Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX052218\ Data File : VX001917.D Acq On : 23 May 2018 02:19 Operator : JC/MD Sample : VX0522WBSD02 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 29 Sample Multiplier: 1 Quant Time: May 23 03:44:58 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X051518W.M Quant Title : SW846 8260 QLast Update : Tue May 15 01:36:22 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 245310 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 323109 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 271476 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 182645 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 172174 52.36 ug/l 0.00 Spiked Amount 50.000 Recovery = 104.72% 35) Dibromofluoromethane 5.51 113 144853 53.12 ug/l 0.00 Spiked Amount 50.000 Recovery = 106.24% 50) Toluene-d8 8.72 98 528595 54.13 ug/l 0.00 Spiked Amount 50.000 Recovery = 108.26% 62) 4-Bromofluorobenzene 11.14 95 174820 49.72 ug/l 0.00 Spiked Amount 50.000 Recovery = 99.44% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 42274 17.17 ug/l 97 3) Chloromethane 1.32 50 52895 19.89 ug/l 98 4) Vinyl Chloride 1.40 62 53568 18.63 ug/l 99 5) Bromomethane 1.64 94 33965 26.58 ug/l 97 6) Chloroethane 1.73 64 35826 19.78 ug/l 97 7) Trichlorofluoromethane 1.93 101 82200 19.68 ug/l 99 8) Diethyl Ether 2.19 74 36901 21.46 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.39 101 47687 18.96 ug/l 98 10) Methyl Iodide 2.51 142 49255 21.29 ug/l 98 11) Tert butyl alcohol 3.08 59 80807 138.42 ug/l 98 12) 1,1-Dichloroethene 2.37 96 45956 18.95 ug/l 96 13) Acrolein 2.29 56 19397 46.85 ug/l 96 14) Allyl chloride 2.73 41 93025 20.76 ug/l 95 15) Acrylonitrile 3.15 53 179408 122.36 ug/l 99 16) Acetone 2.45 43 163479 126.59 ug/l 98 17) Carbon Disulfide 2.57 76 96545 15.26 ug/l 99 18) Methyl Acetate 2.78 43 103957 27.53 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 181106 22.16 ug/l 100 20) Methylene Chloride 2.86 84 57136 20.67 ug/l 100 21) trans-1,2-Dichloroethene 3.17 96 50844 19.04 ug/l 99 22) Diisopropyl ether 3.88 45 193304 22.48 ug/l 98 23) Vinyl Acetate 3.83 43 644303 104.01 ug/l 99 24) 1,1-Dichloroethane 3.70 63 100883 21.40 ug/l 99 25) 2-Butanone 4.71 43 260796 131.90 ug/l 97 26) 2,2-Dichloropropane 4.59 77 50657 13.35 ug/l 95 27) cis-1,2-Dichloroethene 4.60 96 64137 21.10 ug/l 97 28) Bromochloromethane 5.03 49 53457 25.52 ug/l 97 29) Tetrahydrofuran 5.18 42 168508 130.74 ug/l 98 30) Chloroform 5.23 83 109552 22.12 ug/l 98 31) Cyclohexane 5.58 56 79518 19.24 ug/l 96 32) 1,1,1-Trichloroethane 5.50 97 90461 21.14 ug/l 98 36) 1,1-Dichloropropene 5.80 75 71945 19.34 ug/l 99 37) Ethyl Acetate 4.87 43 95914 24.74 ug/l 100 38) Carbon Tetrachloride 5.79 117 80126 20.56 ug/l 99 39) Methylcyclohexane 7.46 83 76842 17.68 ug/l 98 40) Benzene 6.15 78 234913 21.44 ug/l 100 41) Methacrylonitrile 5.07 41 54783 24.44 ug/l 98 42) 1,2-Dichloroethane 6.21 62 89149 22.49 ug/l 99 43) Isopropyl Acetate 6.48 43 141704 23.36 ug/l 99 44) Trichloroethene 7.22 130 69678 20.49 ug/l 96 45) 1,2-Dichloropropane 7.52 63 62915 23.40 ug/l 99 46) Dibromomethane 7.67 93 41199 21.82 ug/l 99 47) Bromodichloromethane 7.90 83 78559 22.42 ug/l 95 48) Methyl methacrylate 7.79 41 77065 24.13 ug/l 98 49) 1,4-Dioxane 7.76 88 34943 568.32 ug/l 98 51) 4-Methyl-2-Pentanone 8.66 43 513345 133.52 ug/l 98 52) Toluene 8.79 92 152276 21.62 ug/l 97 53) t-1,3-Dichloropropene 8.44 75 84557 20.51 ug/l 100 54) cis-1,3-Dichloropropene 9.05 75 75260 20.71 ug/l 100 55) 1,1,2-Trichloroethane 9.22 97 57953 21.53 ug/l 97 56) Ethyl methacrylate 9.19 69 81552 21.36 ug/l 99 57) 1,3-Dichloropropane 9.38 76 95448 21.18 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 239092 121.77 ug/l 100 59) 2-Hexanone 9.51 43 343498 124.81 ug/l 98 60) Dibromochloromethane 9.59 129 58624 21.27 ug/l 100 61) 1,2-Dibromoethane 9.68 107 59973 21.28 ug/l 99 64) Tetrachloroethene 9.34 164 76025 21.51 ug/l 95 65) Chlorobenzene 10.15 112 156083 20.90 ug/l 97 66) 1,1,1,2-Tetrachloroethane 10.23 131 58227 22.08 ug/l 99 67) Ethyl Benzene 10.26 91 248149 20.79 ug/l 99 68) m/p-Xylenes 10.37 106 199081 42.28 ug/l 100 69) o-Xylene 10.70 106 94685 21.00 ug/l 97 70) Styrene 10.72 104 160701 21.61 ug/l 99 71) Bromoform 10.87 173 47220 21.04 ug/l # 100 73) Isopropylbenzene 11.02 105 261295 21.72 ug/l 99 74) N-amyl acetate 6.48 43 141704 24.57 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 85206 23.61 ug/l 98 76) 1,2,3-Trichloropropane 11.30 75 81263m 23.40 ug/l 77) Bromobenzene 11.26 156 76734 21.71 ug/l 99 78) n-propylbenzene 11.37 91 288662 21.30 ug/l 99 79) 2-Chlorotoluene 11.43 91 175680 21.68 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 217050 22.00 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 18621 18.23 ug/l 91 82) 4-Chlorotoluene 11.52 91 203495 21.31 ug/l 100 83) tert-Butylbenzene 11.77 119 210689 21.46 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 223853 21.91 ug/l 100 85) sec-Butylbenzene 11.95 105 260668 21.50 ug/l 100 86) p-Isopropyltoluene 12.07 119 237262 21.15 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 138189 21.14 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 141355 20.91 ug/l 99 89) n-Butylbenzene 12.40 91 190938 19.68 ug/l 99 90) Hexachloroethane 12.60 117 36629 21.03 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 139073 21.35 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 18858 24.49 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 104712 20.17 ug/l 99 94) Hexachlorobutadiene 13.79 225 55560 19.94 ug/l 98 95) Naphthalene 13.84 128 300877 22.30 ug/l 99 96) 1,2,3-Trichlorobenzene 14.02 180 109951 21.03 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed