Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX052718\ Data File : VX002063.D Acq On : 27 May 2018 12:53 Operator : JC/MD Sample : VX0527WBS01 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 4 Sample Multiplier: 1 Quant Time: May 29 03:24:18 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X052418W.M Quant Title : SW846 8260 QLast Update : Thu May 24 13:09:03 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 248515 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.86 114 341164 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 318114 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 214684 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 201250 45.30 ug/l 0.00 Spiked Amount 50.000 Recovery = 90.60% 35) Dibromofluoromethane 5.51 113 156640 45.91 ug/l 0.00 Spiked Amount 50.000 Recovery = 91.82% 50) Toluene-d8 8.72 98 592745 47.99 ug/l 0.00 Spiked Amount 50.000 Recovery = 95.98% 62) 4-Bromofluorobenzene 11.14 95 226247 46.82 ug/l 0.00 Spiked Amount 50.000 Recovery = 93.64% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 59640 17.87 ug/l 96 3) Chloromethane 1.32 50 92595 24.22 ug/l 100 4) Vinyl Chloride 1.40 62 73466 19.90 ug/l 99 5) Bromomethane 1.64 94 39775 22.88 ug/l 96 6) Chloroethane 1.73 64 47264 21.72 ug/l 99 7) Trichlorofluoromethane 1.93 101 119916 21.63 ug/l 98 8) Diethyl Ether 2.19 74 44729 22.23 ug/l 100 9) 1,1,2-Trichlorotrifluoroet 2.39 101 68627 22.18 ug/l 98 10) Methyl Iodide 2.51 142 63331 15.13 ug/l 98 11) Tert butyl alcohol 3.07 59 90424 103.70 ug/l 99 12) 1,1-Dichloroethene 2.37 96 60595 20.92 ug/l 97 13) Acrolein 2.29 56 23507 62.35 ug/l 98 14) Allyl chloride 2.73 41 130287 21.43 ug/l 98 15) Acrylonitrile 3.15 53 190153 106.05 ug/l 99 16) Acetone 2.45 43 191788 111.87 ug/l 99 17) Carbon Disulfide 2.57 76 157366 18.88 ug/l 99 18) Methyl Acetate 2.78 43 98839 23.33 ug/l 99 19) Methyl tert-butyl Ether 3.20 73 238258 21.87 ug/l 98 20) Methylene Chloride 2.86 84 86439 28.40 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 64727 22.07 ug/l 97 22) Diisopropyl ether 3.87 45 238644 19.30 ug/l 99 23) Vinyl Acetate 3.82 43 1059518 103.32 ug/l 98 24) 1,1-Dichloroethane 3.70 63 131525 22.39 ug/l 98 25) 2-Butanone 4.70 43 277078 88.18 ug/l 100 26) 2,2-Dichloropropane 4.59 77 108550 18.25 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 71263 18.87 ug/l 88 28) Bromochloromethane 5.02 49 53064 20.28 ug/l 99 29) Tetrahydrofuran 5.17 42 174983 85.59 ug/l 99 30) Chloroform 5.21 83 123307 18.63 ug/l 97 31) Cyclohexane 5.57 56 110239 18.01 ug/l 95 32) 1,1,1-Trichloroethane 5.49 97 111927 18.14 ug/l 99 36) 1,1-Dichloropropene 5.81 75 87485 18.44 ug/l 97 37) Ethyl Acetate 4.86 43 108079 17.47 ug/l 100 38) Carbon Tetrachloride 5.79 117 97879 17.69 ug/l 98 39) Methylcyclohexane 7.46 83 112384 19.28 ug/l 100 40) Benzene 6.15 78 271119 19.50 ug/l 97 41) Methacrylonitrile 5.06 41 61978 18.12 ug/l 97 42) 1,2-Dichloroethane 6.20 62 105698 19.03 ug/l 99 43) Isopropyl Acetate 6.46 43 187979 18.24 ug/l 99 44) Trichloroethene 7.21 130 78221 19.31 ug/l 99 45) 1,2-Dichloropropane 7.52 63 74486 19.73 ug/l 94 46) Dibromomethane 7.67 93 48351 19.34 ug/l 99 47) Bromodichloromethane 7.90 83 95971 18.01 ug/l 98 48) Methyl methacrylate 7.78 41 95996 18.30 ug/l 99 49) 1,4-Dioxane 7.76 88 34093 368.76 ug/l 97 51) 4-Methyl-2-Pentanone 8.65 43 573076 92.22 ug/l 100 52) Toluene 8.79 92 174264 19.70 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 115348 18.79 ug/l 97 54) cis-1,3-Dichloropropene 9.04 75 109761 18.35 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 71605 19.37 ug/l 99 56) Ethyl methacrylate 9.18 69 117119 18.42 ug/l 100 57) 1,3-Dichloropropane 9.37 76 120480 19.79 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 287869 102.16 ug/l 99 59) 2-Hexanone 9.50 43 443098 92.48 ug/l 99 60) Dibromochloromethane 9.59 129 77949 17.81 ug/l 99 61) 1,2-Dibromoethane 9.68 107 74807 19.29 ug/l 100 64) Tetrachloroethene 9.34 164 90350 19.81 ug/l 99 65) Chlorobenzene 10.14 112 195971 19.44 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 75042 18.44 ug/l 100 67) Ethyl Benzene 10.26 91 340047 19.42 ug/l 99 68) m/p-Xylenes 10.36 106 261585 39.08 ug/l 99 69) o-Xylene 10.70 106 129252 19.34 ug/l 99 70) Styrene 10.71 104 212418 19.16 ug/l 100 71) Bromoform 10.86 173 62261 16.13 ug/l # 99 73) Isopropylbenzene 11.02 105 350046 19.25 ug/l 99 74) N-amyl acetate 6.46 43 187979 17.91 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 101455 19.64 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 109628m 21.26 ug/l 77) Bromobenzene 11.26 156 93410 19.37 ug/l 96 78) n-propylbenzene 11.37 91 392314 19.27 ug/l 100 79) 2-Chlorotoluene 11.43 91 236603 19.79 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 299669 19.29 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 33852 15.78 ug/l 94 82) 4-Chlorotoluene 11.51 91 276100 19.23 ug/l 100 83) tert-Butylbenzene 11.77 119 290717 19.07 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 306767 19.11 ug/l 98 85) sec-Butylbenzene 11.95 105 353681 19.30 ug/l 100 86) p-Isopropyltoluene 12.07 119 319225 19.47 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 168513 19.51 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 168825 19.55 ug/l 99 89) n-Butylbenzene 12.39 91 270951 19.50 ug/l 100 90) Hexachloroethane 12.60 117 54560 16.87 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 170229 19.34 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 25015 15.48 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 124741 19.82 ug/l 99 94) Hexachlorobutadiene 13.79 225 65301 19.29 ug/l 98 95) Naphthalene 13.84 128 366255 18.89 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 127492 19.58 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed