Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX052718\ Data File : VX002064.D Acq On : 27 May 2018 13:19 Operator : JC/MD Sample : VX0527WBSD01 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 5 Sample Multiplier: 1 Quant Time: May 29 07:34:36 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X052418W.M Quant Title : SW846 8260 QLast Update : Thu May 24 13:09:03 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 240157 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 333741 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 311306 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 203988 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 204196 47.57 ug/l 0.00 Spiked Amount 50.000 Recovery = 95.14% 35) Dibromofluoromethane 5.51 113 156011 46.75 ug/l 0.00 Spiked Amount 50.000 Recovery = 93.50% 50) Toluene-d8 8.72 98 579371 47.95 ug/l 0.00 Spiked Amount 50.000 Recovery = 95.90% 62) 4-Bromofluorobenzene 11.14 95 221996 46.96 ug/l 0.00 Spiked Amount 50.000 Recovery = 93.92% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 57943 17.98 ug/l 97 3) Chloromethane 1.32 50 89338 24.18 ug/l 99 4) Vinyl Chloride 1.40 62 72263 20.25 ug/l 99 5) Bromomethane 1.64 94 38631 23.00 ug/l 97 6) Chloroethane 1.73 64 46033 21.89 ug/l 97 7) Trichlorofluoromethane 1.93 101 116000 21.65 ug/l 99 8) Diethyl Ether 2.19 74 45235 23.27 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.39 101 65910 22.04 ug/l 97 10) Methyl Iodide 2.51 142 67121 16.59 ug/l 98 11) Tert butyl alcohol 3.07 59 99190 117.71 ug/l 98 12) 1,1-Dichloroethene 2.38 96 59467 21.24 ug/l 100 13) Acrolein 2.29 56 25801 70.82 ug/l 95 14) Allyl chloride 2.73 41 131062 22.31 ug/l 98 15) Acrylonitrile 3.15 53 199367 115.05 ug/l 100 16) Acetone 2.45 43 197364 119.13 ug/l 99 17) Carbon Disulfide 2.57 76 153943 19.11 ug/l 99 18) Methyl Acetate 2.78 43 104310 25.58 ug/l 98 19) Methyl tert-butyl Ether 3.21 73 241966 22.98 ug/l 98 20) Methylene Chloride 2.86 84 78190 26.47 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 62964 22.23 ug/l 95 22) Diisopropyl ether 3.87 45 240464 20.12 ug/l 96 23) Vinyl Acetate 3.82 43 1061254 107.10 ug/l 98 24) 1,1-Dichloroethane 3.70 63 123125 21.69 ug/l 99 25) 2-Butanone 4.71 43 293296 96.59 ug/l 100 26) 2,2-Dichloropropane 4.59 77 107081 18.63 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 71352 19.55 ug/l 84 28) Bromochloromethane 5.03 49 53676 21.33 ug/l 99 29) Tetrahydrofuran 5.17 42 187306 94.81 ug/l 99 30) Chloroform 5.22 83 123646 19.33 ug/l 97 31) Cyclohexane 5.58 56 108782 18.39 ug/l 97 32) 1,1,1-Trichloroethane 5.50 97 112264 18.83 ug/l 99 36) 1,1-Dichloropropene 5.80 75 86007 18.53 ug/l 98 37) Ethyl Acetate 4.86 43 113733 18.79 ug/l 100 38) Carbon Tetrachloride 5.79 117 98590 18.21 ug/l 97 39) Methylcyclohexane 7.46 83 107776 18.90 ug/l 96 40) Benzene 6.15 78 269609 19.82 ug/l 100 41) Methacrylonitrile 5.06 41 65016 19.53 ug/l 98 42) 1,2-Dichloroethane 6.20 62 105754 19.47 ug/l 99 43) Isopropyl Acetate 6.47 43 194144 19.25 ug/l 99 44) Trichloroethene 7.22 130 77381 19.52 ug/l 100 45) 1,2-Dichloropropane 7.52 63 74593 20.20 ug/l 97 46) Dibromomethane 7.67 93 50154 20.51 ug/l 98 47) Bromodichloromethane 7.90 83 96077 18.43 ug/l 99 48) Methyl methacrylate 7.78 41 99427 19.37 ug/l 99 49) 1,4-Dioxane 7.76 88 36746 406.29 ug/l 98 51) 4-Methyl-2-Pentanone 8.65 43 609505 100.27 ug/l 99 52) Toluene 8.79 92 171333 19.80 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 115706 19.27 ug/l 98 54) cis-1,3-Dichloropropene 9.05 75 109449 18.70 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 71861 19.87 ug/l 99 56) Ethyl methacrylate 9.18 69 119099 19.15 ug/l 98 57) 1,3-Dichloropropane 9.38 76 121695 20.43 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 293669 106.54 ug/l 100 59) 2-Hexanone 9.50 43 470506 100.38 ug/l 99 60) Dibromochloromethane 9.59 129 79939 18.67 ug/l 99 61) 1,2-Dibromoethane 9.68 107 76020 20.04 ug/l 100 64) Tetrachloroethene 9.34 164 86505 19.38 ug/l 99 65) Chlorobenzene 10.14 112 194649 19.74 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 75025 18.84 ug/l 100 67) Ethyl Benzene 10.26 91 330920 19.31 ug/l 99 68) m/p-Xylenes 10.36 106 253864 38.75 ug/l 100 69) o-Xylene 10.70 106 126817 19.39 ug/l 100 70) Styrene 10.72 104 211544 19.50 ug/l 99 71) Bromoform 10.86 173 63095 16.71 ug/l 98 73) Isopropylbenzene 11.02 105 339748 19.67 ug/l 100 74) N-amyl acetate 6.47 43 194144 19.76 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 104704 21.44 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 95780m 19.55 ug/l 77) Bromobenzene 11.26 156 90558 19.76 ug/l 97 78) n-propylbenzene 11.37 91 378492 19.56 ug/l 100 79) 2-Chlorotoluene 11.43 91 231346 20.44 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 286713 19.42 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 34213 16.78 ug/l 92 82) 4-Chlorotoluene 11.51 91 264742 19.40 ug/l 100 83) tert-Butylbenzene 11.77 119 280047 19.33 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 294064 19.28 ug/l 99 85) sec-Butylbenzene 11.95 105 335897 19.29 ug/l 99 86) p-Isopropyltoluene 12.07 119 300963 19.31 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 162246 19.77 ug/l 98 88) 1,4-Dichlorobenzene 12.10 146 162544 19.81 ug/l 100 89) n-Butylbenzene 12.39 91 252833 19.15 ug/l 99 90) Hexachloroethane 12.60 117 51897 16.88 ug/l 98 91) 1,2-Dichlorobenzene 12.40 146 167318 20.01 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 25847 16.83 ug/l 97 93) 1,2,4-Trichlorobenzene 13.65 180 116850 19.54 ug/l 99 94) Hexachlorobutadiene 13.79 225 62447 19.41 ug/l 100 95) Naphthalene 13.84 128 364988 19.81 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 121666 19.66 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed