Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX052718\ Data File : VX002061.D Acq On : 27 May 2018 11:34 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 2 Sample Multiplier: 1 Quant Time: May 29 03:14:26 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X052418W.M Quant Title : SW846 8260 QLast Update : Thu May 24 13:09:03 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 244650 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.86 114 350254 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 334056 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 237049 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 202152 46.23 ug/l 0.00 Spiked Amount 50.000 Recovery = 92.46% 35) Dibromofluoromethane 5.51 113 160835 45.92 ug/l 0.00 Spiked Amount 50.000 Recovery = 91.84% 50) Toluene-d8 8.72 98 596577 47.05 ug/l 0.00 Spiked Amount 50.000 Recovery = 94.10% 62) 4-Bromofluorobenzene 11.14 95 241010 48.58 ug/l 0.00 Spiked Amount 50.000 Recovery = 97.16% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 130522 42.32 ug/l 98 3) Chloromethane 1.32 50 220880 58.68 ug/l 100 4) Vinyl Chloride 1.41 62 168366 46.32 ug/l 99 5) Bromomethane 1.64 94 79222 47.30 ug/l 97 6) Chloroethane 1.72 64 109766 51.23 ug/l 99 7) Trichlorofluoromethane 1.93 101 271102 49.67 ug/l 99 8) Diethyl Ether 2.19 74 111094 56.10 ug/l 100 9) 1,1,2-Trichlorotrifluoroet 2.39 101 152694 50.13 ug/l 98 10) Methyl Iodide 2.51 142 176185 42.75 ug/l 99 11) Tert butyl alcohol 3.07 59 217776 253.70 ug/l 99 12) 1,1-Dichloroethene 2.37 96 138785 48.67 ug/l 95 13) Acrolein 2.30 56 63532 171.18 ug/l 100 14) Allyl chloride 2.73 41 317639 53.07 ug/l 98 15) Acrylonitrile 3.15 53 460539 260.90 ug/l 99 16) Acetone 2.45 43 460576 272.90 ug/l 100 17) Carbon Disulfide 2.57 76 364584 44.42 ug/l 99 18) Methyl Acetate 2.78 43 239391 59.09 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 585586 54.60 ug/l 99 20) Methylene Chloride 2.86 84 295199 102.78 ug/l 98 21) trans-1,2-Dichloroethene 3.17 96 151409 54.69 ug/l 98 22) Diisopropyl ether 3.87 45 611224 50.20 ug/l 97 23) Vinyl Acetate 3.82 43 2709671 268.42 ug/l 99 24) 1,1-Dichloroethane 3.70 63 315068 54.48 ug/l 100 25) 2-Butanone 4.71 43 678397 219.31 ug/l 98 26) 2,2-Dichloropropane 4.59 77 255917 43.72 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 172001 46.26 ug/l 99 28) Bromochloromethane 5.02 49 130010 53.64 ug/l 99 29) Tetrahydrofuran 5.16 42 435338 216.31 ug/l 100 30) Chloroform 5.22 83 302202 46.38 ug/l 98 31) Cyclohexane 5.58 56 248209 41.19 ug/l 98 32) 1,1,1-Trichloroethane 5.50 97 263696 43.41 ug/l 99 36) 1,1-Dichloropropene 5.80 75 211084 43.33 ug/l 99 37) Ethyl Acetate 4.86 43 267945 42.19 ug/l 100 38) Carbon Tetrachloride 5.78 117 232882 40.99 ug/l 99 39) Methylcyclohexane 7.46 83 257663 43.05 ug/l 98 40) Benzene 6.15 78 655682 45.94 ug/l 100 41) Methacrylonitrile 5.06 41 152244 45.29 ug/l 98 42) 1,2-Dichloroethane 6.20 62 260476 45.69 ug/l 100 43) Isopropyl Acetate 6.46 43 473331 44.73 ug/l 99 44) Trichloroethene 7.21 130 188520 45.33 ug/l 99 45) 1,2-Dichloropropane 7.52 63 184629 47.63 ug/l 99 46) Dibromomethane 7.67 93 122339 47.67 ug/l 99 47) Bromodichloromethane 7.90 83 245038 44.78 ug/l 100 48) Methyl methacrylate 7.78 41 238873 44.35 ug/l 99 49) 1,4-Dioxane 7.76 88 83930 884.25 ug/l 96 51) 4-Methyl-2-Pentanone 8.65 43 1450314 227.34 ug/l 100 52) Toluene 8.79 92 423858 46.66 ug/l 99 53) t-1,3-Dichloropropene 8.44 75 294422 46.72 ug/l 99 54) cis-1,3-Dichloropropene 9.04 75 284023 46.25 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 179381 47.27 ug/l 98 56) Ethyl methacrylate 9.18 69 296610 45.44 ug/l 99 57) 1,3-Dichloropropane 9.38 76 300467 48.07 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 724010 250.27 ug/l 100 59) 2-Hexanone 9.50 43 1122950 228.28 ug/l 100 60) Dibromochloromethane 9.59 129 206308 45.90 ug/l 99 61) 1,2-Dibromoethane 9.68 107 190047 47.73 ug/l 99 64) Tetrachloroethene 9.34 164 218757 45.67 ug/l 99 65) Chlorobenzene 10.14 112 493116 46.59 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 193457 45.27 ug/l 100 67) Ethyl Benzene 10.26 91 846905 46.06 ug/l 99 68) m/p-Xylenes 10.36 106 656587 93.41 ug/l 100 69) o-Xylene 10.70 106 326859 46.57 ug/l 100 70) Styrene 10.71 104 553316 47.54 ug/l 99 71) Bromoform 10.86 173 171905 42.42 ug/l # 99 73) Isopropylbenzene 11.02 105 864739 43.08 ug/l 100 74) N-amyl acetate 6.46 43 473331 45.15 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 264786 48.18 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 284933m 50.04 ug/l 77) Bromobenzene 11.26 156 240926 45.24 ug/l 97 78) n-propylbenzene 11.37 91 996130 44.31 ug/l 100 79) 2-Chlorotoluene 11.43 91 604101 48.93 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 753285 43.91 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 93894 39.63 ug/l 95 82) 4-Chlorotoluene 11.51 91 716903 45.21 ug/l 100 83) tert-Butylbenzene 11.77 119 722456 42.92 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 788235 44.46 ug/l 100 85) sec-Butylbenzene 11.95 105 889985 43.98 ug/l 100 86) p-Isopropyltoluene 12.07 119 811564 44.82 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 438227 45.95 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 445407 46.71 ug/l 99 89) n-Butylbenzene 12.39 91 709207 46.22 ug/l 99 90) Hexachloroethane 12.60 117 142675 39.94 ug/l 98 91) 1,2-Dichlorobenzene 12.40 146 450675 46.38 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 68813 38.56 ug/l 100 93) 1,2,4-Trichlorobenzene 13.65 180 335307 48.25 ug/l 100 94) Hexachlorobutadiene 13.79 225 167231 44.74 ug/l 99 95) Naphthalene 13.84 128 966727 45.15 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 340179 47.31 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed