Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX052218\ Data File : VX001914.D Acq On : 23 May 2018 00:58 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 26 Sample Multiplier: 1 Quant Time: May 23 01:17:27 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 246745 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 318969 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 269232 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 181643 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 165527 50.05 ug/l 0.00 Spiked Amount 50.000 Recovery = 100.10% 35) Dibromofluoromethane 5.51 113 143910 53.46 ug/l 0.00 Spiked Amount 50.000 Recovery = 106.92% 50) Toluene-d8 8.72 98 523791 54.33 ug/l 0.00 Spiked Amount 50.000 Recovery = 108.66% 62) 4-Bromofluorobenzene 11.15 95 171826 49.50 ug/l 0.00 Spiked Amount 50.000 Recovery = 99.00% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 109741 44.32 ug/l 99 3) Chloromethane 1.32 50 130020 48.61 ug/l 99 4) Vinyl Chloride 1.40 62 138426 47.87 ug/l 100 5) Bromomethane 1.64 94 59347 48.68 ug/l 95 6) Chloroethane 1.72 64 91831 50.42 ug/l 99 7) Trichlorofluoromethane 1.93 101 205180 48.83 ug/l 100 8) Diethyl Ether 2.19 74 89356 51.66 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.38 101 121673 48.10 ug/l 99 10) Methyl Iodide 2.51 142 142148 61.07 ug/l 99 11) Tert butyl alcohol 3.09 59 184155 313.62 ug/l 100 12) 1,1-Dichloroethene 2.37 96 115696 47.44 ug/l 97 13) Acrolein 2.30 56 49828 119.65 ug/l 97 14) Allyl chloride 2.73 41 234738 52.07 ug/l 98 15) Acrylonitrile 3.15 53 430456 291.87 ug/l 100 16) Acetone 2.45 43 377190 290.37 ug/l 98 17) Carbon Disulfide 2.57 76 251066 39.46 ug/l 99 18) Methyl Acetate 2.78 43 248472 65.43 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 438362 53.33 ug/l 98 20) Methylene Chloride 2.86 84 139025 50.00 ug/l 97 21) trans-1,2-Dichloroethene 3.17 96 125411 46.68 ug/l 98 22) Diisopropyl ether 3.88 45 486583 56.27 ug/l 99 23) Vinyl Acetate 3.83 43 1631718 261.89 ug/l 99 24) 1,1-Dichloroethane 3.70 63 248244 52.34 ug/l 100 25) 2-Butanone 4.72 43 633773 318.67 ug/l 98 26) 2,2-Dichloropropane 4.59 77 137907 36.12 ug/l 97 27) cis-1,2-Dichloroethene 4.60 96 159296 52.11 ug/l 98 28) Bromochloromethane 5.03 49 133353 63.30 ug/l 99 29) Tetrahydrofuran 5.18 42 409812 316.12 ug/l 98 30) Chloroform 5.22 83 273483 54.90 ug/l 98 31) Cyclohexane 5.58 56 205517 49.44 ug/l 99 32) 1,1,1-Trichloroethane 5.50 97 232298 53.96 ug/l 99 36) 1,1-Dichloropropene 5.80 75 186718 50.85 ug/l 99 37) Ethyl Acetate 4.87 43 234113 61.18 ug/l 99 38) Carbon Tetrachloride 5.78 117 206734 53.75 ug/l 99 39) Methylcyclohexane 7.46 83 209629 48.86 ug/l 97 40) Benzene 6.15 78 587408 54.30 ug/l 100 41) Methacrylonitrile 5.07 41 134921 60.97 ug/l 99 42) 1,2-Dichloroethane 6.20 62 215793 55.15 ug/l 99 43) Isopropyl Acetate 6.48 43 358568 59.87 ug/l 99 44) Trichloroethene 7.22 130 178490 53.16 ug/l 100 45) 1,2-Dichloropropane 7.52 63 152212 57.34 ug/l 98 46) Dibromomethane 7.67 93 103071 55.29 ug/l 99 47) Bromodichloromethane 7.90 83 205248 59.34 ug/l 98 48) Methyl methacrylate 7.79 41 196390 62.30 ug/l 97 49) 1,4-Dioxane 7.76 88 85459 1407.95 ug/l 98 51) 4-Methyl-2-Pentanone 8.66 43 1261852 332.46 ug/l 99 52) Toluene 8.79 92 381540 54.89 ug/l 99 53) t-1,3-Dichloropropene 8.44 75 223122 54.82 ug/l 100 54) cis-1,3-Dichloropropene 9.05 75 202174 56.36 ug/l 98 55) 1,1,2-Trichloroethane 9.23 97 152295 57.31 ug/l 98 56) Ethyl methacrylate 9.19 69 213712 56.71 ug/l 100 57) 1,3-Dichloropropane 9.38 76 247315 55.59 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 605978 312.62 ug/l 100 59) 2-Hexanone 9.51 43 845743 311.28 ug/l 99 60) Dibromochloromethane 9.59 129 154466 56.77 ug/l 100 61) 1,2-Dibromoethane 9.68 107 150239 54.01 ug/l 99 64) Tetrachloroethene 9.34 164 214418 61.18 ug/l 100 65) Chlorobenzene 10.15 112 391688 52.89 ug/l 98 66) 1,1,1,2-Tetrachloroethane 10.23 131 150101 57.39 ug/l 99 67) Ethyl Benzene 10.26 91 633244 53.50 ug/l 100 68) m/p-Xylenes 10.37 106 507961 108.78 ug/l 100 69) o-Xylene 10.71 106 247001 55.23 ug/l 100 70) Styrene 10.72 104 419768 56.91 ug/l 100 71) Bromoform 10.87 173 129611 53.05 ug/l 100 73) Isopropylbenzene 11.02 105 669018 55.93 ug/l 100 74) N-amyl acetate 6.48 43 358568 62.52 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 204789 57.07 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 202394m 58.60 ug/l 77) Bromobenzene 11.26 156 192338 54.72 ug/l 99 78) n-propylbenzene 11.37 91 742210 55.07 ug/l 99 79) 2-Chlorotoluene 11.43 91 442914 54.95 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 555519 56.61 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 52662 45.74 ug/l 96 82) 4-Chlorotoluene 11.52 91 515750 54.32 ug/l 99 83) tert-Butylbenzene 11.77 119 539816 55.28 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 576333 56.71 ug/l 100 85) sec-Butylbenzene 11.95 105 676352 56.10 ug/l 100 86) p-Isopropyltoluene 12.07 119 620529 55.63 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 345329 53.12 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 348241 51.81 ug/l 100 89) n-Butylbenzene 12.40 91 506826 52.53 ug/l 100 90) Hexachloroethane 12.60 117 100899 58.24 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 352707 54.46 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 49497 64.63 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 270873 52.47 ug/l 99 94) Hexachlorobutadiene 13.79 225 146697 52.93 ug/l 100 95) Naphthalene 13.84 128 793060 59.10 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 283564 54.54 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed