropane 4.59 77 146238 37.97 ug/l 97 27) cis-1,2-Dichloroethene 4.60 96 160951 52.20 ug/l 99 28) Bromochloromethane 5.03 49 134745 63.41 ug/l 99 29) Tetrahydrofuran 5.18 42 412747 315.66 ug/l 98 30) Chloroform 5.22 83 276817 55.09 ug/l 100 31) Cyclohexane 5.58 56 207075 49.38 ug/l 98 32) 1,1,1-Trichloroethane 5.50 97 234523 54.01 ug/l 99 36) 1,1-Dichloropropene 5.80 75 187391 49.29 ug/l 100 37) Ethyl Acetate 4.87 43 237371 59.91 ug/l 99 38) Carbon Tetrachloride 5.79 117 208634 52.39 ug/l 99 39) Methylcyclohexane 7.46 83 210048 47.29 ug/l 98 40) Benzene 6.15 78 592174 52.87 ug/l 99 41) Methacrylonitrile 5.07 41 137659 60.08 ug/l 97 42) 1,2-Dichloroethane 6.20 62 220338 54.39 ug/l 100 43) Isopropyl Acetate 6.48 43 364459 58.78 ug/l 99 44) Trichloroethene 7.22 130 175473 50.47 ug/l 98 45) 1,2-Dichloropropane 7.52 63 155773 56.68 ug/l 99 46) Dibromomethane 7.67 93 104814 54.31 ug/l 100 47) Bromodichloromethane 7.90 83 207370 57.90 ug/l 98 48) Methyl methacrylate 7.79 41 199713 61.19 ug/l 99 49) 1,4-Dioxane 7.76 88 84440 1343.65 ug/l 99 51) 4-Methyl-2-Pentanone 8.66 43 1272995 323.94 ug/l 99 52) Toluene 8.79 92 382272 53.11 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 229583 54.48 ug/l 100 54) cis-1,3-Dichloropropene 9.05 75 203894 54.89 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 148916 54.13 ug/l 98 56) Ethyl methacrylate 9.19 69 225247 57.73 ug/l 99 57) 1,3-Dichloropropane 9.38 76 239489 51.99 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 602175 300.05 ug/l 100 59) 2-Hexanone 9.51 43 859413 305.51 ug/l 99 60) Dibromochloromethane 9.59 129 157274 55.83 ug/l 99 61) 1,2-Dibromoethane 9.68 107 153753 53.38 ug/l 99 64) Tetrachloroethene 9.34 164 180137 49.03 ug/l 99 65) Chlorobenzene 10.15 112 395598 50.96 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 152741 55.71 ug/l 99 67) Ethyl Benzene 10.26 91 644508 51.95 ug/l 100 68) m/p-Xylenes 10.37 106 510959 104.38 ug/l 99 69) o-Xylene 10.71 106 250875 53.52 ug/l 99 70) Styrene 10.72 104 420943 54.45 ug/l 100 71) Bromoform 10.87 173 132961 51.98 ug/l 100 73) Isopropylbenzene 11.02 105 675831 53.96 ug/l 100 74) N-amyl acetate 6.48 43 364459 60.70 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 216731 57.69 ug/l 98 76) 1,2,3-Trichloropropane 11.30 75 207257m 57.31 ug/l 77) Bromobenzene 11.26 156 194343 52.81 ug/l 100 78) n-propylbenzene 11.37 91 747891 53.01 ug/l 99 79) 2-Chlorotoluene 11.43 91 447442 53.02 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 557358 54.25 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 53386 44.39 ug/l 95 82) 4-Chlorotoluene 11.52 91 522801 52.59 ug/l 99 83) tert-Butylbenzene 11.77 119 557000 54.48 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 581012 54.61 ug/l 100 85) sec-Butylbenzene 11.95 105 679984 53.88 ug/l 100 86) p-Isopropyltoluene 12.07 119 624854 53.50 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 349013 51.28 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 352242 50.05 ug/l 99 89) n-Butylbenzene 12.40 91 507190 50.21 ug/l 100 90) Hexachloroethane 12.60 117 104427 57.57 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 354614 52.30 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 49851 62.17 ug/l 99 93) 1,2,4-Trichlorobenzene 13.65 180 270338 50.01 ug/l 100 94) Hexachlorobutadiene 13.79 225 144077 49.65 ug/l 99 95) Naphthalene 13.84 128 799440 56.90 ug/l 100 96) 1,2,3-Trichlorobenzene 14.03 180 283435 52.08 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed