Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX052218\ Data File : VX001916.D Acq On : 23 May 2018 01:52 Operator : JC/MD Sample : VX0522WBS02 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 28 Sample Multiplier: 1 Quant Time: May 23 03:28:46 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 247782 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 328325 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 277785 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 186191 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 173699 52.30 ug/l 0.00 Spiked Amount 50.000 Recovery = 104.60% 35) Dibromofluoromethane 5.51 113 148326 53.53 ug/l 0.00 Spiked Amount 50.000 Recovery = 107.06% 50) Toluene-d8 8.72 98 542431 54.66 ug/l 0.00 Spiked Amount 50.000 Recovery = 109.32% 62) 4-Bromofluorobenzene 11.14 95 176674 49.45 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.90% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 44240 17.79 ug/l 98 3) Chloromethane 1.32 50 53167 19.79 ug/l 98 4) Vinyl Chloride 1.40 62 55936 19.26 ug/l 99 5) Bromomethane 1.64 94 33549 25.92 ug/l 98 6) Chloroethane 1.73 64 37905 20.72 ug/l 97 7) Trichlorofluoromethane 1.93 101 85085 20.16 ug/l 99 8) Diethyl Ether 2.19 74 35938 20.69 ug/l 100 9) 1,1,2-Trichlorotrifluoroet 2.39 101 49270 19.40 ug/l 98 10) Methyl Iodide 2.51 142 50890 21.77 ug/l 99 11) Tert butyl alcohol 3.08 59 82038 139.13 ug/l 99 12) 1,1-Dichloroethene 2.37 96 47449 19.37 ug/l 93 13) Acrolein 2.30 56 19043 45.54 ug/l 97 14) Allyl chloride 2.73 41 94147 20.80 ug/l 97 15) Acrylonitrile 3.15 53 174260 117.66 ug/l 99 16) Acetone 2.45 43 160607 123.12 ug/l 98 17) Carbon Disulfide 2.57 76 99413 15.56 ug/l 99 18) Methyl Acetate 2.78 43 102295 26.82 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 177320 21.48 ug/l 99 20) Methylene Chloride 2.86 84 57130 20.46 ug/l 98 21) trans-1,2-Dichloroethene 3.17 96 51920 19.24 ug/l 98 22) Diisopropyl ether 3.88 45 196561 22.63 ug/l 97 23) Vinyl Acetate 3.83 43 639313 102.18 ug/l 99 24) 1,1-Dichloroethane 3.70 63 103150 21.66 ug/l 99 25) 2-Butanone 4.71 43 260929 130.65 ug/l 98 26) 2,2-Dichloropropane 4.59 77 53908 14.06 ug/l 97 27) cis-1,2-Dichloroethene 4.60 96 63957 20.83 ug/l 97 28) Bromochloromethane 5.03 49 53466 25.27 ug/l 97 29) Tetrahydrofuran 5.18 42 167113 128.37 ug/l 97 30) Chloroform 5.22 83 112473 22.48 ug/l 99 31) Cyclohexane 5.58 56 82214 19.69 ug/l 94 32) 1,1,1-Trichloroethane 5.50 97 93697 21.67 ug/l 99 36) 1,1-Dichloropropene 5.81 75 74155 19.62 ug/l 98 37) Ethyl Acetate 4.87 43 93975 23.86 ug/l 100 38) Carbon Tetrachloride 5.79 117 82000 20.71 ug/l 97 39) Methylcyclohexane 7.46 83 79625 18.03 ug/l 96 40) Benzene 6.15 78 239646 21.52 ug/l 100 41) Methacrylonitrile 5.07 41 53192 23.35 ug/l 99 42) 1,2-Dichloroethane 6.21 62 89074 22.12 ug/l 99 43) Isopropyl Acetate 6.48 43 140089 22.72 ug/l 99 44) Trichloroethene 7.22 130 72437 20.96 ug/l 96 45) 1,2-Dichloropropane 7.52 63 62100 22.73 ug/l 99 46) Dibromomethane 7.67 93 41211 21.48 ug/l 98 47) Bromodichloromethane 7.91 83 78230 21.97 ug/l 98 48) Methyl methacrylate 7.79 41 75431 23.25 ug/l 98 49) 1,4-Dioxane 7.76 88 33538 536.80 ug/l 95 51) 4-Methyl-2-Pentanone 8.66 43 503054 128.76 ug/l 98 52) Toluene 8.79 92 154604 21.61 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 85652 20.45 ug/l 98 54) cis-1,3-Dichloropropene 9.05 75 75077 20.33 ug/l 100 55) 1,1,2-Trichloroethane 9.22 97 59583 21.78 ug/l 99 56) Ethyl methacrylate 9.19 69 81267 20.95 ug/l 99 57) 1,3-Dichloropropane 9.38 76 96682 21.11 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 237173 118.87 ug/l 100 59) 2-Hexanone 9.51 43 339341 121.34 ug/l 99 60) Dibromochloromethane 9.59 129 59606 21.28 ug/l 99 61) 1,2-Dibromoethane 9.68 107 60462 21.12 ug/l 99 64) Tetrachloroethene 9.34 164 78284 21.65 ug/l 99 65) Chlorobenzene 10.14 112 160207 20.97 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 59161 21.92 ug/l 100 67) Ethyl Benzene 10.26 91 251517 20.60 ug/l 100 68) m/p-Xylenes 10.37 106 203750 42.29 ug/l 99 69) o-Xylene 10.70 106 97442 21.12 ug/l 98 70) Styrene 10.72 104 165547 21.75 ug/l 100 71) Bromoform 10.86 173 47273 20.65 ug/l # 98 73) Isopropylbenzene 11.02 105 268005 21.86 ug/l 100 74) N-amyl acetate 6.48 43 140089 23.83 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 85172 23.16 ug/l 98 76) 1,2,3-Trichloropropane 11.30 75 81412m 22.99 ug/l 77) Bromobenzene 11.26 156 78282 21.73 ug/l 99 78) n-propylbenzene 11.37 91 293630 21.26 ug/l 100 79) 2-Chlorotoluene 11.43 91 179595 21.74 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 221005 21.97 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 18721 18.02 ug/l 89 82) 4-Chlorotoluene 11.52 91 207750 21.34 ug/l 100 83) tert-Butylbenzene 11.77 119 213536 21.33 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 230380 22.12 ug/l 99 85) sec-Butylbenzene 11.95 105 267524 21.65 ug/l 100 86) p-Isopropyltoluene 12.07 119 245310 21.45 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 140250 21.05 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 141906 20.60 ug/l 99 89) n-Butylbenzene 12.40 91 196557 19.88 ug/l 99 90) Hexachloroethane 12.60 117 38713 21.80 ug/l 98 91) 1,2-Dichlorobenzene 12.40 146 141647 21.34 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 18966 24.16 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 106771 20.18 ug/l 100 94) Hexachlorobutadiene 13.79 225 57476 20.23 ug/l 99 95) Naphthalene 13.84 128 298588 21.71 ug/l 99 96) 1,2,3-Trichlorobenzene 14.02 180 111846 20.99 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed